In situ preparation of CuS cathode with unique stability and high rate performance for lithium ion batteries

A simple approach, for the first time, was presented for in situ preparation of the CuS cathode. The obtained CuS cathodes were investigated by the measurements of X-ray diffraction pattern, scanning electronic microscopy, and electrochemical performance. The results indicate the CuS cathodes are co...

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Veröffentlicht in:Electrochimica acta 2012-10, Vol.80, p.264-268
Hauptverfasser: Wang, Yourong, Zhang, Xianwang, Chen, Peng, Liao, Hantao, Cheng, Siqing
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container_title Electrochimica acta
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Zhang, Xianwang
Chen, Peng
Liao, Hantao
Cheng, Siqing
description A simple approach, for the first time, was presented for in situ preparation of the CuS cathode. The obtained CuS cathodes were investigated by the measurements of X-ray diffraction pattern, scanning electronic microscopy, and electrochemical performance. The results indicate the CuS cathodes are composed of plenty of nano flakes, which construct a large 3-D net structure. Moreover, the CuS cathodes exhibit reversible capacity of 447.4, 414.1, 389.9 and 376.0mAhg−1 at 0.2C, 0.5C, 1C and 2C respectively and excellent cycle stability for more than 100 cycles. The possible mechanism of the unique stability of the CuS cathode was discussed.
doi_str_mv 10.1016/j.electacta.2012.07.004
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source Elsevier ScienceDirect Journals
subjects Applied sciences
Cathodes
CuS cathode
Cyclic voltammetry
Direct energy conversion and energy accumulation
Electrical engineering. Electrical power engineering
Electrical power engineering
Electrochemical conversion: primary and secondary batteries, fuel cells
Electrochemical properties
Electronics
Exact sciences and technology
Lithium ion battery
Lithium-ion batteries
Microscopy
Nanocomposites
Nanomaterials
Nanostructure
Scanning
Stability
Three dimensional
X-rays
title In situ preparation of CuS cathode with unique stability and high rate performance for lithium ion batteries
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