GC models for separation optimization in pressure-tunable tandem capillary columns operated isothermally

In the previous part of this study, a significant improvement of the fundamental relationships that control GC resolution in a pressure‐tunable assembly operating in isothermal conditions inside a single oven was made. A theoretical approach for the correct choice of the working temperature was prop...

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Veröffentlicht in:Journal of separation science 2014-02, Vol.37 (4), p.412-418
Hauptverfasser: Veschetti, Enrico, Russo, Mario Vincenzo
Format: Artikel
Sprache:eng
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Zusammenfassung:In the previous part of this study, a significant improvement of the fundamental relationships that control GC resolution in a pressure‐tunable assembly operating in isothermal conditions inside a single oven was made. A theoretical approach for the correct choice of the working temperature was proposed for the first time. In this second part of our report, a new interfacing device has been proposed for a rapid and reliable alignment of the two columns at the midpoint junction. Moreover, the results of a series of experimental tests have confirmed the validity of the proposed mathematical models.
ISSN:1615-9306
1615-9314
DOI:10.1002/jssc.201301045