Remote Impacts of Methyl Substituents on the Guest-Binding Ability of Self-Assembled Cages

We synthesized self‐assembled coordination cages in which 1,10‐phenanthroline derivatives serve as capping ligands. Substituents at the 2,9‐positions of the phenanthroline ligand covered the outside of the cage but had an impact on the guest binding inside the cage. Introduction of methyl groups at...

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Veröffentlicht in:	Chemistry, an Asian journal an Asian journal, 2014-05, Vol.9 (5), p.1321-1328
Hauptverfasser:	Fang, Yu, Murase, Takashi, Fujita, Makoto
Format:	Artikel
Sprache:	eng
Schlagworte:	Binding sites Chemistry Crystallography, X-Ray High temperature host-guest systems ligand effects Ligands Models, Molecular molecular recognition Molecular Structure Phenanthrolines - chemistry self-assembly through-space interactions
Online-Zugang:	Volltext
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