Study on 2.0μm fluorescence of Ho-doped water-free fluorotellurite glasses

•Ho-TZNF60 glasses were made by specially-designed PCDH technique.•Mid-IR emission spectra were deeply probed experimentally.•The longest fluorescence lifetime at 2.04μm is presented in Ho-TZNF60 glass.•1.00Ho-TZNF60 glass is ideal material to develop Mid-IR fiber lasers. Ho3+-doped water-free fluor...

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Veröffentlicht in:Optical materials 2013-10, Vol.35 (12), p.2573-2576
Hauptverfasser: He, Jianli, Zhan, Huan, Zhou, Zhiguang, Zhang, Aidong, Lin, Aoxiang
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container_issue 12
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container_title Optical materials
container_volume 35
creator He, Jianli
Zhan, Huan
Zhou, Zhiguang
Zhang, Aidong
Lin, Aoxiang
description •Ho-TZNF60 glasses were made by specially-designed PCDH technique.•Mid-IR emission spectra were deeply probed experimentally.•The longest fluorescence lifetime at 2.04μm is presented in Ho-TZNF60 glass.•1.00Ho-TZNF60 glass is ideal material to develop Mid-IR fiber lasers. Ho3+-doped water-free fluorotellurite glasses with composition of 60TeO2–30ZnF2–10NaF (mol%, TZNF60) were made by using specially-designed physical and chemical dehydration technique. 2.04μm fluorescence (Ho3+: 5I7→5I8) was observed experimentally and presented in this paper: A broad bandwidth of ∼149nm, large simulated emission cross-section of 7.2×10−21cm2, and the longest reported fluorescence lifetime of ∼10ms among all the reported Ho3+-doped oxide glasses. Thanks to the absence of OH groups and low phonon energy with the addition fluorides into tellurite oxide glasses, 1.00Ho-TZNF60 glass demonstrates the maximum figure of merit (σem×τf) of 7.13×10−27m2s, thus regarded as a promising optical material for the development of 2.0μm fiber lasers.
doi_str_mv 10.1016/j.optmat.2013.07.031
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subjects Cross sections
Emission
Exact sciences and technology
Fiber lasers
Fiber materials
Fluorescence
Fluorotellurite glasses
Fundamental areas of phenomenology (including applications)
Glass
Holmium
Lasers
Optical materials
Optics
Oxides
Physics
Simulation
title Study on 2.0μm fluorescence of Ho-doped water-free fluorotellurite glasses
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