Synthesis, spectral and photophysical properties of novel phthalocyanines bearing bulky phenantroxy moiety
The synthesis, characterization, spectral and photophysical properties of soluble 9-Phenanthroxy substituted oxo-titanium (IV), zinc, magnesium and nickel phthalocyanines (1a, 1b, 1c and 1d) are reported for the first time. The new compounds have been characterized by elemental analysis, FT-IR, 1H–N...
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| Veröffentlicht in: | Journal of luminescence 2013-02, Vol.134, p.483-490 |
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| container_title | Journal of luminescence |
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| creator | ERDOGMUS, Ali LÜTFI UGUR, Ahmet MEMISOGLU, Abdussamed ERDEN, Ibrahim |
| description | The synthesis, characterization, spectral and photophysical properties of soluble 9-Phenanthroxy substituted oxo-titanium (IV), zinc, magnesium and nickel phthalocyanines (1a, 1b, 1c and 1d) are reported for the first time. The new compounds have been characterized by elemental analysis, FT-IR, 1H–NMR spectroscopy, electronic spectroscopy and mass spectra. General trends are described for spectral, fluorescence properties and fluorescence quantum yields of these compounds in dimethylsulfoxide (DMSO) and toluene. All phthalocyanine complexes (1a to 1d) exhibited excellent solubility in organic solvents such as dichloromethane, chloroform, THF, toluene, DMF and DMSO.
► New metallophthalocyanines (1a–1d) were synthesized. ► These new phthalocyanine derivatives show the enhanced solubility in organic solvents. ► The spectral and photophysical properties of TiO(IV), zinc (II) and Mg(II) phthalocyanine (1a–1c) are investigated in DMSO and toluene. ► Ground state electronic absorption and fluorescence spectra. |
| doi_str_mv | 10.1016/j.jlumin.2012.07.041 |
| format | Article |
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► New metallophthalocyanines (1a–1d) were synthesized. ► These new phthalocyanine derivatives show the enhanced solubility in organic solvents. ► The spectral and photophysical properties of TiO(IV), zinc (II) and Mg(II) phthalocyanine (1a–1c) are investigated in DMSO and toluene. ► Ground state electronic absorption and fluorescence spectra.</description><identifier>ISSN: 0022-2313</identifier><identifier>EISSN: 1872-7883</identifier><identifier>DOI: 10.1016/j.jlumin.2012.07.041</identifier><identifier>CODEN: JLUMA8</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Atomic and molecular physics ; Electronics ; Exact sciences and technology ; Fluorescence ; Fluorescence and phosphorescence spectra ; Fluorescence and phosphorescence; radiationless transitions, quenching (intersystem crossing, internal conversion) ; Magnesium ; Molecular properties and interactions with photons ; Nickel ; Phthalocyanine ; Physics ; Spectra ; Spectroscopy ; Synthesis ; Titanium ; Toluene ; Zinc</subject><ispartof>Journal of luminescence, 2013-02, Vol.134, p.483-490</ispartof><rights>2012 Elsevier B.V.</rights><rights>2014 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c402t-d9b615d8fc134ab39ba1b3b24ddd49ab8daaef6c0ce770a4c5b47c5d680decfd3</citedby><cites>FETCH-LOGICAL-c402t-d9b615d8fc134ab39ba1b3b24ddd49ab8daaef6c0ce770a4c5b47c5d680decfd3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jlumin.2012.07.041$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3536,27903,27904,45974</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=26742442$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>ERDOGMUS, Ali</creatorcontrib><creatorcontrib>LÜTFI UGUR, Ahmet</creatorcontrib><creatorcontrib>MEMISOGLU, Abdussamed</creatorcontrib><creatorcontrib>ERDEN, Ibrahim</creatorcontrib><title>Synthesis, spectral and photophysical properties of novel phthalocyanines bearing bulky phenantroxy moiety</title><title>Journal of luminescence</title><description>The synthesis, characterization, spectral and photophysical properties of soluble 9-Phenanthroxy substituted oxo-titanium (IV), zinc, magnesium and nickel phthalocyanines (1a, 1b, 1c and 1d) are reported for the first time. The new compounds have been characterized by elemental analysis, FT-IR, 1H–NMR spectroscopy, electronic spectroscopy and mass spectra. General trends are described for spectral, fluorescence properties and fluorescence quantum yields of these compounds in dimethylsulfoxide (DMSO) and toluene. All phthalocyanine complexes (1a to 1d) exhibited excellent solubility in organic solvents such as dichloromethane, chloroform, THF, toluene, DMF and DMSO.
► New metallophthalocyanines (1a–1d) were synthesized. ► These new phthalocyanine derivatives show the enhanced solubility in organic solvents. ► The spectral and photophysical properties of TiO(IV), zinc (II) and Mg(II) phthalocyanine (1a–1c) are investigated in DMSO and toluene. ► Ground state electronic absorption and fluorescence spectra.</description><subject>Atomic and molecular physics</subject><subject>Electronics</subject><subject>Exact sciences and technology</subject><subject>Fluorescence</subject><subject>Fluorescence and phosphorescence spectra</subject><subject>Fluorescence and phosphorescence; radiationless transitions, quenching (intersystem crossing, internal conversion)</subject><subject>Magnesium</subject><subject>Molecular properties and interactions with photons</subject><subject>Nickel</subject><subject>Phthalocyanine</subject><subject>Physics</subject><subject>Spectra</subject><subject>Spectroscopy</subject><subject>Synthesis</subject><subject>Titanium</subject><subject>Toluene</subject><subject>Zinc</subject><issn>0022-2313</issn><issn>1872-7883</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp9kM1O3TAQhS3UStxC36CLbJBYNMF2nL8NUoUKrYTEgrK2xvakcZprB9sXkbev0UVddjXSzJlzZj5CvjBaMcraq7mal8PeuopTxivaVVSwE7JjfcfLru_rD2RHKeclr1l9Sj7FOFNK66EfdmR-3FyaMNr4tYgr6hRgKcCZYp188uu0RatzZw1-xZAsxsKPhfMvmHtTmmDxegNnXR4ohGDd70Idlj9bnqIDl4J_3Yq9t5i2c_JxhCXi5_d6Rp5uv_-6-VHeP9z9vPl2X2pBeSrNoFrWmH7UrBag6kEBU7XiwhgjBlC9AcCx1VRj11EQulGi041pe2pQj6Y-I5dH33z08wFjknsbNS4LOPSHKFmTjRvRMpql4ijVwccYcJRrsHsIm2RUvqGVszyilW9oJe1kRpvXLt4TIGY6YwCnbfy3y9tOcCF41l0fdZjffbEYZNQWnUZjQ0Ytjbf_D_oLvk2Vwg</recordid><startdate>20130201</startdate><enddate>20130201</enddate><creator>ERDOGMUS, Ali</creator><creator>LÜTFI UGUR, Ahmet</creator><creator>MEMISOGLU, Abdussamed</creator><creator>ERDEN, Ibrahim</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20130201</creationdate><title>Synthesis, spectral and photophysical properties of novel phthalocyanines bearing bulky phenantroxy moiety</title><author>ERDOGMUS, Ali ; LÜTFI UGUR, Ahmet ; MEMISOGLU, Abdussamed ; ERDEN, Ibrahim</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c402t-d9b615d8fc134ab39ba1b3b24ddd49ab8daaef6c0ce770a4c5b47c5d680decfd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Atomic and molecular physics</topic><topic>Electronics</topic><topic>Exact sciences and technology</topic><topic>Fluorescence</topic><topic>Fluorescence and phosphorescence spectra</topic><topic>Fluorescence and phosphorescence; radiationless transitions, quenching (intersystem crossing, internal conversion)</topic><topic>Magnesium</topic><topic>Molecular properties and interactions with photons</topic><topic>Nickel</topic><topic>Phthalocyanine</topic><topic>Physics</topic><topic>Spectra</topic><topic>Spectroscopy</topic><topic>Synthesis</topic><topic>Titanium</topic><topic>Toluene</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>ERDOGMUS, Ali</creatorcontrib><creatorcontrib>LÜTFI UGUR, Ahmet</creatorcontrib><creatorcontrib>MEMISOGLU, Abdussamed</creatorcontrib><creatorcontrib>ERDEN, Ibrahim</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of luminescence</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>ERDOGMUS, Ali</au><au>LÜTFI UGUR, Ahmet</au><au>MEMISOGLU, Abdussamed</au><au>ERDEN, Ibrahim</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, spectral and photophysical properties of novel phthalocyanines bearing bulky phenantroxy moiety</atitle><jtitle>Journal of luminescence</jtitle><date>2013-02-01</date><risdate>2013</risdate><volume>134</volume><spage>483</spage><epage>490</epage><pages>483-490</pages><issn>0022-2313</issn><eissn>1872-7883</eissn><coden>JLUMA8</coden><abstract>The synthesis, characterization, spectral and photophysical properties of soluble 9-Phenanthroxy substituted oxo-titanium (IV), zinc, magnesium and nickel phthalocyanines (1a, 1b, 1c and 1d) are reported for the first time. The new compounds have been characterized by elemental analysis, FT-IR, 1H–NMR spectroscopy, electronic spectroscopy and mass spectra. General trends are described for spectral, fluorescence properties and fluorescence quantum yields of these compounds in dimethylsulfoxide (DMSO) and toluene. All phthalocyanine complexes (1a to 1d) exhibited excellent solubility in organic solvents such as dichloromethane, chloroform, THF, toluene, DMF and DMSO.
► New metallophthalocyanines (1a–1d) were synthesized. ► These new phthalocyanine derivatives show the enhanced solubility in organic solvents. ► The spectral and photophysical properties of TiO(IV), zinc (II) and Mg(II) phthalocyanine (1a–1c) are investigated in DMSO and toluene. ► Ground state electronic absorption and fluorescence spectra.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jlumin.2012.07.041</doi><tpages>8</tpages></addata></record> |
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| subjects | Atomic and molecular physics Electronics Exact sciences and technology Fluorescence Fluorescence and phosphorescence spectra Fluorescence and phosphorescence radiationless transitions, quenching (intersystem crossing, internal conversion) Magnesium Molecular properties and interactions with photons Nickel Phthalocyanine Physics Spectra Spectroscopy Synthesis Titanium Toluene Zinc |
| title | Synthesis, spectral and photophysical properties of novel phthalocyanines bearing bulky phenantroxy moiety |
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