Electrochemically directed synthesis of Cu2(I)(TCNQF4(II-))(MeCN)2 (TCNQF4 = 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane): voltammetry, simulations, bulk electrolysis, spectroscopy, photoactivity, and X-ray crystal structure of the Cu2(I)(TCNQF4(II-))(EtCN)2 analogue

The new compound Cu2(I)(TCNQF4(II-))(MeCN)2 (TCNQF4(2-) = dianion of 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane) has been synthesized by electrochemically directed synthesis involving reduction of TCNQF4 to TCNQF4(2-) in acetonitrile containing [Cu(MeCN)4](+)(MeCN) and 0.1 M Bu4NPF6. In on...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Inorganic chemistry 2014-03, Vol.53 (6), p.3230-3242
Hauptverfasser:	Le, Thanh H, Nafady, Ayman, Vo, Nguyen T, Elliott, Robert W, Hudson, Timothy A, Robson, Richard, Abrahams, Brendan F, Martin, Lisandra L, Bond, Alan M
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!