Evolution of Raman spectra in nitrogen doped graphene

We present systematical Raman studies of nitrogen doped graphene (NG). Defective graphene by Ar+ ion bombardment was also studied for comparison. It was found that the defects/nitrogen dopants in NG are not homogenous. Our results also suggest that the G peak position and I2D/IG ratio cannot be simp...

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Veröffentlicht in:Carbon (New York) 2013-09, Vol.61, p.57-62
Hauptverfasser: Zafar, Zainab, Ni, Zhen Hua, Wu, Xing, Shi, Zhi Xiang, Nan, Hai Yan, Bai, Jing, Sun, Li Tao
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container_end_page 62
container_issue
container_start_page 57
container_title Carbon (New York)
container_volume 61
creator Zafar, Zainab
Ni, Zhen Hua
Wu, Xing
Shi, Zhi Xiang
Nan, Hai Yan
Bai, Jing
Sun, Li Tao
description We present systematical Raman studies of nitrogen doped graphene (NG). Defective graphene by Ar+ ion bombardment was also studied for comparison. It was found that the defects/nitrogen dopants in NG are not homogenous. Our results also suggest that the G peak position and I2D/IG ratio cannot be simply used as fingerprint of doping concentration in NG. Both doping and compressive strain (as verified by transmission electron microscope) contribute to the shift of Raman peaks, while both doping and lattice defects contribute to the attenuation of 2D peak. Finally, the nature of defects in NG was probed and found that they are boundary defects. The detail analysis of the evolution of Raman spectra in NG would greatly help on the characterization and future application of this novel material.
doi_str_mv 10.1016/j.carbon.2013.04.065
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subjects Attenuation
Boundaries
Carbon
Cross-disciplinary physics: materials science
rheology
Defects
Doping
Evolution
Exact sciences and technology
Fullerenes and related materials
diamonds, graphite
Graphene
Materials science
Physics
Raman spectra
Specific materials
title Evolution of Raman spectra in nitrogen doped graphene
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