Adsorption Process of CO2 on Silicalite‑1 Zeolite Using Single-Crystal X‑ray Method

Adsorption Process of CO2 on Silicalite‑1 Zeolite Using Single-Crystal X‑ray Method

The process of CO2 adsorption on silicalite-1 zeolite (MFI-type) is revealed using a single-crystal X-ray method. The structure of CO2-silicalite-1 with a small amount of CO2 in the pore is determined, wherein most of CO2 molecules are located in the straight channel. It indicates the straight chann...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Langmuir 2014-04, Vol.30 (13), p.3749-3753
Hauptverfasser: Fujiyama, Shinjiro, Kamiya, Natsumi, Nishi, Koji, Yokomori, Yoshinobu
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 3753
container_issue 13
container_start_page 3749
container_title Langmuir
container_volume 30
creator Fujiyama, Shinjiro
Kamiya, Natsumi
Nishi, Koji
Yokomori, Yoshinobu
description The process of CO2 adsorption on silicalite-1 zeolite (MFI-type) is revealed using a single-crystal X-ray method. The structure of CO2-silicalite-1 with a small amount of CO2 in the pore is determined, wherein most of CO2 molecules are located in the straight channel. It indicates the straight channel is the most stable sorption site based on the van der Waals interactions between the CO2 and the framework, and the CO2 molecules initially adsorb in the straight channel in the adsorption process. This is the first report to describe the structure of MFI-type zeolites with the adsorbate molecules occupying only the straight channel.
doi_str_mv 10.1021/la404962e
format Article
fullrecord <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_proquest_miscellaneous_1514437149</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1514437149</sourcerecordid><originalsourceid>FETCH-LOGICAL-a278t-72bcd8d65f36f34e590d1d71fb4c64eaba821c28c3265f24c596378ca6133ef93</originalsourceid><addsrcrecordid>eNo90M1KAzEQB_Agiq3Vgy8guQheVvO1ye6xLPUDKhW0KF5CNsnWLemmJruH3nwFX9EncUurpxlmfgzDH4BzjK4xIvjGKYZYzok9AEOcEpSkGRGHYIgEo4lgnA7ASYxLhFBOWX4MBoRxkiHGh-B1bKIP67b2DXwKXtsYoa9gMSOwnzzXrtbK1a39-frG8N36bQ_nsW4W_bJZOJsUYRNb5eBbT4LawEfbfnhzCo4q5aI929cRmN9OXor7ZDq7eyjG00QRkbWJIKU2meFpRXlFmU1zZLARuCqZ5syqUmUEa5JpSnpDmE5zTkWmFceU2iqnI3C1u7sO_rOzsZWrOmrrnGqs76LEKWaMCsy29GJPu3JljVyHeqXCRv6F0YPLHVA6yqXvQtN_LjGS25Dlf8j0F1EqbKk</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1514437149</pqid></control><display><type>article</type><title>Adsorption Process of CO2 on Silicalite‑1 Zeolite Using Single-Crystal X‑ray Method</title><source>ACS Publications</source><creator>Fujiyama, Shinjiro ; Kamiya, Natsumi ; Nishi, Koji ; Yokomori, Yoshinobu</creator><creatorcontrib>Fujiyama, Shinjiro ; Kamiya, Natsumi ; Nishi, Koji ; Yokomori, Yoshinobu</creatorcontrib><description>The process of CO2 adsorption on silicalite-1 zeolite (MFI-type) is revealed using a single-crystal X-ray method. The structure of CO2-silicalite-1 with a small amount of CO2 in the pore is determined, wherein most of CO2 molecules are located in the straight channel. It indicates the straight channel is the most stable sorption site based on the van der Waals interactions between the CO2 and the framework, and the CO2 molecules initially adsorb in the straight channel in the adsorption process. This is the first report to describe the structure of MFI-type zeolites with the adsorbate molecules occupying only the straight channel.</description><identifier>ISSN: 0743-7463</identifier><identifier>EISSN: 1520-5827</identifier><identifier>DOI: 10.1021/la404962e</identifier><identifier>PMID: 24628046</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><ispartof>Langmuir, 2014-04, Vol.30 (13), p.3749-3753</ispartof><rights>Copyright © 2014 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/la404962e$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/la404962e$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/24628046$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Fujiyama, Shinjiro</creatorcontrib><creatorcontrib>Kamiya, Natsumi</creatorcontrib><creatorcontrib>Nishi, Koji</creatorcontrib><creatorcontrib>Yokomori, Yoshinobu</creatorcontrib><title>Adsorption Process of CO2 on Silicalite‑1 Zeolite Using Single-Crystal X‑ray Method</title><title>Langmuir</title><addtitle>Langmuir</addtitle><description>The process of CO2 adsorption on silicalite-1 zeolite (MFI-type) is revealed using a single-crystal X-ray method. The structure of CO2-silicalite-1 with a small amount of CO2 in the pore is determined, wherein most of CO2 molecules are located in the straight channel. It indicates the straight channel is the most stable sorption site based on the van der Waals interactions between the CO2 and the framework, and the CO2 molecules initially adsorb in the straight channel in the adsorption process. This is the first report to describe the structure of MFI-type zeolites with the adsorbate molecules occupying only the straight channel.</description><issn>0743-7463</issn><issn>1520-5827</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNo90M1KAzEQB_Agiq3Vgy8guQheVvO1ye6xLPUDKhW0KF5CNsnWLemmJruH3nwFX9EncUurpxlmfgzDH4BzjK4xIvjGKYZYzok9AEOcEpSkGRGHYIgEo4lgnA7ASYxLhFBOWX4MBoRxkiHGh-B1bKIP67b2DXwKXtsYoa9gMSOwnzzXrtbK1a39-frG8N36bQ_nsW4W_bJZOJsUYRNb5eBbT4LawEfbfnhzCo4q5aI929cRmN9OXor7ZDq7eyjG00QRkbWJIKU2meFpRXlFmU1zZLARuCqZ5syqUmUEa5JpSnpDmE5zTkWmFceU2iqnI3C1u7sO_rOzsZWrOmrrnGqs76LEKWaMCsy29GJPu3JljVyHeqXCRv6F0YPLHVA6yqXvQtN_LjGS25Dlf8j0F1EqbKk</recordid><startdate>20140408</startdate><enddate>20140408</enddate><creator>Fujiyama, Shinjiro</creator><creator>Kamiya, Natsumi</creator><creator>Nishi, Koji</creator><creator>Yokomori, Yoshinobu</creator><general>American Chemical Society</general><scope>NPM</scope><scope>7X8</scope></search><sort><creationdate>20140408</creationdate><title>Adsorption Process of CO2 on Silicalite‑1 Zeolite Using Single-Crystal X‑ray Method</title><author>Fujiyama, Shinjiro ; Kamiya, Natsumi ; Nishi, Koji ; Yokomori, Yoshinobu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a278t-72bcd8d65f36f34e590d1d71fb4c64eaba821c28c3265f24c596378ca6133ef93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fujiyama, Shinjiro</creatorcontrib><creatorcontrib>Kamiya, Natsumi</creatorcontrib><creatorcontrib>Nishi, Koji</creatorcontrib><creatorcontrib>Yokomori, Yoshinobu</creatorcontrib><collection>PubMed</collection><collection>MEDLINE - Academic</collection><jtitle>Langmuir</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fujiyama, Shinjiro</au><au>Kamiya, Natsumi</au><au>Nishi, Koji</au><au>Yokomori, Yoshinobu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Adsorption Process of CO2 on Silicalite‑1 Zeolite Using Single-Crystal X‑ray Method</atitle><jtitle>Langmuir</jtitle><addtitle>Langmuir</addtitle><date>2014-04-08</date><risdate>2014</risdate><volume>30</volume><issue>13</issue><spage>3749</spage><epage>3753</epage><pages>3749-3753</pages><issn>0743-7463</issn><eissn>1520-5827</eissn><abstract>The process of CO2 adsorption on silicalite-1 zeolite (MFI-type) is revealed using a single-crystal X-ray method. The structure of CO2-silicalite-1 with a small amount of CO2 in the pore is determined, wherein most of CO2 molecules are located in the straight channel. It indicates the straight channel is the most stable sorption site based on the van der Waals interactions between the CO2 and the framework, and the CO2 molecules initially adsorb in the straight channel in the adsorption process. This is the first report to describe the structure of MFI-type zeolites with the adsorbate molecules occupying only the straight channel.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>24628046</pmid><doi>10.1021/la404962e</doi><tpages>5</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0743-7463
ispartof Langmuir, 2014-04, Vol.30 (13), p.3749-3753
issn 0743-7463
1520-5827
language eng
recordid cdi_proquest_miscellaneous_1514437149
source ACS Publications
title Adsorption Process of CO2 on Silicalite‑1 Zeolite Using Single-Crystal X‑ray Method
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-01T19%3A24%3A43IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Adsorption%20Process%20of%20CO2%20on%20Silicalite%E2%80%911%20Zeolite%20Using%20Single-Crystal%20X%E2%80%91ray%20Method&rft.jtitle=Langmuir&rft.au=Fujiyama,%20Shinjiro&rft.date=2014-04-08&rft.volume=30&rft.issue=13&rft.spage=3749&rft.epage=3753&rft.pages=3749-3753&rft.issn=0743-7463&rft.eissn=1520-5827&rft_id=info:doi/10.1021/la404962e&rft_dat=%3Cproquest_pubme%3E1514437149%3C/proquest_pubme%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1514437149&rft_id=info:pmid/24628046&rfr_iscdi=true