A Straightforward Strategy toward Large BN-Embedded π‑Systems: Synthesis, Structure, and Optoelectronic Properties of Extended BN Heterosuperbenzenes
A straightforward strategy has been used to construct large BN-embedded π-systems simply from azaacenes. BN heterosuperbenzene derivatives, the largest BN heteroaromatics to date, have been synthesized in three steps. The molecules exhibit curved π-surfaces, showing two different conformations which...
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| Veröffentlicht in: | Journal of the American Chemical Society 2014-03, Vol.136 (10), p.3764-3767 |
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| container_end_page | 3767 |
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| container_issue | 10 |
| container_start_page | 3764 |
| container_title | Journal of the American Chemical Society |
| container_volume | 136 |
| creator | Wang, Xiao-Ye Zhuang, Fang-Dong Wang, Rui-Bo Wang, Xin-Chang Cao, Xiao-Yu Wang, Jie-Yu Pei, Jian |
| description | A straightforward strategy has been used to construct large BN-embedded π-systems simply from azaacenes. BN heterosuperbenzene derivatives, the largest BN heteroaromatics to date, have been synthesized in three steps. The molecules exhibit curved π-surfaces, showing two different conformations which are self-organized into a sandwich structure and further packed into a π-stacking column. The assembled microribbons exhibit good charge transport properties and photoconductivity, representing an important step toward the optoelectronic applications of BN-embedded aromatics. |
| doi_str_mv | 10.1021/ja500117z |
| format | Article |
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BN heterosuperbenzene derivatives, the largest BN heteroaromatics to date, have been synthesized in three steps. The molecules exhibit curved π-surfaces, showing two different conformations which are self-organized into a sandwich structure and further packed into a π-stacking column. 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Am. Chem. Soc</addtitle><date>2014-03-12</date><risdate>2014</risdate><volume>136</volume><issue>10</issue><spage>3764</spage><epage>3767</epage><pages>3764-3767</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><abstract>A straightforward strategy has been used to construct large BN-embedded π-systems simply from azaacenes. BN heterosuperbenzene derivatives, the largest BN heteroaromatics to date, have been synthesized in three steps. The molecules exhibit curved π-surfaces, showing two different conformations which are self-organized into a sandwich structure and further packed into a π-stacking column. The assembled microribbons exhibit good charge transport properties and photoconductivity, representing an important step toward the optoelectronic applications of BN-embedded aromatics.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>24579565</pmid><doi>10.1021/ja500117z</doi><tpages>4</tpages></addata></record> |
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| source | MEDLINE; American Chemical Society Journals |
| subjects | Aza Compounds - chemistry Chemistry Techniques, Synthetic - economics Chemistry Techniques, Synthetic - methods Equipment Design Models, Molecular Molecular Conformation Polycyclic Aromatic Hydrocarbons - chemical synthesis Polycyclic Aromatic Hydrocarbons - chemistry Transistors, Electronic |
| title | A Straightforward Strategy toward Large BN-Embedded π‑Systems: Synthesis, Structure, and Optoelectronic Properties of Extended BN Heterosuperbenzenes |
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