Amine-modified maleic anhydride containing terpolymers for the adsorption of uranyl ion in aqueous solutions
Maleic anhydride–styrene–methyl methacrylate (MA–S–MM) terpolymer was prepared. It was modified by ethylenediamine (EDA) and diethylenetriamine (DETA) in order to get cross-linked polymers bearing carboxyl and amine groups. Modified polymers used as an adsorbent for the removal of UO 2 2+ from water...
Gespeichert in:
| Veröffentlicht in: | Journal of radioanalytical and nuclear chemistry 2013-11, Vol.298 (2), p.923-930 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 930 |
|---|---|
| container_issue | 2 |
| container_start_page | 923 |
| container_title | Journal of radioanalytical and nuclear chemistry |
| container_volume | 298 |
| creator | Simsek, Selcuk Yilmaz, Ersen Boztug, Ali |
| description | Maleic anhydride–styrene–methyl methacrylate (MA–S–MM) terpolymer was prepared. It was modified by ethylenediamine (EDA) and diethylenetriamine (DETA) in order to get cross-linked polymers bearing carboxyl and amine groups. Modified polymers used as an adsorbent for the removal of UO
2
2+
from water. The characterizations of structures of all the polymers were performed by Fourier transform infrared. The adsorptive features of adsorbents were then investigated for UO
2
2+
in view of dependency on ion concentration, pH, temperature and kinetics. Experimentally obtained isotherms were evaluated with reference to Langmuir, Freundlich and Dubinin–Radushkevich models. The maximum monolayer adsorption capacity for UO
2
2+
was found to be 1.59 and 2.43 mol kg
−1
for EDA–MA–S–MM and DETA–MA–S–MM, respectively. It can be said that the new modified polymers prepared in our laboratory have been suggested as new adsorbents for uranyl ions. |
| doi_str_mv | 10.1007/s10967-013-2529-4 |
| format | Article |
| fullrecord | <record><control><sourceid>gale_proqu</sourceid><recordid>TN_cdi_proquest_miscellaneous_1506366787</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A348568804</galeid><sourcerecordid>A348568804</sourcerecordid><originalsourceid>FETCH-LOGICAL-c360t-b3f2e1bf64fa87856642900060713f58a9a53c6ed57ce1f1b26afc243f3fbbcd3</originalsourceid><addsrcrecordid>eNp9kTtv5CAUhdEqkXaS7A_YjnIbEh424HIUbR5SpDRJjTC-zDCyYRbsYv79Yjl1dAt00fnQORyEfjN6zyhVD4XRTipCmSC85R1pfqAda7UmXGl6hXaUC0laJdhPdFPKiVLaaS12aNxPIQKZ0hB8gAFPdoTgsI3Hy5DDANilONsQQzzgGfI5jZcJcsE-ZTwfAduhpHyeQ4o4ebxkGy8jXrcQsf23QFoKLmlcVkW5Q9fejgV-fZ236PPp78fjC3l7f3593L8RJySdSS88B9Z72XirlW6lbHhXHUuqmPCttp1thZMwtMoB86zn0nrHG-GF73s3iFv0Z3v3nFP1UGYzheJgHG1cDRnWUimkVFpV6f0mPdTgJkSf5mxdnQGmULODD_V-L5pqQ2vaVIBtgMuplAzenHOYbL4YRs1ahdmqMLUKs1ZhVoZvTKnaeIBsTmnJsX7BN9B_mf-OJg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1506366787</pqid></control><display><type>article</type><title>Amine-modified maleic anhydride containing terpolymers for the adsorption of uranyl ion in aqueous solutions</title><source>SpringerLink Journals</source><creator>Simsek, Selcuk ; Yilmaz, Ersen ; Boztug, Ali</creator><creatorcontrib>Simsek, Selcuk ; Yilmaz, Ersen ; Boztug, Ali</creatorcontrib><description>Maleic anhydride–styrene–methyl methacrylate (MA–S–MM) terpolymer was prepared. It was modified by ethylenediamine (EDA) and diethylenetriamine (DETA) in order to get cross-linked polymers bearing carboxyl and amine groups. Modified polymers used as an adsorbent for the removal of UO
2
2+
from water. The characterizations of structures of all the polymers were performed by Fourier transform infrared. The adsorptive features of adsorbents were then investigated for UO
2
2+
in view of dependency on ion concentration, pH, temperature and kinetics. Experimentally obtained isotherms were evaluated with reference to Langmuir, Freundlich and Dubinin–Radushkevich models. The maximum monolayer adsorption capacity for UO
2
2+
was found to be 1.59 and 2.43 mol kg
−1
for EDA–MA–S–MM and DETA–MA–S–MM, respectively. It can be said that the new modified polymers prepared in our laboratory have been suggested as new adsorbents for uranyl ions.</description><identifier>ISSN: 0236-5731</identifier><identifier>EISSN: 1588-2780</identifier><identifier>DOI: 10.1007/s10967-013-2529-4</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Adsorbents ; Adsorption ; Amines ; Chemical properties ; Chemistry ; Chemistry and Materials Science ; Crosslinking ; DETA ; Diagnostic Radiology ; Electronic design automation ; Ethylenediamines ; Fourier transforms ; Hadrons ; Heavy Ions ; Inorganic Chemistry ; Maleic anhydride ; Methyl methacrylate ; Nuclear Chemistry ; Nuclear Physics ; Physical Chemistry ; Polymers ; Terpolymers</subject><ispartof>Journal of radioanalytical and nuclear chemistry, 2013-11, Vol.298 (2), p.923-930</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2013</rights><rights>COPYRIGHT 2013 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c360t-b3f2e1bf64fa87856642900060713f58a9a53c6ed57ce1f1b26afc243f3fbbcd3</citedby><cites>FETCH-LOGICAL-c360t-b3f2e1bf64fa87856642900060713f58a9a53c6ed57ce1f1b26afc243f3fbbcd3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10967-013-2529-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10967-013-2529-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Simsek, Selcuk</creatorcontrib><creatorcontrib>Yilmaz, Ersen</creatorcontrib><creatorcontrib>Boztug, Ali</creatorcontrib><title>Amine-modified maleic anhydride containing terpolymers for the adsorption of uranyl ion in aqueous solutions</title><title>Journal of radioanalytical and nuclear chemistry</title><addtitle>J Radioanal Nucl Chem</addtitle><description>Maleic anhydride–styrene–methyl methacrylate (MA–S–MM) terpolymer was prepared. It was modified by ethylenediamine (EDA) and diethylenetriamine (DETA) in order to get cross-linked polymers bearing carboxyl and amine groups. Modified polymers used as an adsorbent for the removal of UO
2
2+
from water. The characterizations of structures of all the polymers were performed by Fourier transform infrared. The adsorptive features of adsorbents were then investigated for UO
2
2+
in view of dependency on ion concentration, pH, temperature and kinetics. Experimentally obtained isotherms were evaluated with reference to Langmuir, Freundlich and Dubinin–Radushkevich models. The maximum monolayer adsorption capacity for UO
2
2+
was found to be 1.59 and 2.43 mol kg
−1
for EDA–MA–S–MM and DETA–MA–S–MM, respectively. It can be said that the new modified polymers prepared in our laboratory have been suggested as new adsorbents for uranyl ions.</description><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Amines</subject><subject>Chemical properties</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crosslinking</subject><subject>DETA</subject><subject>Diagnostic Radiology</subject><subject>Electronic design automation</subject><subject>Ethylenediamines</subject><subject>Fourier transforms</subject><subject>Hadrons</subject><subject>Heavy Ions</subject><subject>Inorganic Chemistry</subject><subject>Maleic anhydride</subject><subject>Methyl methacrylate</subject><subject>Nuclear Chemistry</subject><subject>Nuclear Physics</subject><subject>Physical Chemistry</subject><subject>Polymers</subject><subject>Terpolymers</subject><issn>0236-5731</issn><issn>1588-2780</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp9kTtv5CAUhdEqkXaS7A_YjnIbEh424HIUbR5SpDRJjTC-zDCyYRbsYv79Yjl1dAt00fnQORyEfjN6zyhVD4XRTipCmSC85R1pfqAda7UmXGl6hXaUC0laJdhPdFPKiVLaaS12aNxPIQKZ0hB8gAFPdoTgsI3Hy5DDANilONsQQzzgGfI5jZcJcsE-ZTwfAduhpHyeQ4o4ebxkGy8jXrcQsf23QFoKLmlcVkW5Q9fejgV-fZ236PPp78fjC3l7f3593L8RJySdSS88B9Z72XirlW6lbHhXHUuqmPCttp1thZMwtMoB86zn0nrHG-GF73s3iFv0Z3v3nFP1UGYzheJgHG1cDRnWUimkVFpV6f0mPdTgJkSf5mxdnQGmULODD_V-L5pqQ2vaVIBtgMuplAzenHOYbL4YRs1ahdmqMLUKs1ZhVoZvTKnaeIBsTmnJsX7BN9B_mf-OJg</recordid><startdate>20131101</startdate><enddate>20131101</enddate><creator>Simsek, Selcuk</creator><creator>Yilmaz, Ersen</creator><creator>Boztug, Ali</creator><general>Springer Netherlands</general><general>Springer</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>JG9</scope><scope>KR7</scope><scope>L7M</scope></search><sort><creationdate>20131101</creationdate><title>Amine-modified maleic anhydride containing terpolymers for the adsorption of uranyl ion in aqueous solutions</title><author>Simsek, Selcuk ; Yilmaz, Ersen ; Boztug, Ali</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c360t-b3f2e1bf64fa87856642900060713f58a9a53c6ed57ce1f1b26afc243f3fbbcd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Adsorbents</topic><topic>Adsorption</topic><topic>Amines</topic><topic>Chemical properties</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crosslinking</topic><topic>DETA</topic><topic>Diagnostic Radiology</topic><topic>Electronic design automation</topic><topic>Ethylenediamines</topic><topic>Fourier transforms</topic><topic>Hadrons</topic><topic>Heavy Ions</topic><topic>Inorganic Chemistry</topic><topic>Maleic anhydride</topic><topic>Methyl methacrylate</topic><topic>Nuclear Chemistry</topic><topic>Nuclear Physics</topic><topic>Physical Chemistry</topic><topic>Polymers</topic><topic>Terpolymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Simsek, Selcuk</creatorcontrib><creatorcontrib>Yilmaz, Ersen</creatorcontrib><creatorcontrib>Boztug, Ali</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of radioanalytical and nuclear chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Simsek, Selcuk</au><au>Yilmaz, Ersen</au><au>Boztug, Ali</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Amine-modified maleic anhydride containing terpolymers for the adsorption of uranyl ion in aqueous solutions</atitle><jtitle>Journal of radioanalytical and nuclear chemistry</jtitle><stitle>J Radioanal Nucl Chem</stitle><date>2013-11-01</date><risdate>2013</risdate><volume>298</volume><issue>2</issue><spage>923</spage><epage>930</epage><pages>923-930</pages><issn>0236-5731</issn><eissn>1588-2780</eissn><abstract>Maleic anhydride–styrene–methyl methacrylate (MA–S–MM) terpolymer was prepared. It was modified by ethylenediamine (EDA) and diethylenetriamine (DETA) in order to get cross-linked polymers bearing carboxyl and amine groups. Modified polymers used as an adsorbent for the removal of UO
2
2+
from water. The characterizations of structures of all the polymers were performed by Fourier transform infrared. The adsorptive features of adsorbents were then investigated for UO
2
2+
in view of dependency on ion concentration, pH, temperature and kinetics. Experimentally obtained isotherms were evaluated with reference to Langmuir, Freundlich and Dubinin–Radushkevich models. The maximum monolayer adsorption capacity for UO
2
2+
was found to be 1.59 and 2.43 mol kg
−1
for EDA–MA–S–MM and DETA–MA–S–MM, respectively. It can be said that the new modified polymers prepared in our laboratory have been suggested as new adsorbents for uranyl ions.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10967-013-2529-4</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0236-5731 |
| ispartof | Journal of radioanalytical and nuclear chemistry, 2013-11, Vol.298 (2), p.923-930 |
| issn | 0236-5731 1588-2780 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1506366787 |
| source | SpringerLink Journals |
| subjects | Adsorbents Adsorption Amines Chemical properties Chemistry Chemistry and Materials Science Crosslinking DETA Diagnostic Radiology Electronic design automation Ethylenediamines Fourier transforms Hadrons Heavy Ions Inorganic Chemistry Maleic anhydride Methyl methacrylate Nuclear Chemistry Nuclear Physics Physical Chemistry Polymers Terpolymers |
| title | Amine-modified maleic anhydride containing terpolymers for the adsorption of uranyl ion in aqueous solutions |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-09T13%3A20%3A06IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale_proqu&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Amine-modified%20maleic%20anhydride%20containing%20terpolymers%20for%20the%20adsorption%20of%20uranyl%20ion%20in%20aqueous%20solutions&rft.jtitle=Journal%20of%20radioanalytical%20and%20nuclear%20chemistry&rft.au=Simsek,%20Selcuk&rft.date=2013-11-01&rft.volume=298&rft.issue=2&rft.spage=923&rft.epage=930&rft.pages=923-930&rft.issn=0236-5731&rft.eissn=1588-2780&rft_id=info:doi/10.1007/s10967-013-2529-4&rft_dat=%3Cgale_proqu%3EA348568804%3C/gale_proqu%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1506366787&rft_id=info:pmid/&rft_galeid=A348568804&rfr_iscdi=true |