Alignment of Palladium Complexes into Columnar Liquid Crystals Driven by Peripheral Triphenylene Substituents

A new triphenylene-imine (ImH) and its ortho-palladated complexes (μ-X)2[Pd2Im2] (X = CH3COO–, Cl–, Br–), (μ-Cl)(μ-SC n H2n+1)[Pd2Im2] (n = 6, 12), [PdIm(acac)] [PdIm Cl(CNC6H4OC12H25)], [PdImCl(CNC6H3(OC12H25)2)], and [PdImCl(CNC6H2(OC12H25)3)] have been prepared. The free imine ligand is not a liq...

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Veröffentlicht in:	Inorganic chemistry 2014-04, Vol.53 (7), p.3449-3455
Hauptverfasser:	Tritto, Emiliano, Chico, Rubén, Sanz-Enguita, Gerardo, Folcia, César L, Ortega, Josu, Coco, Silverio, Espinet, Pablo
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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