Formation of a dense and continuous Al2O3 layer in nano thermal barrier coating systems for the suppression of spinel growth on the Al2O3 oxide scale during oxidation

•Formation of a dense and continues Al2O3 (TGO) layer on the nanostructured NiCrAlY.•Formation of a discontinues and thicker Al2O3 (TGO) layer on the normal NiCrAlY.•Bi-layered TGO thickness in normal TBC system was much higher.•Continues and thin Al2O3 layer on the nano BC would act as an infiltrat...

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Veröffentlicht in:Journal of alloys and compounds 2013-09, Vol.571, p.205-220
Hauptverfasser: Daroonparvar, Mohammadreza, Yajid, Muhamad Azizi Mat, Yusof, Noordin Mohd, Hussain, Mohammad Sakhawat, Rad, Hamid Reza Bakhsheshi
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container_issue
container_start_page 205
container_title Journal of alloys and compounds
container_volume 571
creator Daroonparvar, Mohammadreza
Yajid, Muhamad Azizi Mat
Yusof, Noordin Mohd
Hussain, Mohammad Sakhawat
Rad, Hamid Reza Bakhsheshi
description •Formation of a dense and continues Al2O3 (TGO) layer on the nanostructured NiCrAlY.•Formation of a discontinues and thicker Al2O3 (TGO) layer on the normal NiCrAlY.•Bi-layered TGO thickness in normal TBC system was much higher.•Continues and thin Al2O3 layer on the nano BC would act as an infiltration barrier.•Bi-layered TGO thickness can predict TBC durability during cyclic oxidation. A continuous and thin Al2O3 layer would act as an infiltration barrier to diminish the growth of spinels in thermal barrier coating systems. Therefore, isothermal oxidation of normal NiCrAlY/YSZ, nano NiCrAlY/YSZ and nano NiCrAlY/YSZ/nano Al2O3 coatings was investigated at 1000°C. These samples were then subjected to thermal cycles at 1150°C. The microstructural characterisation showed that the spinel growth in the nano NiCrAlY/YSZ/nano Al2O3 coating was much lower than the other coatings. This observation can be related to the formation of a fully continuous Al2O3 layer on the nano NiCrAlY coating during pre-oxidation at 1000°C and also to the presence of a nano Al2O3 layer over the YSZ coating.
doi_str_mv 10.1016/j.jallcom.2013.03.168
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A continuous and thin Al2O3 layer would act as an infiltration barrier to diminish the growth of spinels in thermal barrier coating systems. Therefore, isothermal oxidation of normal NiCrAlY/YSZ, nano NiCrAlY/YSZ and nano NiCrAlY/YSZ/nano Al2O3 coatings was investigated at 1000°C. These samples were then subjected to thermal cycles at 1150°C. The microstructural characterisation showed that the spinel growth in the nano NiCrAlY/YSZ/nano Al2O3 coating was much lower than the other coatings. 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subjects Aluminum oxide
Coatings
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Diffusion
Diffusion in solids
Exact sciences and technology
Intermetallic compounds
Ion and electron beam-assisted deposition
ion plating
Materials science
Methods of crystal growth
physics of crystal growth
Methods of deposition of films and coatings
film growth and epitaxy
Nanostructure
Nanostructures
Oxidation
Oxides
Physics
Plasma deposition
Spinel
Theory and models of crystal growth
physics of crystal growth, crystal morphology and orientation
Thermal barrier coatings
Transport properties of condensed matter (nonelectronic)
Yttria stabilized zirconia
title Formation of a dense and continuous Al2O3 layer in nano thermal barrier coating systems for the suppression of spinel growth on the Al2O3 oxide scale during oxidation
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