New double molybdate Na9Fe(MoO4)6: Synthesis, structure, properties
A new double molybdate Na9Fe(MoO4)6 was synthesized using solid state reactions and studied with X-ray powder diffraction, second harmonic generation (SHG) technique, differential scanning calorimetry, X-ray fluorescence analysis, Mössbauer and dielectric impedance spectroscopy. Single crystals of N...
Gespeichert in:
| Veröffentlicht in: | Journal of solid state chemistry 2013-09, Vol.205, p.149-153 |
|---|---|
| Hauptverfasser: | , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 153 |
|---|---|
| container_issue | |
| container_start_page | 149 |
| container_title | Journal of solid state chemistry |
| container_volume | 205 |
| creator | Savina, Aleksandra A. Solodovnikov, Sergey F. Basovich, Olga M. Solodovnikova, Zoya A. Belov, Dmitry A. Pokholok, Konstantin V. Gudkova, Irina A. Stefanovich, Sergey Yu Lazoryak, Bogdan I. Khaikina, Elena G. |
| description | A new double molybdate Na9Fe(MoO4)6 was synthesized using solid state reactions and studied with X-ray powder diffraction, second harmonic generation (SHG) technique, differential scanning calorimetry, X-ray fluorescence analysis, Mössbauer and dielectric impedance spectroscopy. Single crystals of Na9Fe(MoO4)6 were obtained and its structure was solved (the space group R3¯, a=14.8264(2), c=19.2402(3)Å, V=3662.79(9)Å3, Z=6, R=0.0132). The structure is related to that of sodium ion conductor II-Na3Fe2(AsO4)3. The basic structure units are polyhedral clusters composed of central FeО6 octahedron sharing edges with three Na(1)О6 octahedra. The clusters share common vertices with bridging МоО4 tetrahedra to form an open 3D framework where the cavities are occupied by Na(2) and Na(3) atoms. The compound melts incongruently at 904.7±0.2K. Arrhenius type temperature dependence of electric conductivity σ has been registered in solid state (σ=6.8×10−2Sсm−1 at 800K), thus allowing considering Na9Fe(MoO4)6 as a new sodium ion conductor.
A new double molybdate Na9Fe(MoO4)6 was synthesized and structurally characterized, its physicochemical properties were studied. [Display omitted]
•A new compound Na9Fe(MoO4)6 was synthesized as ceramics and single crystals.•Na9Fe(MoO4)6 structure is related to that of sodium-ion conductor II-Na3Fe2(AsO4)3.•Physicochemical properties of the compound were studied.•Arrhenius plot for conductivity showed 6.8×10−2Scm−1 at 800K, Ea~0.8eV.•Thus, Na9Fe(MoO4)6 may be considered as a new sodium ion conductor. |
| doi_str_mv | 10.1016/j.jssc.2013.07.007 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1513436263</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0022459613003307</els_id><sourcerecordid>1513436263</sourcerecordid><originalsourceid>FETCH-LOGICAL-c248t-1859d1c2a143876e6ec8cc1fa640c51f130bbd52c16a12cd6744ce11fbe82a473</originalsourceid><addsrcrecordid>eNp9kDFPwzAQhS0EEqXwB5gyFokEn-M4CWJBFQWk0g6AxGY5l4twlTbFdkD996QqM9Nb3nen9zF2CTwBDupmlay8x0RwSBOeJ5znR2wEvMziXKiPYzbiXIhYZqU6ZWferzgHyAo5YtMF_UR111ctReuu3VW1CRQtTDmjyUu3lFfqNnrdbcIneeuvIx9cj6F3dB1tXbclFyz5c3bSmNbTxV-O2fvs4W36FM-Xj8_T-3mMQhYhhiIra0BhQKZFrkgRFojQGCU5ZtBAyquqzgSCMiCwVrmUSABNRYUwMk_HbHK4O7z-6skHvbYeqW3Nhrrea8gglakSKh2q4lBF13nvqNFbZ9fG7TRwvTemV3pvTO-NaZ7rwdgA3R0gGkZ8W3Lao6UNUm0dYdB1Z__DfwFKF3OK</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1513436263</pqid></control><display><type>article</type><title>New double molybdate Na9Fe(MoO4)6: Synthesis, structure, properties</title><source>Access via ScienceDirect (Elsevier)</source><creator>Savina, Aleksandra A. ; Solodovnikov, Sergey F. ; Basovich, Olga M. ; Solodovnikova, Zoya A. ; Belov, Dmitry A. ; Pokholok, Konstantin V. ; Gudkova, Irina A. ; Stefanovich, Sergey Yu ; Lazoryak, Bogdan I. ; Khaikina, Elena G.</creator><creatorcontrib>Savina, Aleksandra A. ; Solodovnikov, Sergey F. ; Basovich, Olga M. ; Solodovnikova, Zoya A. ; Belov, Dmitry A. ; Pokholok, Konstantin V. ; Gudkova, Irina A. ; Stefanovich, Sergey Yu ; Lazoryak, Bogdan I. ; Khaikina, Elena G.</creatorcontrib><description>A new double molybdate Na9Fe(MoO4)6 was synthesized using solid state reactions and studied with X-ray powder diffraction, second harmonic generation (SHG) technique, differential scanning calorimetry, X-ray fluorescence analysis, Mössbauer and dielectric impedance spectroscopy. Single crystals of Na9Fe(MoO4)6 were obtained and its structure was solved (the space group R3¯, a=14.8264(2), c=19.2402(3)Å, V=3662.79(9)Å3, Z=6, R=0.0132). The structure is related to that of sodium ion conductor II-Na3Fe2(AsO4)3. The basic structure units are polyhedral clusters composed of central FeО6 octahedron sharing edges with three Na(1)О6 octahedra. The clusters share common vertices with bridging МоО4 tetrahedra to form an open 3D framework where the cavities are occupied by Na(2) and Na(3) atoms. The compound melts incongruently at 904.7±0.2K. Arrhenius type temperature dependence of electric conductivity σ has been registered in solid state (σ=6.8×10−2Sсm−1 at 800K), thus allowing considering Na9Fe(MoO4)6 as a new sodium ion conductor.
A new double molybdate Na9Fe(MoO4)6 was synthesized and structurally characterized, its physicochemical properties were studied. [Display omitted]
•A new compound Na9Fe(MoO4)6 was synthesized as ceramics and single crystals.•Na9Fe(MoO4)6 structure is related to that of sodium-ion conductor II-Na3Fe2(AsO4)3.•Physicochemical properties of the compound were studied.•Arrhenius plot for conductivity showed 6.8×10−2Scm−1 at 800K, Ea~0.8eV.•Thus, Na9Fe(MoO4)6 may be considered as a new sodium ion conductor.</description><identifier>ISSN: 0022-4596</identifier><identifier>EISSN: 1095-726X</identifier><identifier>DOI: 10.1016/j.jssc.2013.07.007</identifier><language>eng</language><publisher>Elsevier Inc</publisher><subject>Clusters ; Conductors (devices) ; Crystal structure ; Electrical conductivity ; Molybdates ; Sodium ; Sodium–iron molybdate ; Solid state ; Solid-state electrolyte ; Temperature dependence ; Three dimensional</subject><ispartof>Journal of solid state chemistry, 2013-09, Vol.205, p.149-153</ispartof><rights>2013 Elsevier Inc.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c248t-1859d1c2a143876e6ec8cc1fa640c51f130bbd52c16a12cd6744ce11fbe82a473</citedby><cites>FETCH-LOGICAL-c248t-1859d1c2a143876e6ec8cc1fa640c51f130bbd52c16a12cd6744ce11fbe82a473</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jssc.2013.07.007$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Savina, Aleksandra A.</creatorcontrib><creatorcontrib>Solodovnikov, Sergey F.</creatorcontrib><creatorcontrib>Basovich, Olga M.</creatorcontrib><creatorcontrib>Solodovnikova, Zoya A.</creatorcontrib><creatorcontrib>Belov, Dmitry A.</creatorcontrib><creatorcontrib>Pokholok, Konstantin V.</creatorcontrib><creatorcontrib>Gudkova, Irina A.</creatorcontrib><creatorcontrib>Stefanovich, Sergey Yu</creatorcontrib><creatorcontrib>Lazoryak, Bogdan I.</creatorcontrib><creatorcontrib>Khaikina, Elena G.</creatorcontrib><title>New double molybdate Na9Fe(MoO4)6: Synthesis, structure, properties</title><title>Journal of solid state chemistry</title><description>A new double molybdate Na9Fe(MoO4)6 was synthesized using solid state reactions and studied with X-ray powder diffraction, second harmonic generation (SHG) technique, differential scanning calorimetry, X-ray fluorescence analysis, Mössbauer and dielectric impedance spectroscopy. Single crystals of Na9Fe(MoO4)6 were obtained and its structure was solved (the space group R3¯, a=14.8264(2), c=19.2402(3)Å, V=3662.79(9)Å3, Z=6, R=0.0132). The structure is related to that of sodium ion conductor II-Na3Fe2(AsO4)3. The basic structure units are polyhedral clusters composed of central FeО6 octahedron sharing edges with three Na(1)О6 octahedra. The clusters share common vertices with bridging МоО4 tetrahedra to form an open 3D framework where the cavities are occupied by Na(2) and Na(3) atoms. The compound melts incongruently at 904.7±0.2K. Arrhenius type temperature dependence of electric conductivity σ has been registered in solid state (σ=6.8×10−2Sсm−1 at 800K), thus allowing considering Na9Fe(MoO4)6 as a new sodium ion conductor.
A new double molybdate Na9Fe(MoO4)6 was synthesized and structurally characterized, its physicochemical properties were studied. [Display omitted]
•A new compound Na9Fe(MoO4)6 was synthesized as ceramics and single crystals.•Na9Fe(MoO4)6 structure is related to that of sodium-ion conductor II-Na3Fe2(AsO4)3.•Physicochemical properties of the compound were studied.•Arrhenius plot for conductivity showed 6.8×10−2Scm−1 at 800K, Ea~0.8eV.•Thus, Na9Fe(MoO4)6 may be considered as a new sodium ion conductor.</description><subject>Clusters</subject><subject>Conductors (devices)</subject><subject>Crystal structure</subject><subject>Electrical conductivity</subject><subject>Molybdates</subject><subject>Sodium</subject><subject>Sodium–iron molybdate</subject><subject>Solid state</subject><subject>Solid-state electrolyte</subject><subject>Temperature dependence</subject><subject>Three dimensional</subject><issn>0022-4596</issn><issn>1095-726X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp9kDFPwzAQhS0EEqXwB5gyFokEn-M4CWJBFQWk0g6AxGY5l4twlTbFdkD996QqM9Nb3nen9zF2CTwBDupmlay8x0RwSBOeJ5znR2wEvMziXKiPYzbiXIhYZqU6ZWferzgHyAo5YtMF_UR111ctReuu3VW1CRQtTDmjyUu3lFfqNnrdbcIneeuvIx9cj6F3dB1tXbclFyz5c3bSmNbTxV-O2fvs4W36FM-Xj8_T-3mMQhYhhiIra0BhQKZFrkgRFojQGCU5ZtBAyquqzgSCMiCwVrmUSABNRYUwMk_HbHK4O7z-6skHvbYeqW3Nhrrea8gglakSKh2q4lBF13nvqNFbZ9fG7TRwvTemV3pvTO-NaZ7rwdgA3R0gGkZ8W3Lao6UNUm0dYdB1Z__DfwFKF3OK</recordid><startdate>20130901</startdate><enddate>20130901</enddate><creator>Savina, Aleksandra A.</creator><creator>Solodovnikov, Sergey F.</creator><creator>Basovich, Olga M.</creator><creator>Solodovnikova, Zoya A.</creator><creator>Belov, Dmitry A.</creator><creator>Pokholok, Konstantin V.</creator><creator>Gudkova, Irina A.</creator><creator>Stefanovich, Sergey Yu</creator><creator>Lazoryak, Bogdan I.</creator><creator>Khaikina, Elena G.</creator><general>Elsevier Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20130901</creationdate><title>New double molybdate Na9Fe(MoO4)6: Synthesis, structure, properties</title><author>Savina, Aleksandra A. ; Solodovnikov, Sergey F. ; Basovich, Olga M. ; Solodovnikova, Zoya A. ; Belov, Dmitry A. ; Pokholok, Konstantin V. ; Gudkova, Irina A. ; Stefanovich, Sergey Yu ; Lazoryak, Bogdan I. ; Khaikina, Elena G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c248t-1859d1c2a143876e6ec8cc1fa640c51f130bbd52c16a12cd6744ce11fbe82a473</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Clusters</topic><topic>Conductors (devices)</topic><topic>Crystal structure</topic><topic>Electrical conductivity</topic><topic>Molybdates</topic><topic>Sodium</topic><topic>Sodium–iron molybdate</topic><topic>Solid state</topic><topic>Solid-state electrolyte</topic><topic>Temperature dependence</topic><topic>Three dimensional</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Savina, Aleksandra A.</creatorcontrib><creatorcontrib>Solodovnikov, Sergey F.</creatorcontrib><creatorcontrib>Basovich, Olga M.</creatorcontrib><creatorcontrib>Solodovnikova, Zoya A.</creatorcontrib><creatorcontrib>Belov, Dmitry A.</creatorcontrib><creatorcontrib>Pokholok, Konstantin V.</creatorcontrib><creatorcontrib>Gudkova, Irina A.</creatorcontrib><creatorcontrib>Stefanovich, Sergey Yu</creatorcontrib><creatorcontrib>Lazoryak, Bogdan I.</creatorcontrib><creatorcontrib>Khaikina, Elena G.</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of solid state chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Savina, Aleksandra A.</au><au>Solodovnikov, Sergey F.</au><au>Basovich, Olga M.</au><au>Solodovnikova, Zoya A.</au><au>Belov, Dmitry A.</au><au>Pokholok, Konstantin V.</au><au>Gudkova, Irina A.</au><au>Stefanovich, Sergey Yu</au><au>Lazoryak, Bogdan I.</au><au>Khaikina, Elena G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>New double molybdate Na9Fe(MoO4)6: Synthesis, structure, properties</atitle><jtitle>Journal of solid state chemistry</jtitle><date>2013-09-01</date><risdate>2013</risdate><volume>205</volume><spage>149</spage><epage>153</epage><pages>149-153</pages><issn>0022-4596</issn><eissn>1095-726X</eissn><abstract>A new double molybdate Na9Fe(MoO4)6 was synthesized using solid state reactions and studied with X-ray powder diffraction, second harmonic generation (SHG) technique, differential scanning calorimetry, X-ray fluorescence analysis, Mössbauer and dielectric impedance spectroscopy. Single crystals of Na9Fe(MoO4)6 were obtained and its structure was solved (the space group R3¯, a=14.8264(2), c=19.2402(3)Å, V=3662.79(9)Å3, Z=6, R=0.0132). The structure is related to that of sodium ion conductor II-Na3Fe2(AsO4)3. The basic structure units are polyhedral clusters composed of central FeО6 octahedron sharing edges with three Na(1)О6 octahedra. The clusters share common vertices with bridging МоО4 tetrahedra to form an open 3D framework where the cavities are occupied by Na(2) and Na(3) atoms. The compound melts incongruently at 904.7±0.2K. Arrhenius type temperature dependence of electric conductivity σ has been registered in solid state (σ=6.8×10−2Sсm−1 at 800K), thus allowing considering Na9Fe(MoO4)6 as a new sodium ion conductor.
A new double molybdate Na9Fe(MoO4)6 was synthesized and structurally characterized, its physicochemical properties were studied. [Display omitted]
•A new compound Na9Fe(MoO4)6 was synthesized as ceramics and single crystals.•Na9Fe(MoO4)6 structure is related to that of sodium-ion conductor II-Na3Fe2(AsO4)3.•Physicochemical properties of the compound were studied.•Arrhenius plot for conductivity showed 6.8×10−2Scm−1 at 800K, Ea~0.8eV.•Thus, Na9Fe(MoO4)6 may be considered as a new sodium ion conductor.</abstract><pub>Elsevier Inc</pub><doi>10.1016/j.jssc.2013.07.007</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-4596 |
| ispartof | Journal of solid state chemistry, 2013-09, Vol.205, p.149-153 |
| issn | 0022-4596 1095-726X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1513436263 |
| source | Access via ScienceDirect (Elsevier) |
| subjects | Clusters Conductors (devices) Crystal structure Electrical conductivity Molybdates Sodium Sodium–iron molybdate Solid state Solid-state electrolyte Temperature dependence Three dimensional |
| title | New double molybdate Na9Fe(MoO4)6: Synthesis, structure, properties |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-03T17%3A13%3A25IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=New%20double%20molybdate%20Na9Fe(MoO4)6:%20Synthesis,%20structure,%20properties&rft.jtitle=Journal%20of%20solid%20state%20chemistry&rft.au=Savina,%20Aleksandra%20A.&rft.date=2013-09-01&rft.volume=205&rft.spage=149&rft.epage=153&rft.pages=149-153&rft.issn=0022-4596&rft.eissn=1095-726X&rft_id=info:doi/10.1016/j.jssc.2013.07.007&rft_dat=%3Cproquest_cross%3E1513436263%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1513436263&rft_id=info:pmid/&rft_els_id=S0022459613003307&rfr_iscdi=true |