Temperature effect on the surface phase transitions of monolayer films of C12E1 at air/water interface
The temperature-dependent conformational states of a monolayer film of ethylene glycol monododecyl ether (C 12 E 1 ) at the air/water interface have been investigated using ellipsometry, surface tension, external reflection–absorption FTIR spectroscopy and two-dimensional infrared (2DIR) correlation...
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| Veröffentlicht in: | Colloid and polymer science 2013-11, Vol.291 (11), p.2647-2652 |
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| container_issue | 11 |
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| container_title | Colloid and polymer science |
| container_volume | 291 |
| creator | Mehta, Surinder K. Imai, Yosuke Takumi, Hiroki Shibata, Kinue Sakamoto, Hiroyasu Takiue, Takanori Matsubara, Hiroki Aratono, Makoto |
| description | The temperature-dependent conformational states of a monolayer film of ethylene glycol monododecyl ether (C
12
E
1
) at the air/water interface have been investigated using ellipsometry, surface tension, external reflection–absorption FTIR spectroscopy and two-dimensional infrared (2DIR) correlation analysis. The ellipticity coefficients and the entropy associated with C
12
E
1
adsorption changed almost discontinuously at certain temperatures, which manifested the interfacial phase transitions. The phase transition and coexistence of two phases were further clarified using 2DIR correlation analysis with temperature perturbation. The asynchronous correlation maps revealed that both bands of asymmetric and symmetric C–H stretching vibration in one-dimensional IR were split into two components, which confirmed the coexistence of two phases at the interface. |
| doi_str_mv | 10.1007/s00396-013-3010-1 |
| format | Article |
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12
E
1
) at the air/water interface have been investigated using ellipsometry, surface tension, external reflection–absorption FTIR spectroscopy and two-dimensional infrared (2DIR) correlation analysis. The ellipticity coefficients and the entropy associated with C
12
E
1
adsorption changed almost discontinuously at certain temperatures, which manifested the interfacial phase transitions. The phase transition and coexistence of two phases were further clarified using 2DIR correlation analysis with temperature perturbation. The asynchronous correlation maps revealed that both bands of asymmetric and symmetric C–H stretching vibration in one-dimensional IR were split into two components, which confirmed the coexistence of two phases at the interface.</description><identifier>ISSN: 0303-402X</identifier><identifier>EISSN: 1435-1536</identifier><identifier>DOI: 10.1007/s00396-013-3010-1</identifier><identifier>CODEN: CPMSB6</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Correlation analysis ; Exact sciences and technology ; Food Science ; Gas-liquid interface and liquid-liquid interface ; General and physical chemistry ; Nanotechnology and Microengineering ; Original Contribution ; Physical Chemistry ; Polymer Sciences ; Soft and Granular Matter ; Surface physical chemistry ; Surface-active agents: properties</subject><ispartof>Colloid and polymer science, 2013-11, Vol.291 (11), p.2647-2652</ispartof><rights>Springer-Verlag Berlin Heidelberg 2013</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c303t-18c74864dc9d129ce33d8ed4a28062169f58877f536f24c2837a10e8546230343</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00396-013-3010-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00396-013-3010-1$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27830802$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Mehta, Surinder K.</creatorcontrib><creatorcontrib>Imai, Yosuke</creatorcontrib><creatorcontrib>Takumi, Hiroki</creatorcontrib><creatorcontrib>Shibata, Kinue</creatorcontrib><creatorcontrib>Sakamoto, Hiroyasu</creatorcontrib><creatorcontrib>Takiue, Takanori</creatorcontrib><creatorcontrib>Matsubara, Hiroki</creatorcontrib><creatorcontrib>Aratono, Makoto</creatorcontrib><title>Temperature effect on the surface phase transitions of monolayer films of C12E1 at air/water interface</title><title>Colloid and polymer science</title><addtitle>Colloid Polym Sci</addtitle><description>The temperature-dependent conformational states of a monolayer film of ethylene glycol monododecyl ether (C
12
E
1
) at the air/water interface have been investigated using ellipsometry, surface tension, external reflection–absorption FTIR spectroscopy and two-dimensional infrared (2DIR) correlation analysis. The ellipticity coefficients and the entropy associated with C
12
E
1
adsorption changed almost discontinuously at certain temperatures, which manifested the interfacial phase transitions. The phase transition and coexistence of two phases were further clarified using 2DIR correlation analysis with temperature perturbation. The asynchronous correlation maps revealed that both bands of asymmetric and symmetric C–H stretching vibration in one-dimensional IR were split into two components, which confirmed the coexistence of two phases at the interface.</description><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Correlation analysis</subject><subject>Exact sciences and technology</subject><subject>Food Science</subject><subject>Gas-liquid interface and liquid-liquid interface</subject><subject>General and physical chemistry</subject><subject>Nanotechnology and Microengineering</subject><subject>Original Contribution</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Soft and Granular Matter</subject><subject>Surface physical chemistry</subject><subject>Surface-active agents: properties</subject><issn>0303-402X</issn><issn>1435-1536</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LJDEQhoMoOLr-gL3lsuCl16oknU4fl8EvGPCisLcQMpW1pbszJmnEf2_GkT16qUDVWw-ph7GfCL8RoLvKALLXDaBsJCA0eMRWqGTbYCv1MVuBBNkoEH9P2VnOLwCgeq1XLDzStKPkypKIUwjkC48zL8_E85KC88R3zy4TL8nNeShDnDOPgU9xjqN7p8TDME6frTWKa-SucDekqzdX6myYa91DfrCT4MZMF1_vOXu6uX5c3zWbh9v79Z9N4-v_SoPGd8potfX9FkXvScqtoa1ywoAWqPvQGtN1od4UhPLCyM4hkGmVFhWg5Dm7PHB3Kb4ulIudhuxpHN1McckWW9CyQ6OxRvEQ9SnmnCjYXRoml94tgt07tQentjq1e6d2v_PrC--yd2OoTvyQ_y-KzkgwIGpOHHK5juZ_lOxLXNJcL_8G_gHCAoT7</recordid><startdate>20131101</startdate><enddate>20131101</enddate><creator>Mehta, Surinder K.</creator><creator>Imai, Yosuke</creator><creator>Takumi, Hiroki</creator><creator>Shibata, Kinue</creator><creator>Sakamoto, Hiroyasu</creator><creator>Takiue, Takanori</creator><creator>Matsubara, Hiroki</creator><creator>Aratono, Makoto</creator><general>Springer Berlin Heidelberg</general><general>Springer</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20131101</creationdate><title>Temperature effect on the surface phase transitions of monolayer films of C12E1 at air/water interface</title><author>Mehta, Surinder K. ; Imai, Yosuke ; Takumi, Hiroki ; Shibata, Kinue ; Sakamoto, Hiroyasu ; Takiue, Takanori ; Matsubara, Hiroki ; Aratono, Makoto</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c303t-18c74864dc9d129ce33d8ed4a28062169f58877f536f24c2837a10e8546230343</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Correlation analysis</topic><topic>Exact sciences and technology</topic><topic>Food Science</topic><topic>Gas-liquid interface and liquid-liquid interface</topic><topic>General and physical chemistry</topic><topic>Nanotechnology and Microengineering</topic><topic>Original Contribution</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Soft and Granular Matter</topic><topic>Surface physical chemistry</topic><topic>Surface-active agents: properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mehta, Surinder K.</creatorcontrib><creatorcontrib>Imai, Yosuke</creatorcontrib><creatorcontrib>Takumi, Hiroki</creatorcontrib><creatorcontrib>Shibata, Kinue</creatorcontrib><creatorcontrib>Sakamoto, Hiroyasu</creatorcontrib><creatorcontrib>Takiue, Takanori</creatorcontrib><creatorcontrib>Matsubara, Hiroki</creatorcontrib><creatorcontrib>Aratono, Makoto</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Colloid and polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mehta, Surinder K.</au><au>Imai, Yosuke</au><au>Takumi, Hiroki</au><au>Shibata, Kinue</au><au>Sakamoto, Hiroyasu</au><au>Takiue, Takanori</au><au>Matsubara, Hiroki</au><au>Aratono, Makoto</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Temperature effect on the surface phase transitions of monolayer films of C12E1 at air/water interface</atitle><jtitle>Colloid and polymer science</jtitle><stitle>Colloid Polym Sci</stitle><date>2013-11-01</date><risdate>2013</risdate><volume>291</volume><issue>11</issue><spage>2647</spage><epage>2652</epage><pages>2647-2652</pages><issn>0303-402X</issn><eissn>1435-1536</eissn><coden>CPMSB6</coden><abstract>The temperature-dependent conformational states of a monolayer film of ethylene glycol monododecyl ether (C
12
E
1
) at the air/water interface have been investigated using ellipsometry, surface tension, external reflection–absorption FTIR spectroscopy and two-dimensional infrared (2DIR) correlation analysis. The ellipticity coefficients and the entropy associated with C
12
E
1
adsorption changed almost discontinuously at certain temperatures, which manifested the interfacial phase transitions. The phase transition and coexistence of two phases were further clarified using 2DIR correlation analysis with temperature perturbation. The asynchronous correlation maps revealed that both bands of asymmetric and symmetric C–H stretching vibration in one-dimensional IR were split into two components, which confirmed the coexistence of two phases at the interface.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00396-013-3010-1</doi><tpages>6</tpages></addata></record> |
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| subjects | Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Correlation analysis Exact sciences and technology Food Science Gas-liquid interface and liquid-liquid interface General and physical chemistry Nanotechnology and Microengineering Original Contribution Physical Chemistry Polymer Sciences Soft and Granular Matter Surface physical chemistry Surface-active agents: properties |
| title | Temperature effect on the surface phase transitions of monolayer films of C12E1 at air/water interface |
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