Redox Centers Evolution in Phospho-Olivine Type (LiFe0.5Mn0.5 PO4) Nanoplatelets with Uniform Cation Distribution

In phospho-olivine type structures with mixed cations (LiM1M2PO4), the octahedral M1 and M2 sites that dictate the degree of intersites order/disorder play a key role in determining their electrochemical redox potentials. In the case of LiFe x Mn1–x PO4, for example, in micrometer-sized particles sy...

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Veröffentlicht in:	Nano letters 2014-03, Vol.14 (3), p.1477-1483
Hauptverfasser:	Paolella, Andrea, Bertoni, Giovanni, Dilena, Enrico, Marras, Sergio, Ansaldo, Alberto, Manna, Liberato, George, Chandramohan
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical synthesis methods Condensed matter: structure, mechanical and thermal properties Cross-disciplinary physics: materials science rheology Electrochemical Techniques Equations of state, phase equilibria, and phase transitions Exact sciences and technology Materials science Metals - chemistry Methods of nanofabrication Nanocrystalline materials Nanoparticles - chemistry Nanoparticles - ultrastructure Nanoscale materials and structures: fabrication and characterization Oxidation-Reduction Phosphates - chemistry Physics Specific phase transitions Structural transitions in nanoscale materials
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