Synthesis and upconversion luminescence in highly crystalline YOF:Yb3+/Er3+ and Yb3+/Tm3+ microboxes
► YOF:Ln3+ microboxes were successfully synthesized for the first time. ► The mixed NaNO3–KNO3 flux cooling method was adopted. ► Multicolor UC emissions of YOF:Yb3+/Er3+ microboxes can be achieved. ► The intense NIR emission in YOF:Yb3+/Tm3+ microboxes is obtained. Highly crystalline YOF:Ln3+ (Ln=Y...
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| Veröffentlicht in: | Optical materials 2013-04, Vol.35 (6), p.1283-1287 |
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| creator | Ding, Mingye Lu, Chunhua Cao, Linhai Ni, Yaru Xu, Zhongzi |
| description | ► YOF:Ln3+ microboxes were successfully synthesized for the first time. ► The mixed NaNO3–KNO3 flux cooling method was adopted. ► Multicolor UC emissions of YOF:Yb3+/Er3+ microboxes can be achieved. ► The intense NIR emission in YOF:Yb3+/Tm3+ microboxes is obtained.
Highly crystalline YOF:Ln3+ (Ln=Yb, Er, Tm) microboxes were successfully synthesized for the first time by using a mixed NaNO3–KNO3 flux cooling method at a holding temperature of 600°C for 2h in air. The results indicated that the as-obtained products belonged to tetragonal system and exhibited microboxes morphology with side lengths of 0.5–2μm. The upconversion luminescence properties of as-prepared YOF:Yb3+/Er3+ and YOF:Yb3+/Tm3+ were investigated in detail. Under 980nm laser diode (LD) excitation, the emission intensity and the corresponding luminescence colors of YOF:Yb3+/Er3+ and YOF:Yb3+/Tm3+ could be precisely adjusted by changing the doping concentration of Yb3+ ions. Furthermore, the paper also offers a new alternative in synthesizing such materials and opens the possibility to meet the increasing commercial demand. |
| doi_str_mv | 10.1016/j.optmat.2013.01.043 |
| format | Article |
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Highly crystalline YOF:Ln3+ (Ln=Yb, Er, Tm) microboxes were successfully synthesized for the first time by using a mixed NaNO3–KNO3 flux cooling method at a holding temperature of 600°C for 2h in air. The results indicated that the as-obtained products belonged to tetragonal system and exhibited microboxes morphology with side lengths of 0.5–2μm. The upconversion luminescence properties of as-prepared YOF:Yb3+/Er3+ and YOF:Yb3+/Tm3+ were investigated in detail. Under 980nm laser diode (LD) excitation, the emission intensity and the corresponding luminescence colors of YOF:Yb3+/Er3+ and YOF:Yb3+/Tm3+ could be precisely adjusted by changing the doping concentration of Yb3+ ions. Furthermore, the paper also offers a new alternative in synthesizing such materials and opens the possibility to meet the increasing commercial demand.</description><identifier>ISSN: 0925-3467</identifier><identifier>EISSN: 1873-1252</identifier><identifier>DOI: 10.1016/j.optmat.2013.01.043</identifier><language>eng</language><publisher>Oxford: Elsevier B.V</publisher><subject>Cooling ; Crystal structure ; Demand ; Doping ; Exact sciences and technology ; Flux cooling method ; Frequency conversion ; harmonic generation, including high-order harmonic generation ; Fundamental areas of phenomenology (including applications) ; Luminescence ; Microorganisms ; Nanostructure ; Nonlinear optics ; Optical materials ; Optics ; Oxyfluorides ; Physics ; Upconversion</subject><ispartof>Optical materials, 2013-04, Vol.35 (6), p.1283-1287</ispartof><rights>2013 Elsevier B.V.</rights><rights>2014 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c332t-493581743f6661fa519fa990c99b80783e703818fe908958da6092785b76acad3</citedby><cites>FETCH-LOGICAL-c332t-493581743f6661fa519fa990c99b80783e703818fe908958da6092785b76acad3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.optmat.2013.01.043$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>315,781,785,3551,27926,27927,45997</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27247832$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Ding, Mingye</creatorcontrib><creatorcontrib>Lu, Chunhua</creatorcontrib><creatorcontrib>Cao, Linhai</creatorcontrib><creatorcontrib>Ni, Yaru</creatorcontrib><creatorcontrib>Xu, Zhongzi</creatorcontrib><title>Synthesis and upconversion luminescence in highly crystalline YOF:Yb3+/Er3+ and Yb3+/Tm3+ microboxes</title><title>Optical materials</title><description>► YOF:Ln3+ microboxes were successfully synthesized for the first time. ► The mixed NaNO3–KNO3 flux cooling method was adopted. ► Multicolor UC emissions of YOF:Yb3+/Er3+ microboxes can be achieved. ► The intense NIR emission in YOF:Yb3+/Tm3+ microboxes is obtained.
Highly crystalline YOF:Ln3+ (Ln=Yb, Er, Tm) microboxes were successfully synthesized for the first time by using a mixed NaNO3–KNO3 flux cooling method at a holding temperature of 600°C for 2h in air. The results indicated that the as-obtained products belonged to tetragonal system and exhibited microboxes morphology with side lengths of 0.5–2μm. The upconversion luminescence properties of as-prepared YOF:Yb3+/Er3+ and YOF:Yb3+/Tm3+ were investigated in detail. Under 980nm laser diode (LD) excitation, the emission intensity and the corresponding luminescence colors of YOF:Yb3+/Er3+ and YOF:Yb3+/Tm3+ could be precisely adjusted by changing the doping concentration of Yb3+ ions. Furthermore, the paper also offers a new alternative in synthesizing such materials and opens the possibility to meet the increasing commercial demand.</description><subject>Cooling</subject><subject>Crystal structure</subject><subject>Demand</subject><subject>Doping</subject><subject>Exact sciences and technology</subject><subject>Flux cooling method</subject><subject>Frequency conversion ; harmonic generation, including high-order harmonic generation</subject><subject>Fundamental areas of phenomenology (including applications)</subject><subject>Luminescence</subject><subject>Microorganisms</subject><subject>Nanostructure</subject><subject>Nonlinear optics</subject><subject>Optical materials</subject><subject>Optics</subject><subject>Oxyfluorides</subject><subject>Physics</subject><subject>Upconversion</subject><issn>0925-3467</issn><issn>1873-1252</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNqFkElLAzEYhoMoWJd_4GEugiAzzb54EKTUBQQP6sFTSDMZmzKTqclU7L83tcWjnsJHnm95HwDOEKwQRHy8qPrl0JmhwhCRCqIKUrIHRkgKUiLM8D4YQYVZSSgXh-AopQWEEDPOR6B-Xodh7pJPhQl1sVraPny6mHwfinbV-eCSdcG6wodi7t_n7bqwcZ0G07b5r3h7ur16m5HL8TSSy58JP9VLl6vO29jP-i-XTsBBY9rkTnfvMXi9nb5M7svHp7uHyc1jaQnBQ0kVYRIJShrOOWoMQ6oxSkGr1ExCIYkTkEgkG6egVEzWhudYQrKZ4MaamhyDi-3cZew_Vi4NuvP5_LY1wfWrpBFDhErFKf4fJVRRJjKeUbpFc5yUomv0MvrOxLVGUG_864Xe-tcb_xoinf3ntvPdBpOsaZtogvXptxcLTHOkzSXXW85lM5_eRZ2s3yivfXR20HXv_170DcBTmxo</recordid><startdate>20130401</startdate><enddate>20130401</enddate><creator>Ding, Mingye</creator><creator>Lu, Chunhua</creator><creator>Cao, Linhai</creator><creator>Ni, Yaru</creator><creator>Xu, Zhongzi</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope></search><sort><creationdate>20130401</creationdate><title>Synthesis and upconversion luminescence in highly crystalline YOF:Yb3+/Er3+ and Yb3+/Tm3+ microboxes</title><author>Ding, Mingye ; Lu, Chunhua ; Cao, Linhai ; Ni, Yaru ; Xu, Zhongzi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c332t-493581743f6661fa519fa990c99b80783e703818fe908958da6092785b76acad3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Cooling</topic><topic>Crystal structure</topic><topic>Demand</topic><topic>Doping</topic><topic>Exact sciences and technology</topic><topic>Flux cooling method</topic><topic>Frequency conversion ; harmonic generation, including high-order harmonic generation</topic><topic>Fundamental areas of phenomenology (including applications)</topic><topic>Luminescence</topic><topic>Microorganisms</topic><topic>Nanostructure</topic><topic>Nonlinear optics</topic><topic>Optical materials</topic><topic>Optics</topic><topic>Oxyfluorides</topic><topic>Physics</topic><topic>Upconversion</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ding, Mingye</creatorcontrib><creatorcontrib>Lu, Chunhua</creatorcontrib><creatorcontrib>Cao, Linhai</creatorcontrib><creatorcontrib>Ni, Yaru</creatorcontrib><creatorcontrib>Xu, Zhongzi</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Optical materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ding, Mingye</au><au>Lu, Chunhua</au><au>Cao, Linhai</au><au>Ni, Yaru</au><au>Xu, Zhongzi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and upconversion luminescence in highly crystalline YOF:Yb3+/Er3+ and Yb3+/Tm3+ microboxes</atitle><jtitle>Optical materials</jtitle><date>2013-04-01</date><risdate>2013</risdate><volume>35</volume><issue>6</issue><spage>1283</spage><epage>1287</epage><pages>1283-1287</pages><issn>0925-3467</issn><eissn>1873-1252</eissn><abstract>► YOF:Ln3+ microboxes were successfully synthesized for the first time. ► The mixed NaNO3–KNO3 flux cooling method was adopted. ► Multicolor UC emissions of YOF:Yb3+/Er3+ microboxes can be achieved. ► The intense NIR emission in YOF:Yb3+/Tm3+ microboxes is obtained.
Highly crystalline YOF:Ln3+ (Ln=Yb, Er, Tm) microboxes were successfully synthesized for the first time by using a mixed NaNO3–KNO3 flux cooling method at a holding temperature of 600°C for 2h in air. The results indicated that the as-obtained products belonged to tetragonal system and exhibited microboxes morphology with side lengths of 0.5–2μm. The upconversion luminescence properties of as-prepared YOF:Yb3+/Er3+ and YOF:Yb3+/Tm3+ were investigated in detail. Under 980nm laser diode (LD) excitation, the emission intensity and the corresponding luminescence colors of YOF:Yb3+/Er3+ and YOF:Yb3+/Tm3+ could be precisely adjusted by changing the doping concentration of Yb3+ ions. Furthermore, the paper also offers a new alternative in synthesizing such materials and opens the possibility to meet the increasing commercial demand.</abstract><cop>Oxford</cop><pub>Elsevier B.V</pub><doi>10.1016/j.optmat.2013.01.043</doi><tpages>5</tpages></addata></record> |
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| subjects | Cooling Crystal structure Demand Doping Exact sciences and technology Flux cooling method Frequency conversion harmonic generation, including high-order harmonic generation Fundamental areas of phenomenology (including applications) Luminescence Microorganisms Nanostructure Nonlinear optics Optical materials Optics Oxyfluorides Physics Upconversion |
| title | Synthesis and upconversion luminescence in highly crystalline YOF:Yb3+/Er3+ and Yb3+/Tm3+ microboxes |
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