The Nucleophilicity of a Dialkylcarbene: Unusual Activation Parameters for Additions of Adamantanylidene to Simple Alkenes

Computational and experimental results demonstrate that adamantanylidene (1) behaves as a highly reactive nucleophile toward common alkenes. It is the only known saturated nucleophilic carbene that lacks direct or vinylogous heteroatomic substitution. The activation energy and enthalpy for addition...

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Veröffentlicht in:	Journal of the American Chemical Society 2014-04, Vol.136 (13), p.4885-4888
Hauptverfasser:	Moss, Robert A, Wang, Lei, Krogh-Jespersen, Karsten
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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