The role of transition metals in the catalytic activity of Pt alloys: quantification of strain and ligand effects

The oxygen reduction reaction (ORR) activity as a function of thickness of the Pt shell on Pt-Ni alloy nanoparticles was established. We demonstrated that the effects of transition metals could only extend to a very thin Pt shell, which was 0.9-1.0 nm for Pt3Ni.

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Veröffentlicht in:Chemical Communications 2014-01, Vol.50 (17), p.2173-2176
Hauptverfasser: Shao, Minhua, Odell, Jonathan H, Peles, Amra, Su, Dong
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container_title Chemical Communications
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creator Shao, Minhua
Odell, Jonathan H
Peles, Amra
Su, Dong
description The oxygen reduction reaction (ORR) activity as a function of thickness of the Pt shell on Pt-Ni alloy nanoparticles was established. We demonstrated that the effects of transition metals could only extend to a very thin Pt shell, which was 0.9-1.0 nm for Pt3Ni.
doi_str_mv 10.1039/c3cc47341d
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Alloys
core-shell
ENERGY PLANNING, POLICY, AND ECONOMY
functional nanomaterials
Ligands
Nanoparticles
oxygen reduction reaction
Platinum
Platinum base alloys
Pt-Ni alloy
Shells
Strain
Transition metals
title The role of transition metals in the catalytic activity of Pt alloys: quantification of strain and ligand effects
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