The role of transition metals in the catalytic activity of Pt alloys: quantification of strain and ligand effects
The oxygen reduction reaction (ORR) activity as a function of thickness of the Pt shell on Pt-Ni alloy nanoparticles was established. We demonstrated that the effects of transition metals could only extend to a very thin Pt shell, which was 0.9-1.0 nm for Pt3Ni.
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Veröffentlicht in: | Chemical Communications 2014-01, Vol.50 (17), p.2173-2176 |
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creator | Shao, Minhua Odell, Jonathan H Peles, Amra Su, Dong |
description | The oxygen reduction reaction (ORR) activity as a function of thickness of the Pt shell on Pt-Ni alloy nanoparticles was established. We demonstrated that the effects of transition metals could only extend to a very thin Pt shell, which was 0.9-1.0 nm for Pt3Ni. |
doi_str_mv | 10.1039/c3cc47341d |
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source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | Alloys core-shell ENERGY PLANNING, POLICY, AND ECONOMY functional nanomaterials Ligands Nanoparticles oxygen reduction reaction Platinum Platinum base alloys Pt-Ni alloy Shells Strain Transition metals |
title | The role of transition metals in the catalytic activity of Pt alloys: quantification of strain and ligand effects |
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