Synthesis and properties of the cationic fluorocarbon emulsifier-free latex in a new micellar system
Cationic fluorocarbon emulsifier-free latex (CFEL) based on hexafluorobutyl methacrylate (FA), styrene, butyl acrylate, and methacrylatoethyl trimethyl ammonium chloride is successfully prepared in a new micellar system in which the fluorinated surface active monomer (FSM) based on isophorone diisoc...
Gespeichert in:
| Veröffentlicht in: | Colloid and polymer science 2014, Vol.292 (1), p.123-131 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 131 |
|---|---|
| container_issue | 1 |
| container_start_page | 123 |
| container_title | Colloid and polymer science |
| container_volume | 292 |
| creator | Li, Ganghui Li, Ning Wang, Chen Niu, Yuhua Gong, Xuemei |
| description | Cationic fluorocarbon emulsifier-free latex (CFEL) based on hexafluorobutyl methacrylate (FA), styrene, butyl acrylate, and methacrylatoethyl trimethyl ammonium chloride is successfully prepared in a new micellar system in which the fluorinated surface active monomer (FSM) based on isophorone diisocyanate, dodecafluoroheptanol, and allyl polyethylene glycol is used. The chemical structure of FSM is characterized by Fourier transform infrared spectroscopy,
1
H-NMR, and its surface-active properties have been investigated by surface tension determinator. Besides, effect of FSM, FA, and also the curing temperature on the latex and film properties has been investigated by the coagulation ratio (
W
c
), precipitation ratio (
W
p
), Nano-ZS particle sizer, contact angle, and water absorption ratio, respectively. The results show that the FSM is successfully prepared. The CMC of FSM is 2.37 g L
−1
and the
γ
CMC
is 26.31mN m
−1
accordingly. The more FSM content makes more stable emulsion and have only little adverse effect on its film properties. When the FSM content increases from 1.05 to 13.11 %, the
W
c
and
W
p
decrease by 83.5 and 32.1 %, respectively, and the surface free energy (
γ
) of CFEL film only increases by 8.3 %. The more FA content makes less stable emulsion but have favorable effect on its film properties. When the FA content increases from 0 to 25.11 %, the
γ
is decreased by 55.1 %. The curing temperature has much impact on film property. For example, the
γ
from 27.47 to 20.36 mJ · m
−2
when the curing temperature rises from 30 to 110 °C. |
| doi_str_mv | 10.1007/s00396-013-3060-4 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1506366995</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1506366995</sourcerecordid><originalsourceid>FETCH-LOGICAL-c379t-d3bcf1d1601ec8e3a36d9c5e4598ed3d986f7740597f4addd3ed9e756fe904ea3</originalsourceid><addsrcrecordid>eNp1kE-LFDEQxYMoOK5-AG8BEbxEK5M_3TnK4qqw4EEFbyGbVDRLdzKmutH59vY4i4jgqQ7v9x6vHmNPJbyUAMMrAlDOCpBKKLAg9D22k1oZIY2y99kOFCihYf_lIXtEdAsA2lm7Y-njsS7fkArxUBM_9HbAvhQk3jLfBB7DUlotkedpbb3F0G9a5TivE5VcsIvcEfkUFvzJS-WBV_zB5xJxmkLndKQF58fsQQ4T4ZO7e8E-X735dPlOXH94-_7y9bWIanCLSOomZpmkBYlxRBWUTS4a1MaNmFRyo83DoMG4IeuQUlKYHA7GZnSgMagL9uKcu73xfUVa_Fzod5OKbSUvDVhlrXNmQ5_9g962tdetnZd2gL0b5Gg3Sp6p2BtRx-wPvcyhH70Ef9rdn3f32-7-tLvXm-f5XXKgGKbcQ42F_hj3o1Ha6VP2_szRJtWv2P9q8N_wX3pzk8Q</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1670297186</pqid></control><display><type>article</type><title>Synthesis and properties of the cationic fluorocarbon emulsifier-free latex in a new micellar system</title><source>SpringerLink Journals - AutoHoldings</source><creator>Li, Ganghui ; Li, Ning ; Wang, Chen ; Niu, Yuhua ; Gong, Xuemei</creator><creatorcontrib>Li, Ganghui ; Li, Ning ; Wang, Chen ; Niu, Yuhua ; Gong, Xuemei</creatorcontrib><description>Cationic fluorocarbon emulsifier-free latex (CFEL) based on hexafluorobutyl methacrylate (FA), styrene, butyl acrylate, and methacrylatoethyl trimethyl ammonium chloride is successfully prepared in a new micellar system in which the fluorinated surface active monomer (FSM) based on isophorone diisocyanate, dodecafluoroheptanol, and allyl polyethylene glycol is used. The chemical structure of FSM is characterized by Fourier transform infrared spectroscopy,
1
H-NMR, and its surface-active properties have been investigated by surface tension determinator. Besides, effect of FSM, FA, and also the curing temperature on the latex and film properties has been investigated by the coagulation ratio (
W
c
), precipitation ratio (
W
p
), Nano-ZS particle sizer, contact angle, and water absorption ratio, respectively. The results show that the FSM is successfully prepared. The CMC of FSM is 2.37 g L
−1
and the
γ
CMC
is 26.31mN m
−1
accordingly. The more FSM content makes more stable emulsion and have only little adverse effect on its film properties. When the FSM content increases from 1.05 to 13.11 %, the
W
c
and
W
p
decrease by 83.5 and 32.1 %, respectively, and the surface free energy (
γ
) of CFEL film only increases by 8.3 %. The more FA content makes less stable emulsion but have favorable effect on its film properties. When the FA content increases from 0 to 25.11 %, the
γ
is decreased by 55.1 %. The curing temperature has much impact on film property. For example, the
γ
from 27.47 to 20.36 mJ · m
−2
when the curing temperature rises from 30 to 110 °C.</description><identifier>ISSN: 0303-402X</identifier><identifier>EISSN: 1435-1536</identifier><identifier>DOI: 10.1007/s00396-013-3060-4</identifier><identifier>CODEN: CPMSB6</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Applied sciences ; Cationic ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Copolymerization ; Exact sciences and technology ; Food Science ; Nanotechnology and Microengineering ; Organic polymers ; Original Contribution ; Physical Chemistry ; Physicochemistry of polymers ; Polymer Sciences ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; Soft and Granular Matter</subject><ispartof>Colloid and polymer science, 2014, Vol.292 (1), p.123-131</ispartof><rights>Springer-Verlag Berlin Heidelberg 2013</rights><rights>2015 INIST-CNRS</rights><rights>Springer-Verlag Berlin Heidelberg 2014</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c379t-d3bcf1d1601ec8e3a36d9c5e4598ed3d986f7740597f4addd3ed9e756fe904ea3</citedby><cites>FETCH-LOGICAL-c379t-d3bcf1d1601ec8e3a36d9c5e4598ed3d986f7740597f4addd3ed9e756fe904ea3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00396-013-3060-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00396-013-3060-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,4022,27922,27923,27924,41487,42556,51318</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=28534946$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Li, Ganghui</creatorcontrib><creatorcontrib>Li, Ning</creatorcontrib><creatorcontrib>Wang, Chen</creatorcontrib><creatorcontrib>Niu, Yuhua</creatorcontrib><creatorcontrib>Gong, Xuemei</creatorcontrib><title>Synthesis and properties of the cationic fluorocarbon emulsifier-free latex in a new micellar system</title><title>Colloid and polymer science</title><addtitle>Colloid Polym Sci</addtitle><description>Cationic fluorocarbon emulsifier-free latex (CFEL) based on hexafluorobutyl methacrylate (FA), styrene, butyl acrylate, and methacrylatoethyl trimethyl ammonium chloride is successfully prepared in a new micellar system in which the fluorinated surface active monomer (FSM) based on isophorone diisocyanate, dodecafluoroheptanol, and allyl polyethylene glycol is used. The chemical structure of FSM is characterized by Fourier transform infrared spectroscopy,
1
H-NMR, and its surface-active properties have been investigated by surface tension determinator. Besides, effect of FSM, FA, and also the curing temperature on the latex and film properties has been investigated by the coagulation ratio (
W
c
), precipitation ratio (
W
p
), Nano-ZS particle sizer, contact angle, and water absorption ratio, respectively. The results show that the FSM is successfully prepared. The CMC of FSM is 2.37 g L
−1
and the
γ
CMC
is 26.31mN m
−1
accordingly. The more FSM content makes more stable emulsion and have only little adverse effect on its film properties. When the FSM content increases from 1.05 to 13.11 %, the
W
c
and
W
p
decrease by 83.5 and 32.1 %, respectively, and the surface free energy (
γ
) of CFEL film only increases by 8.3 %. The more FA content makes less stable emulsion but have favorable effect on its film properties. When the FA content increases from 0 to 25.11 %, the
γ
is decreased by 55.1 %. The curing temperature has much impact on film property. For example, the
γ
from 27.47 to 20.36 mJ · m
−2
when the curing temperature rises from 30 to 110 °C.</description><subject>Applied sciences</subject><subject>Cationic</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Copolymerization</subject><subject>Exact sciences and technology</subject><subject>Food Science</subject><subject>Nanotechnology and Microengineering</subject><subject>Organic polymers</subject><subject>Original Contribution</subject><subject>Physical Chemistry</subject><subject>Physicochemistry of polymers</subject><subject>Polymer Sciences</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>Soft and Granular Matter</subject><issn>0303-402X</issn><issn>1435-1536</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kE-LFDEQxYMoOK5-AG8BEbxEK5M_3TnK4qqw4EEFbyGbVDRLdzKmutH59vY4i4jgqQ7v9x6vHmNPJbyUAMMrAlDOCpBKKLAg9D22k1oZIY2y99kOFCihYf_lIXtEdAsA2lm7Y-njsS7fkArxUBM_9HbAvhQk3jLfBB7DUlotkedpbb3F0G9a5TivE5VcsIvcEfkUFvzJS-WBV_zB5xJxmkLndKQF58fsQQ4T4ZO7e8E-X735dPlOXH94-_7y9bWIanCLSOomZpmkBYlxRBWUTS4a1MaNmFRyo83DoMG4IeuQUlKYHA7GZnSgMagL9uKcu73xfUVa_Fzod5OKbSUvDVhlrXNmQ5_9g962tdetnZd2gL0b5Gg3Sp6p2BtRx-wPvcyhH70Ef9rdn3f32-7-tLvXm-f5XXKgGKbcQ42F_hj3o1Ha6VP2_szRJtWv2P9q8N_wX3pzk8Q</recordid><startdate>2014</startdate><enddate>2014</enddate><creator>Li, Ganghui</creator><creator>Li, Ning</creator><creator>Wang, Chen</creator><creator>Niu, Yuhua</creator><creator>Gong, Xuemei</creator><general>Springer Berlin Heidelberg</general><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>2014</creationdate><title>Synthesis and properties of the cationic fluorocarbon emulsifier-free latex in a new micellar system</title><author>Li, Ganghui ; Li, Ning ; Wang, Chen ; Niu, Yuhua ; Gong, Xuemei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c379t-d3bcf1d1601ec8e3a36d9c5e4598ed3d986f7740597f4addd3ed9e756fe904ea3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Applied sciences</topic><topic>Cationic</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Copolymerization</topic><topic>Exact sciences and technology</topic><topic>Food Science</topic><topic>Nanotechnology and Microengineering</topic><topic>Organic polymers</topic><topic>Original Contribution</topic><topic>Physical Chemistry</topic><topic>Physicochemistry of polymers</topic><topic>Polymer Sciences</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>Soft and Granular Matter</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Ganghui</creatorcontrib><creatorcontrib>Li, Ning</creatorcontrib><creatorcontrib>Wang, Chen</creatorcontrib><creatorcontrib>Niu, Yuhua</creatorcontrib><creatorcontrib>Gong, Xuemei</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Colloid and polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Ganghui</au><au>Li, Ning</au><au>Wang, Chen</au><au>Niu, Yuhua</au><au>Gong, Xuemei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and properties of the cationic fluorocarbon emulsifier-free latex in a new micellar system</atitle><jtitle>Colloid and polymer science</jtitle><stitle>Colloid Polym Sci</stitle><date>2014</date><risdate>2014</risdate><volume>292</volume><issue>1</issue><spage>123</spage><epage>131</epage><pages>123-131</pages><issn>0303-402X</issn><eissn>1435-1536</eissn><coden>CPMSB6</coden><abstract>Cationic fluorocarbon emulsifier-free latex (CFEL) based on hexafluorobutyl methacrylate (FA), styrene, butyl acrylate, and methacrylatoethyl trimethyl ammonium chloride is successfully prepared in a new micellar system in which the fluorinated surface active monomer (FSM) based on isophorone diisocyanate, dodecafluoroheptanol, and allyl polyethylene glycol is used. The chemical structure of FSM is characterized by Fourier transform infrared spectroscopy,
1
H-NMR, and its surface-active properties have been investigated by surface tension determinator. Besides, effect of FSM, FA, and also the curing temperature on the latex and film properties has been investigated by the coagulation ratio (
W
c
), precipitation ratio (
W
p
), Nano-ZS particle sizer, contact angle, and water absorption ratio, respectively. The results show that the FSM is successfully prepared. The CMC of FSM is 2.37 g L
−1
and the
γ
CMC
is 26.31mN m
−1
accordingly. The more FSM content makes more stable emulsion and have only little adverse effect on its film properties. When the FSM content increases from 1.05 to 13.11 %, the
W
c
and
W
p
decrease by 83.5 and 32.1 %, respectively, and the surface free energy (
γ
) of CFEL film only increases by 8.3 %. The more FA content makes less stable emulsion but have favorable effect on its film properties. When the FA content increases from 0 to 25.11 %, the
γ
is decreased by 55.1 %. The curing temperature has much impact on film property. For example, the
γ
from 27.47 to 20.36 mJ · m
−2
when the curing temperature rises from 30 to 110 °C.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00396-013-3060-4</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0303-402X |
| ispartof | Colloid and polymer science, 2014, Vol.292 (1), p.123-131 |
| issn | 0303-402X 1435-1536 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1506366995 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Applied sciences Cationic Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Copolymerization Exact sciences and technology Food Science Nanotechnology and Microengineering Organic polymers Original Contribution Physical Chemistry Physicochemistry of polymers Polymer Sciences Preparation, kinetics, thermodynamics, mechanism and catalysts Soft and Granular Matter |
| title | Synthesis and properties of the cationic fluorocarbon emulsifier-free latex in a new micellar system |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-11T20%3A50%3A03IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20and%20properties%20of%20the%20cationic%20fluorocarbon%20emulsifier-free%20latex%20in%20a%20new%20micellar%20system&rft.jtitle=Colloid%20and%20polymer%20science&rft.au=Li,%20Ganghui&rft.date=2014&rft.volume=292&rft.issue=1&rft.spage=123&rft.epage=131&rft.pages=123-131&rft.issn=0303-402X&rft.eissn=1435-1536&rft.coden=CPMSB6&rft_id=info:doi/10.1007/s00396-013-3060-4&rft_dat=%3Cproquest_cross%3E1506366995%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1670297186&rft_id=info:pmid/&rfr_iscdi=true |