An electrochemical study of oxygen reduction in pyrrolidinium-based ionic liquids for lithium/oxygen batteries
The oxygen redox reaction (ORR) in pyrrolidinium-based ionic liquids (ILs) without and with lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) is investigated at different temperatures for lithium/oxygen battery application. Results obtained by cyclic voltammetry, rotating disk electrode, and ultra...
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Veröffentlicht in: | Electrochimica acta 2012-11, Vol.83, p.94-104 |
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description | The oxygen redox reaction (ORR) in pyrrolidinium-based ionic liquids (ILs) without and with lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) is investigated at different temperatures for lithium/oxygen battery application. Results obtained by cyclic voltammetry, rotating disk electrode, and ultramicroelectrode potential steps at glassy carbon are reported and discussed in relation to the physical–chemical properties of the investigated ILs. Diffusion coefficients and solubility of oxygen in the ILs and tentative values of ORR heterogeneous rate constant in ILs without LiTFSI are reported. The effect of lithium salt on the ORR in IL is also discussed in view of lithium/oxygen battery application. |
doi_str_mv | 10.1016/j.electacta.2012.08.001 |
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Results obtained by cyclic voltammetry, rotating disk electrode, and ultramicroelectrode potential steps at glassy carbon are reported and discussed in relation to the physical–chemical properties of the investigated ILs. Diffusion coefficients and solubility of oxygen in the ILs and tentative values of ORR heterogeneous rate constant in ILs without LiTFSI are reported. The effect of lithium salt on the ORR in IL is also discussed in view of lithium/oxygen battery application.</description><identifier>ISSN: 0013-4686</identifier><identifier>EISSN: 1873-3859</identifier><identifier>DOI: 10.1016/j.electacta.2012.08.001</identifier><identifier>CODEN: ELCAAV</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Applied sciences ; Chemistry ; Cyclic voltammetry ; Diffusion coefficient ; Direct energy conversion and energy accumulation ; Electric batteries ; Electrical engineering. 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subjects | Applied sciences Chemistry Cyclic voltammetry Diffusion coefficient Direct energy conversion and energy accumulation Electric batteries Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Electrochemistry Electrodes Exact sciences and technology General and physical chemistry Glassy carbon electrode Ionic liquids Lithium Lithium batteries Lithium/oxygen battery Oxygen redox reaction Pyrrolidinium-based ionic liquid Rotating disks Solubility |
title | An electrochemical study of oxygen reduction in pyrrolidinium-based ionic liquids for lithium/oxygen batteries |
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