Tetrathiafulvalene-Based Macrocycles Formed by Radical Cation Dimerization: The Role of Intramolecular Hydrogen Bonding and Solvent

Compounds 1 a and 1 b were prepared by appending two tetrathiafulvalene (TTF) units to an aromatic amide segment that is driven by six or two intramolecular NH⋅⋅⋅O hydrogen bonds to adopt a folded conformation. UV/Vis absorption experiments revealed that if the TTF units were oxidized to TTF.+ radi...

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Veröffentlicht in:	Chemistry, an Asian journal an Asian journal, 2014-04, Vol.9 (4), p.1039-1044
Hauptverfasser:	Wang, Wei-Kun, Chen, Yuan-Yuan, Wang, Hui, Zhang, Dan-Wei, Liu, Yi, Li, Zhan-Ting
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry foldamers Hydrogen bonds macrocyclization radical cation dimerization solvent effects
Online-Zugang:	Volltext
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