Synthesis and electrical conductivity of crystalline and glassy alloys in the Ag3GeS3Br-GeS2 system
We have studied the formation of crystalline and glassy alloys in the Ag 3 GeS 3 Br-GeS 2 system (0–52 mol % GeS 2 ; Ag 3 GeS 3 Br is a glass-forming phase of variable composition) and determined the crystallographic parameters of the Ag 3.179(9) Ge 1.474(5) S 4 Br alloy as the saturated solid solut...
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| Veröffentlicht in: | Inorganic materials 2013-09, Vol.49 (9), p.867-871 |
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| container_title | Inorganic materials |
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| creator | Moroz, M. V. Demchenko, P. Yu Mykolaychuk, O. G. Akselrud, L. G. Gladyshevskii, R. E. |
| description | We have studied the formation of crystalline and glassy alloys in the Ag
3
GeS
3
Br-GeS
2
system (0–52 mol % GeS
2
; Ag
3
GeS
3
Br is a glass-forming phase of variable composition) and determined the crystallographic parameters of the Ag
3.179(9)
Ge
1.474(5)
S
4
Br alloy as the saturated solid solution of GeS
2
in Ag
3
GeS
3
Br: sp. gr.
P
2
1
3,
a
= 10.16572(3) Å,
Z
= 4. The electrical conductivity of the crystalline and glassy alloys was measured in the temperature range 250–410 K by a dc probe technique. The current carriers in the alloys are silver cations and halogen anions. We obtained materials with superionic conductivity and proposed a model for conduction in the alloys. |
| doi_str_mv | 10.1134/S0020168513090100 |
| format | Article |
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3
GeS
3
Br-GeS
2
system (0–52 mol % GeS
2
; Ag
3
GeS
3
Br is a glass-forming phase of variable composition) and determined the crystallographic parameters of the Ag
3.179(9)
Ge
1.474(5)
S
4
Br alloy as the saturated solid solution of GeS
2
in Ag
3
GeS
3
Br: sp. gr.
P
2
1
3,
a
= 10.16572(3) Å,
Z
= 4. The electrical conductivity of the crystalline and glassy alloys was measured in the temperature range 250–410 K by a dc probe technique. The current carriers in the alloys are silver cations and halogen anions. We obtained materials with superionic conductivity and proposed a model for conduction in the alloys.</description><identifier>ISSN: 0020-1685</identifier><identifier>EISSN: 1608-3172</identifier><identifier>DOI: 10.1134/S0020168513090100</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Alloys ; Chemistry ; Chemistry and Materials Science ; Industrial Chemistry/Chemical Engineering ; Inorganic Chemistry ; Materials Science</subject><ispartof>Inorganic materials, 2013-09, Vol.49 (9), p.867-871</ispartof><rights>Pleiades Publishing, Ltd. 2013</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c321t-be927c575f3d9447bcec66f801dc4fb369df1e8b524a65aa0c9fd4080892c3f23</citedby><cites>FETCH-LOGICAL-c321t-be927c575f3d9447bcec66f801dc4fb369df1e8b524a65aa0c9fd4080892c3f23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0020168513090100$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0020168513090100$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Moroz, M. V.</creatorcontrib><creatorcontrib>Demchenko, P. Yu</creatorcontrib><creatorcontrib>Mykolaychuk, O. G.</creatorcontrib><creatorcontrib>Akselrud, L. G.</creatorcontrib><creatorcontrib>Gladyshevskii, R. E.</creatorcontrib><title>Synthesis and electrical conductivity of crystalline and glassy alloys in the Ag3GeS3Br-GeS2 system</title><title>Inorganic materials</title><addtitle>Inorg Mater</addtitle><description>We have studied the formation of crystalline and glassy alloys in the Ag
3
GeS
3
Br-GeS
2
system (0–52 mol % GeS
2
; Ag
3
GeS
3
Br is a glass-forming phase of variable composition) and determined the crystallographic parameters of the Ag
3.179(9)
Ge
1.474(5)
S
4
Br alloy as the saturated solid solution of GeS
2
in Ag
3
GeS
3
Br: sp. gr.
P
2
1
3,
a
= 10.16572(3) Å,
Z
= 4. The electrical conductivity of the crystalline and glassy alloys was measured in the temperature range 250–410 K by a dc probe technique. The current carriers in the alloys are silver cations and halogen anions. We obtained materials with superionic conductivity and proposed a model for conduction in the alloys.</description><subject>Alloys</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Inorganic Chemistry</subject><subject>Materials Science</subject><issn>0020-1685</issn><issn>1608-3172</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp9kMtOwzAURC0EEuXxAey8ZBO4fiXxslRQkCqxKKwjx7GLK9cpdoKUv8el7JBYjXTnzEh3ELohcEcI4_drAAqkrAVhIIEAnKAZKaEuGKnoKZod7OLgn6OLlLYAwEUtZ0ivpzB8mOQSVqHDxhs9RKeVx7oP3agH9-WGCfcW6zilQXnvgvlBN16lNOF86aeEXcC5Bs83bGnW7CEWWShOOWJ2V-jMKp_M9a9eovenx7fFc7F6Xb4s5qtCM0qGojWSVlpUwrJOcl612uiytDWQTnPbslJ2lpi6FZSrUigFWtqOQw21pJpZyi7R7bF3H_vP0aSh2bmkjfcqmH5MDRFQMik4rTJKjqiOfUrR2GYf3U7FqSHQHAZt_gyaM_SYSZkNGxObbT_GkD_6J_QNPIN3ww</recordid><startdate>20130901</startdate><enddate>20130901</enddate><creator>Moroz, M. V.</creator><creator>Demchenko, P. Yu</creator><creator>Mykolaychuk, O. G.</creator><creator>Akselrud, L. G.</creator><creator>Gladyshevskii, R. E.</creator><general>Springer US</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20130901</creationdate><title>Synthesis and electrical conductivity of crystalline and glassy alloys in the Ag3GeS3Br-GeS2 system</title><author>Moroz, M. V. ; Demchenko, P. Yu ; Mykolaychuk, O. G. ; Akselrud, L. G. ; Gladyshevskii, R. E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c321t-be927c575f3d9447bcec66f801dc4fb369df1e8b524a65aa0c9fd4080892c3f23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Alloys</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Inorganic Chemistry</topic><topic>Materials Science</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Moroz, M. V.</creatorcontrib><creatorcontrib>Demchenko, P. Yu</creatorcontrib><creatorcontrib>Mykolaychuk, O. G.</creatorcontrib><creatorcontrib>Akselrud, L. G.</creatorcontrib><creatorcontrib>Gladyshevskii, R. E.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Inorganic materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Moroz, M. V.</au><au>Demchenko, P. Yu</au><au>Mykolaychuk, O. G.</au><au>Akselrud, L. G.</au><au>Gladyshevskii, R. E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and electrical conductivity of crystalline and glassy alloys in the Ag3GeS3Br-GeS2 system</atitle><jtitle>Inorganic materials</jtitle><stitle>Inorg Mater</stitle><date>2013-09-01</date><risdate>2013</risdate><volume>49</volume><issue>9</issue><spage>867</spage><epage>871</epage><pages>867-871</pages><issn>0020-1685</issn><eissn>1608-3172</eissn><abstract>We have studied the formation of crystalline and glassy alloys in the Ag
3
GeS
3
Br-GeS
2
system (0–52 mol % GeS
2
; Ag
3
GeS
3
Br is a glass-forming phase of variable composition) and determined the crystallographic parameters of the Ag
3.179(9)
Ge
1.474(5)
S
4
Br alloy as the saturated solid solution of GeS
2
in Ag
3
GeS
3
Br: sp. gr.
P
2
1
3,
a
= 10.16572(3) Å,
Z
= 4. The electrical conductivity of the crystalline and glassy alloys was measured in the temperature range 250–410 K by a dc probe technique. The current carriers in the alloys are silver cations and halogen anions. We obtained materials with superionic conductivity and proposed a model for conduction in the alloys.</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1134/S0020168513090100</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
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| ispartof | Inorganic materials, 2013-09, Vol.49 (9), p.867-871 |
| issn | 0020-1685 1608-3172 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1506395427 |
| source | SpringerLink Journals |
| subjects | Alloys Chemistry Chemistry and Materials Science Industrial Chemistry/Chemical Engineering Inorganic Chemistry Materials Science |
| title | Synthesis and electrical conductivity of crystalline and glassy alloys in the Ag3GeS3Br-GeS2 system |
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