An electrochemical study of oxygen reduction in pyrrolidinium-based ionic liquids for lithium/oxygen batteries

The oxygen redox reaction (ORR) in pyrrolidinium-based ionic liquids (ILs) without and with lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) is investigated at different temperatures for lithium/oxygen battery application. Results obtained by cyclic voltammetry, rotating disk electrode, and ultra...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Electrochimica acta 2012-11, Vol.83, p.94-104
Hauptverfasser: Monaco, Simone, Arangio, Andrea Mario, Soavi, Francesca, Mastragostino, Marina, Paillard, Elie, Passerini, Stefano
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 104
container_issue
container_start_page 94
container_title Electrochimica acta
container_volume 83
creator Monaco, Simone
Arangio, Andrea Mario
Soavi, Francesca
Mastragostino, Marina
Paillard, Elie
Passerini, Stefano
description The oxygen redox reaction (ORR) in pyrrolidinium-based ionic liquids (ILs) without and with lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) is investigated at different temperatures for lithium/oxygen battery application. Results obtained by cyclic voltammetry, rotating disk electrode, and ultramicroelectrode potential steps at glassy carbon are reported and discussed in relation to the physical–chemical properties of the investigated ILs. Diffusion coefficients and solubility of oxygen in the ILs and tentative values of ORR heterogeneous rate constant in ILs without LiTFSI are reported. The effect of lithium salt on the ORR in IL is also discussed in view of lithium/oxygen battery application.
doi_str_mv 10.1016/j.electacta.2012.08.001
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1513446759</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0013468612012613</els_id><sourcerecordid>1365121705</sourcerecordid><originalsourceid>FETCH-LOGICAL-c411t-dd685f44aeb8b0e6056ee272a8205994444844a4ee0bd7dbb785690f6690effd3</originalsourceid><addsrcrecordid>eNqFUU2P2yAURFUrNU37G8qlUi_2Pmzz4WO0areVVupl94wwPLpEDmTBrpp_X9JEe12EeIiZN0_MEPKZQcuAiZt9izPaxdTddsC6FlQLwN6QDVOyb3rFx7dkU1_6ZhBKvCcfStkDgBQSNiTuIv3fn5N9wkOwZqZlWd2JJk_T39NvjDSjW-0SUqQh0uMp5zQHF2JYD81kCjpaoWDpHJ7X4Ar1Kdf78lTxm6vCZJYFc8DykbzzZi746Vq35PH7t4fbH839r7uft7v7xg6MLY1zQnE_DAYnNQEK4AKxk51RHfBxHOpSFR0QYXLSTZNUXIzgRT3Qe9dvydeL7jGn5xXLog-hWJxnEzGtRTPO-mEQko-vU3vBWcck8EqVF6rNqZSMXh9zOJh80gz0OQy91y9h6HMYGpQ-W78lX65DTKkW-2yiDeWlvRNcjfVvlbe78LCa8ydg1sUGjBZdyFVXuxRenfUPhGimDQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1365121705</pqid></control><display><type>article</type><title>An electrochemical study of oxygen reduction in pyrrolidinium-based ionic liquids for lithium/oxygen batteries</title><source>Elsevier ScienceDirect Journals</source><creator>Monaco, Simone ; Arangio, Andrea Mario ; Soavi, Francesca ; Mastragostino, Marina ; Paillard, Elie ; Passerini, Stefano</creator><creatorcontrib>Monaco, Simone ; Arangio, Andrea Mario ; Soavi, Francesca ; Mastragostino, Marina ; Paillard, Elie ; Passerini, Stefano</creatorcontrib><description>The oxygen redox reaction (ORR) in pyrrolidinium-based ionic liquids (ILs) without and with lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) is investigated at different temperatures for lithium/oxygen battery application. Results obtained by cyclic voltammetry, rotating disk electrode, and ultramicroelectrode potential steps at glassy carbon are reported and discussed in relation to the physical–chemical properties of the investigated ILs. Diffusion coefficients and solubility of oxygen in the ILs and tentative values of ORR heterogeneous rate constant in ILs without LiTFSI are reported. The effect of lithium salt on the ORR in IL is also discussed in view of lithium/oxygen battery application.</description><identifier>ISSN: 0013-4686</identifier><identifier>EISSN: 1873-3859</identifier><identifier>DOI: 10.1016/j.electacta.2012.08.001</identifier><identifier>CODEN: ELCAAV</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Applied sciences ; Chemistry ; Cyclic voltammetry ; Diffusion coefficient ; Direct energy conversion and energy accumulation ; Electric batteries ; Electrical engineering. Electrical power engineering ; Electrical power engineering ; Electrochemical conversion: primary and secondary batteries, fuel cells ; Electrochemistry ; Electrodes ; Exact sciences and technology ; General and physical chemistry ; Glassy carbon electrode ; Ionic liquids ; Lithium ; Lithium batteries ; Lithium/oxygen battery ; Oxygen redox reaction ; Pyrrolidinium-based ionic liquid ; Rotating disks ; Solubility</subject><ispartof>Electrochimica acta, 2012-11, Vol.83, p.94-104</ispartof><rights>2012 Elsevier Ltd</rights><rights>2014 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c411t-dd685f44aeb8b0e6056ee272a8205994444844a4ee0bd7dbb785690f6690effd3</citedby><cites>FETCH-LOGICAL-c411t-dd685f44aeb8b0e6056ee272a8205994444844a4ee0bd7dbb785690f6690effd3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0013468612012613$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3536,27903,27904,65309</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=26589820$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Monaco, Simone</creatorcontrib><creatorcontrib>Arangio, Andrea Mario</creatorcontrib><creatorcontrib>Soavi, Francesca</creatorcontrib><creatorcontrib>Mastragostino, Marina</creatorcontrib><creatorcontrib>Paillard, Elie</creatorcontrib><creatorcontrib>Passerini, Stefano</creatorcontrib><title>An electrochemical study of oxygen reduction in pyrrolidinium-based ionic liquids for lithium/oxygen batteries</title><title>Electrochimica acta</title><description>The oxygen redox reaction (ORR) in pyrrolidinium-based ionic liquids (ILs) without and with lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) is investigated at different temperatures for lithium/oxygen battery application. Results obtained by cyclic voltammetry, rotating disk electrode, and ultramicroelectrode potential steps at glassy carbon are reported and discussed in relation to the physical–chemical properties of the investigated ILs. Diffusion coefficients and solubility of oxygen in the ILs and tentative values of ORR heterogeneous rate constant in ILs without LiTFSI are reported. The effect of lithium salt on the ORR in IL is also discussed in view of lithium/oxygen battery application.</description><subject>Applied sciences</subject><subject>Chemistry</subject><subject>Cyclic voltammetry</subject><subject>Diffusion coefficient</subject><subject>Direct energy conversion and energy accumulation</subject><subject>Electric batteries</subject><subject>Electrical engineering. Electrical power engineering</subject><subject>Electrical power engineering</subject><subject>Electrochemical conversion: primary and secondary batteries, fuel cells</subject><subject>Electrochemistry</subject><subject>Electrodes</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Glassy carbon electrode</subject><subject>Ionic liquids</subject><subject>Lithium</subject><subject>Lithium batteries</subject><subject>Lithium/oxygen battery</subject><subject>Oxygen redox reaction</subject><subject>Pyrrolidinium-based ionic liquid</subject><subject>Rotating disks</subject><subject>Solubility</subject><issn>0013-4686</issn><issn>1873-3859</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNqFUU2P2yAURFUrNU37G8qlUi_2Pmzz4WO0areVVupl94wwPLpEDmTBrpp_X9JEe12EeIiZN0_MEPKZQcuAiZt9izPaxdTddsC6FlQLwN6QDVOyb3rFx7dkU1_6ZhBKvCcfStkDgBQSNiTuIv3fn5N9wkOwZqZlWd2JJk_T39NvjDSjW-0SUqQh0uMp5zQHF2JYD81kCjpaoWDpHJ7X4Ar1Kdf78lTxm6vCZJYFc8DykbzzZi746Vq35PH7t4fbH839r7uft7v7xg6MLY1zQnE_DAYnNQEK4AKxk51RHfBxHOpSFR0QYXLSTZNUXIzgRT3Qe9dvydeL7jGn5xXLog-hWJxnEzGtRTPO-mEQko-vU3vBWcck8EqVF6rNqZSMXh9zOJh80gz0OQy91y9h6HMYGpQ-W78lX65DTKkW-2yiDeWlvRNcjfVvlbe78LCa8ydg1sUGjBZdyFVXuxRenfUPhGimDQ</recordid><startdate>20121130</startdate><enddate>20121130</enddate><creator>Monaco, Simone</creator><creator>Arangio, Andrea Mario</creator><creator>Soavi, Francesca</creator><creator>Mastragostino, Marina</creator><creator>Paillard, Elie</creator><creator>Passerini, Stefano</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7SP</scope><scope>7TB</scope><scope>FR3</scope></search><sort><creationdate>20121130</creationdate><title>An electrochemical study of oxygen reduction in pyrrolidinium-based ionic liquids for lithium/oxygen batteries</title><author>Monaco, Simone ; Arangio, Andrea Mario ; Soavi, Francesca ; Mastragostino, Marina ; Paillard, Elie ; Passerini, Stefano</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c411t-dd685f44aeb8b0e6056ee272a8205994444844a4ee0bd7dbb785690f6690effd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Applied sciences</topic><topic>Chemistry</topic><topic>Cyclic voltammetry</topic><topic>Diffusion coefficient</topic><topic>Direct energy conversion and energy accumulation</topic><topic>Electric batteries</topic><topic>Electrical engineering. Electrical power engineering</topic><topic>Electrical power engineering</topic><topic>Electrochemical conversion: primary and secondary batteries, fuel cells</topic><topic>Electrochemistry</topic><topic>Electrodes</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Glassy carbon electrode</topic><topic>Ionic liquids</topic><topic>Lithium</topic><topic>Lithium batteries</topic><topic>Lithium/oxygen battery</topic><topic>Oxygen redox reaction</topic><topic>Pyrrolidinium-based ionic liquid</topic><topic>Rotating disks</topic><topic>Solubility</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Monaco, Simone</creatorcontrib><creatorcontrib>Arangio, Andrea Mario</creatorcontrib><creatorcontrib>Soavi, Francesca</creatorcontrib><creatorcontrib>Mastragostino, Marina</creatorcontrib><creatorcontrib>Paillard, Elie</creatorcontrib><creatorcontrib>Passerini, Stefano</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Electronics &amp; Communications Abstracts</collection><collection>Mechanical &amp; Transportation Engineering Abstracts</collection><collection>Engineering Research Database</collection><jtitle>Electrochimica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Monaco, Simone</au><au>Arangio, Andrea Mario</au><au>Soavi, Francesca</au><au>Mastragostino, Marina</au><au>Paillard, Elie</au><au>Passerini, Stefano</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An electrochemical study of oxygen reduction in pyrrolidinium-based ionic liquids for lithium/oxygen batteries</atitle><jtitle>Electrochimica acta</jtitle><date>2012-11-30</date><risdate>2012</risdate><volume>83</volume><spage>94</spage><epage>104</epage><pages>94-104</pages><issn>0013-4686</issn><eissn>1873-3859</eissn><coden>ELCAAV</coden><abstract>The oxygen redox reaction (ORR) in pyrrolidinium-based ionic liquids (ILs) without and with lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) is investigated at different temperatures for lithium/oxygen battery application. Results obtained by cyclic voltammetry, rotating disk electrode, and ultramicroelectrode potential steps at glassy carbon are reported and discussed in relation to the physical–chemical properties of the investigated ILs. Diffusion coefficients and solubility of oxygen in the ILs and tentative values of ORR heterogeneous rate constant in ILs without LiTFSI are reported. The effect of lithium salt on the ORR in IL is also discussed in view of lithium/oxygen battery application.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.electacta.2012.08.001</doi><tpages>11</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0013-4686
ispartof Electrochimica acta, 2012-11, Vol.83, p.94-104
issn 0013-4686
1873-3859
language eng
recordid cdi_proquest_miscellaneous_1513446759
source Elsevier ScienceDirect Journals
subjects Applied sciences
Chemistry
Cyclic voltammetry
Diffusion coefficient
Direct energy conversion and energy accumulation
Electric batteries
Electrical engineering. Electrical power engineering
Electrical power engineering
Electrochemical conversion: primary and secondary batteries, fuel cells
Electrochemistry
Electrodes
Exact sciences and technology
General and physical chemistry
Glassy carbon electrode
Ionic liquids
Lithium
Lithium batteries
Lithium/oxygen battery
Oxygen redox reaction
Pyrrolidinium-based ionic liquid
Rotating disks
Solubility
title An electrochemical study of oxygen reduction in pyrrolidinium-based ionic liquids for lithium/oxygen batteries
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-26T08%3A42%3A59IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=An%20electrochemical%20study%20of%20oxygen%20reduction%20in%20pyrrolidinium-based%20ionic%20liquids%20for%20lithium/oxygen%20batteries&rft.jtitle=Electrochimica%20acta&rft.au=Monaco,%20Simone&rft.date=2012-11-30&rft.volume=83&rft.spage=94&rft.epage=104&rft.pages=94-104&rft.issn=0013-4686&rft.eissn=1873-3859&rft.coden=ELCAAV&rft_id=info:doi/10.1016/j.electacta.2012.08.001&rft_dat=%3Cproquest_cross%3E1365121705%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1365121705&rft_id=info:pmid/&rft_els_id=S0013468612012613&rfr_iscdi=true