The effects of precipitant agent on structure and performance of LiNi1/3Co1/3Mn1/3O2 cathode material via a carbonate co-precipitation method
The layered structure LiNi1/3Co1/3Mn1/3O2 cathode material was successfully prepared via a carbonate co-precipitation method, followed by a calcination process at high temperature. The effects of precipitant agent on the crystal structure and morphology of the prepared materials have been studied by...
Gespeichert in:
| Veröffentlicht in: | Electrochimica acta 2012-12, Vol.85, p.99-103 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 103 |
|---|---|
| container_issue | |
| container_start_page | 99 |
| container_title | Electrochimica acta |
| container_volume | 85 |
| creator | Yin, Kui Fang, Weimao Zhong, Benhe Guo, Xiaodong Tang, Yan Nie, Xiang |
| description | The layered structure LiNi1/3Co1/3Mn1/3O2 cathode material was successfully prepared via a carbonate co-precipitation method, followed by a calcination process at high temperature. The effects of precipitant agent on the crystal structure and morphology of the prepared materials have been studied by XRD, SEM, and the electrochemical performance was investigated by galvanostatic charge–discharge test, cyclic voltammetry and electrochemical impedance spectroscopy. The carbonate precursors (Ni1/3Co1/3Mn1/3)CO3 synthesized by different precipitant agent show a single phase of hexagonal carbonate but a great difference in morphology. The well-crystallized product LiNi1/3Co1/3Mn1/3O2 with homogeneous mixing of transition metal ions were obtained via different precipitants. The material made form Na2CO3+NH4HCO3 precipitant shows the smallest particles size without agglomeration, the lowest polarization and the lowest interfacial resistance, which leads to excellent comprehensive electrochemical performance. |
| doi_str_mv | 10.1016/j.electacta.2012.06.064 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1513467359</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0013468612010390</els_id><sourcerecordid>1513467359</sourcerecordid><originalsourceid>FETCH-LOGICAL-c341t-9d75af44249bc18e3d0cee3b9045295ab380d6f3feb5d1a8953e9cc420763c3e3</originalsourceid><addsrcrecordid>eNqFUU1r3DAQFaWBbpP-hupS6MUbfds-hqVNC9vmkp6FLI8aLbblStpAf0T_c2fZsNfA8ATDe_NG8wj5yNmWM25uD1uYwFeHtRWMiy0zWOoN2fCulY3sdP-WbBjjslGmM-_I-1IOjLHWtGxD_j0-AYUQcEKhKdA1g49rrG6p1P0GxLTQUvPR12MG6paRrpBDyrNbPJwU-_gz8lu5Swg_FoQHQb2rT2kEOrsKObqJPkdHHbbzkBbsUZ-ai1ONaDHDSXFDroKbCnx4ea_Jr69fHnffmv3D_ffd3b7xUvHa9GOrXVBKqH7wvAM5Mg8gh54pLXrtBtmx0QQZYNAjd12vJfTeK4Gfll6CvCafz3PXnP4coVQ7x-JhmtwC6Vgs11wq00rdv06VRnPBtZBIbc9Un1MpGYJdc5xd_ms5s6es7MFesrKnrCwzWAqVn15MXPFuChmPG8tFLnAV02mDvLszD_A4zxGyLT4CBjFGvGa1Y4qvev0HUiyutw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1365121523</pqid></control><display><type>article</type><title>The effects of precipitant agent on structure and performance of LiNi1/3Co1/3Mn1/3O2 cathode material via a carbonate co-precipitation method</title><source>Elsevier ScienceDirect Journals</source><creator>Yin, Kui ; Fang, Weimao ; Zhong, Benhe ; Guo, Xiaodong ; Tang, Yan ; Nie, Xiang</creator><creatorcontrib>Yin, Kui ; Fang, Weimao ; Zhong, Benhe ; Guo, Xiaodong ; Tang, Yan ; Nie, Xiang</creatorcontrib><description>The layered structure LiNi1/3Co1/3Mn1/3O2 cathode material was successfully prepared via a carbonate co-precipitation method, followed by a calcination process at high temperature. The effects of precipitant agent on the crystal structure and morphology of the prepared materials have been studied by XRD, SEM, and the electrochemical performance was investigated by galvanostatic charge–discharge test, cyclic voltammetry and electrochemical impedance spectroscopy. The carbonate precursors (Ni1/3Co1/3Mn1/3)CO3 synthesized by different precipitant agent show a single phase of hexagonal carbonate but a great difference in morphology. The well-crystallized product LiNi1/3Co1/3Mn1/3O2 with homogeneous mixing of transition metal ions were obtained via different precipitants. The material made form Na2CO3+NH4HCO3 precipitant shows the smallest particles size without agglomeration, the lowest polarization and the lowest interfacial resistance, which leads to excellent comprehensive electrochemical performance.</description><identifier>ISSN: 0013-4686</identifier><identifier>EISSN: 1873-3859</identifier><identifier>DOI: 10.1016/j.electacta.2012.06.064</identifier><identifier>CODEN: ELCAAV</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Agglomeration ; Carbonate co-precipitation ; Carbonates ; Cathodes ; Chemistry ; Coprecipitation ; Crystal structure ; Electrochemistry ; Exact sciences and technology ; General and physical chemistry ; LiNi1/3Co1/3Mn1/3O2 ; Morphology ; Phase (cyclic) ; Precipitant agent ; Precursors ; Transition metals</subject><ispartof>Electrochimica acta, 2012-12, Vol.85, p.99-103</ispartof><rights>2012</rights><rights>2014 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c341t-9d75af44249bc18e3d0cee3b9045295ab380d6f3feb5d1a8953e9cc420763c3e3</citedby><cites>FETCH-LOGICAL-c341t-9d75af44249bc18e3d0cee3b9045295ab380d6f3feb5d1a8953e9cc420763c3e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0013468612010390$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=26736856$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Yin, Kui</creatorcontrib><creatorcontrib>Fang, Weimao</creatorcontrib><creatorcontrib>Zhong, Benhe</creatorcontrib><creatorcontrib>Guo, Xiaodong</creatorcontrib><creatorcontrib>Tang, Yan</creatorcontrib><creatorcontrib>Nie, Xiang</creatorcontrib><title>The effects of precipitant agent on structure and performance of LiNi1/3Co1/3Mn1/3O2 cathode material via a carbonate co-precipitation method</title><title>Electrochimica acta</title><description>The layered structure LiNi1/3Co1/3Mn1/3O2 cathode material was successfully prepared via a carbonate co-precipitation method, followed by a calcination process at high temperature. The effects of precipitant agent on the crystal structure and morphology of the prepared materials have been studied by XRD, SEM, and the electrochemical performance was investigated by galvanostatic charge–discharge test, cyclic voltammetry and electrochemical impedance spectroscopy. The carbonate precursors (Ni1/3Co1/3Mn1/3)CO3 synthesized by different precipitant agent show a single phase of hexagonal carbonate but a great difference in morphology. The well-crystallized product LiNi1/3Co1/3Mn1/3O2 with homogeneous mixing of transition metal ions were obtained via different precipitants. The material made form Na2CO3+NH4HCO3 precipitant shows the smallest particles size without agglomeration, the lowest polarization and the lowest interfacial resistance, which leads to excellent comprehensive electrochemical performance.</description><subject>Agglomeration</subject><subject>Carbonate co-precipitation</subject><subject>Carbonates</subject><subject>Cathodes</subject><subject>Chemistry</subject><subject>Coprecipitation</subject><subject>Crystal structure</subject><subject>Electrochemistry</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>LiNi1/3Co1/3Mn1/3O2</subject><subject>Morphology</subject><subject>Phase (cyclic)</subject><subject>Precipitant agent</subject><subject>Precursors</subject><subject>Transition metals</subject><issn>0013-4686</issn><issn>1873-3859</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNqFUU1r3DAQFaWBbpP-hupS6MUbfds-hqVNC9vmkp6FLI8aLbblStpAf0T_c2fZsNfA8ATDe_NG8wj5yNmWM25uD1uYwFeHtRWMiy0zWOoN2fCulY3sdP-WbBjjslGmM-_I-1IOjLHWtGxD_j0-AYUQcEKhKdA1g49rrG6p1P0GxLTQUvPR12MG6paRrpBDyrNbPJwU-_gz8lu5Swg_FoQHQb2rT2kEOrsKObqJPkdHHbbzkBbsUZ-ai1ONaDHDSXFDroKbCnx4ea_Jr69fHnffmv3D_ffd3b7xUvHa9GOrXVBKqH7wvAM5Mg8gh54pLXrtBtmx0QQZYNAjd12vJfTeK4Gfll6CvCafz3PXnP4coVQ7x-JhmtwC6Vgs11wq00rdv06VRnPBtZBIbc9Un1MpGYJdc5xd_ms5s6es7MFesrKnrCwzWAqVn15MXPFuChmPG8tFLnAV02mDvLszD_A4zxGyLT4CBjFGvGa1Y4qvev0HUiyutw</recordid><startdate>20121215</startdate><enddate>20121215</enddate><creator>Yin, Kui</creator><creator>Fang, Weimao</creator><creator>Zhong, Benhe</creator><creator>Guo, Xiaodong</creator><creator>Tang, Yan</creator><creator>Nie, Xiang</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7SP</scope></search><sort><creationdate>20121215</creationdate><title>The effects of precipitant agent on structure and performance of LiNi1/3Co1/3Mn1/3O2 cathode material via a carbonate co-precipitation method</title><author>Yin, Kui ; Fang, Weimao ; Zhong, Benhe ; Guo, Xiaodong ; Tang, Yan ; Nie, Xiang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c341t-9d75af44249bc18e3d0cee3b9045295ab380d6f3feb5d1a8953e9cc420763c3e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Agglomeration</topic><topic>Carbonate co-precipitation</topic><topic>Carbonates</topic><topic>Cathodes</topic><topic>Chemistry</topic><topic>Coprecipitation</topic><topic>Crystal structure</topic><topic>Electrochemistry</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>LiNi1/3Co1/3Mn1/3O2</topic><topic>Morphology</topic><topic>Phase (cyclic)</topic><topic>Precipitant agent</topic><topic>Precursors</topic><topic>Transition metals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yin, Kui</creatorcontrib><creatorcontrib>Fang, Weimao</creatorcontrib><creatorcontrib>Zhong, Benhe</creatorcontrib><creatorcontrib>Guo, Xiaodong</creatorcontrib><creatorcontrib>Tang, Yan</creatorcontrib><creatorcontrib>Nie, Xiang</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Electronics & Communications Abstracts</collection><jtitle>Electrochimica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yin, Kui</au><au>Fang, Weimao</au><au>Zhong, Benhe</au><au>Guo, Xiaodong</au><au>Tang, Yan</au><au>Nie, Xiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The effects of precipitant agent on structure and performance of LiNi1/3Co1/3Mn1/3O2 cathode material via a carbonate co-precipitation method</atitle><jtitle>Electrochimica acta</jtitle><date>2012-12-15</date><risdate>2012</risdate><volume>85</volume><spage>99</spage><epage>103</epage><pages>99-103</pages><issn>0013-4686</issn><eissn>1873-3859</eissn><coden>ELCAAV</coden><abstract>The layered structure LiNi1/3Co1/3Mn1/3O2 cathode material was successfully prepared via a carbonate co-precipitation method, followed by a calcination process at high temperature. The effects of precipitant agent on the crystal structure and morphology of the prepared materials have been studied by XRD, SEM, and the electrochemical performance was investigated by galvanostatic charge–discharge test, cyclic voltammetry and electrochemical impedance spectroscopy. The carbonate precursors (Ni1/3Co1/3Mn1/3)CO3 synthesized by different precipitant agent show a single phase of hexagonal carbonate but a great difference in morphology. The well-crystallized product LiNi1/3Co1/3Mn1/3O2 with homogeneous mixing of transition metal ions were obtained via different precipitants. The material made form Na2CO3+NH4HCO3 precipitant shows the smallest particles size without agglomeration, the lowest polarization and the lowest interfacial resistance, which leads to excellent comprehensive electrochemical performance.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.electacta.2012.06.064</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0013-4686 |
| ispartof | Electrochimica acta, 2012-12, Vol.85, p.99-103 |
| issn | 0013-4686 1873-3859 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1513467359 |
| source | Elsevier ScienceDirect Journals |
| subjects | Agglomeration Carbonate co-precipitation Carbonates Cathodes Chemistry Coprecipitation Crystal structure Electrochemistry Exact sciences and technology General and physical chemistry LiNi1/3Co1/3Mn1/3O2 Morphology Phase (cyclic) Precipitant agent Precursors Transition metals |
| title | The effects of precipitant agent on structure and performance of LiNi1/3Co1/3Mn1/3O2 cathode material via a carbonate co-precipitation method |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-01T15%3A04%3A04IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=The%20effects%20of%20precipitant%20agent%20on%20structure%20and%20performance%20of%20LiNi1/3Co1/3Mn1/3O2%20cathode%20material%20via%20a%20carbonate%20co-precipitation%20method&rft.jtitle=Electrochimica%20acta&rft.au=Yin,%20Kui&rft.date=2012-12-15&rft.volume=85&rft.spage=99&rft.epage=103&rft.pages=99-103&rft.issn=0013-4686&rft.eissn=1873-3859&rft.coden=ELCAAV&rft_id=info:doi/10.1016/j.electacta.2012.06.064&rft_dat=%3Cproquest_cross%3E1513467359%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1365121523&rft_id=info:pmid/&rft_els_id=S0013468612010390&rfr_iscdi=true |