Optical and electrical properties of new organic thin film

This paper describes a new organic thin film (OTF) (50 nm) which was deposited by spin coated at room temperature. OTF has been constructed from chemically synthesized poly(pentachlorophenyl methacrylate- co -glycidyl methacrylate). Optical properties of the obtained poly(pentachlorophenyl methacryl...

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Veröffentlicht in:Journal of materials science. Materials in electronics 2013-12, Vol.24 (12), p.4833-4838
Hauptverfasser: Çavuş, Hatice Kanbur, Voigt, Monika M., Şahingöz, Recep
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container_issue 12
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container_title Journal of materials science. Materials in electronics
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creator Çavuş, Hatice Kanbur
Voigt, Monika M.
Şahingöz, Recep
description This paper describes a new organic thin film (OTF) (50 nm) which was deposited by spin coated at room temperature. OTF has been constructed from chemically synthesized poly(pentachlorophenyl methacrylate- co -glycidyl methacrylate). Optical properties of the obtained poly(pentachlorophenyl methacrylate- co -glycidyl methacrylate) in solution were tested by ultraviolet–visible absorption spectroscopy. The analysis of the optical absorption data revealed an existence of a direct and indirect transition optical band gap (E g ). The electrical properties of ITO/PEDOT:PSS/OTF/Al heterojunction structure has been investigated by forward and reverse bias current–voltage (I–V) measurements at room temperature. The main electrical parameters such as barrier height (Φ Bo ), ideality factor (n) and reverse saturation current (I o ) have been calculated by applying thermionic emission theory as 0.80 eV, 3.69, 1.86 × 10 −8  A respectively. Additionally, series resistance (R s ), Φ Bo and n were calculated from the forward bias I–V data using the methods of Cheung and Cheung with Norde and showed that these methods can be applied successfully for this structure.
doi_str_mv 10.1007/s10854-013-1483-9
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OTF has been constructed from chemically synthesized poly(pentachlorophenyl methacrylate- co -glycidyl methacrylate). Optical properties of the obtained poly(pentachlorophenyl methacrylate- co -glycidyl methacrylate) in solution were tested by ultraviolet–visible absorption spectroscopy. The analysis of the optical absorption data revealed an existence of a direct and indirect transition optical band gap (E g ). The electrical properties of ITO/PEDOT:PSS/OTF/Al heterojunction structure has been investigated by forward and reverse bias current–voltage (I–V) measurements at room temperature. The main electrical parameters such as barrier height (Φ Bo ), ideality factor (n) and reverse saturation current (I o ) have been calculated by applying thermionic emission theory as 0.80 eV, 3.69, 1.86 × 10 −8  A respectively. Additionally, series resistance (R s ), Φ Bo and n were calculated from the forward bias I–V data using the methods of Cheung and Cheung with Norde and showed that these methods can be applied successfully for this structure.</description><identifier>ISSN: 0957-4522</identifier><identifier>EISSN: 1573-482X</identifier><identifier>DOI: 10.1007/s10854-013-1483-9</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Absorption spectroscopy ; Applied sciences ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Compound structure devices ; Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Cross-disciplinary physics: materials science; rheology ; Electronics ; Exact sciences and technology ; Liquid phase epitaxy; deposition from liquid phases (melts, solutions, and surface layers on liquids) ; Materials ; Materials Science ; Methods of deposition of films and coatings; film growth and epitaxy ; Optical and Electronic Materials ; Optical constants: refractive index, complex dielectric constant, absorption, reflection and transmission coefficients, emissivity ; Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation ; Optical properties of bulk materials and thin films ; Physics ; Semiconductor electronics. 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Materials in electronics</title><addtitle>J Mater Sci: Mater Electron</addtitle><description>This paper describes a new organic thin film (OTF) (50 nm) which was deposited by spin coated at room temperature. OTF has been constructed from chemically synthesized poly(pentachlorophenyl methacrylate- co -glycidyl methacrylate). Optical properties of the obtained poly(pentachlorophenyl methacrylate- co -glycidyl methacrylate) in solution were tested by ultraviolet–visible absorption spectroscopy. The analysis of the optical absorption data revealed an existence of a direct and indirect transition optical band gap (E g ). The electrical properties of ITO/PEDOT:PSS/OTF/Al heterojunction structure has been investigated by forward and reverse bias current–voltage (I–V) measurements at room temperature. The main electrical parameters such as barrier height (Φ Bo ), ideality factor (n) and reverse saturation current (I o ) have been calculated by applying thermionic emission theory as 0.80 eV, 3.69, 1.86 × 10 −8  A respectively. 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Materials in electronics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Çavuş, Hatice Kanbur</au><au>Voigt, Monika M.</au><au>Şahingöz, Recep</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Optical and electrical properties of new organic thin film</atitle><jtitle>Journal of materials science. Materials in electronics</jtitle><stitle>J Mater Sci: Mater Electron</stitle><date>2013-12-01</date><risdate>2013</risdate><volume>24</volume><issue>12</issue><spage>4833</spage><epage>4838</epage><pages>4833-4838</pages><issn>0957-4522</issn><eissn>1573-482X</eissn><abstract>This paper describes a new organic thin film (OTF) (50 nm) which was deposited by spin coated at room temperature. OTF has been constructed from chemically synthesized poly(pentachlorophenyl methacrylate- co -glycidyl methacrylate). Optical properties of the obtained poly(pentachlorophenyl methacrylate- co -glycidyl methacrylate) in solution were tested by ultraviolet–visible absorption spectroscopy. The analysis of the optical absorption data revealed an existence of a direct and indirect transition optical band gap (E g ). The electrical properties of ITO/PEDOT:PSS/OTF/Al heterojunction structure has been investigated by forward and reverse bias current–voltage (I–V) measurements at room temperature. The main electrical parameters such as barrier height (Φ Bo ), ideality factor (n) and reverse saturation current (I o ) have been calculated by applying thermionic emission theory as 0.80 eV, 3.69, 1.86 × 10 −8  A respectively. Additionally, series resistance (R s ), Φ Bo and n were calculated from the forward bias I–V data using the methods of Cheung and Cheung with Norde and showed that these methods can be applied successfully for this structure.</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1007/s10854-013-1483-9</doi><tpages>6</tpages></addata></record>
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subjects Absorption spectroscopy
Applied sciences
Characterization and Evaluation of Materials
Chemistry and Materials Science
Compound structure devices
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Cross-disciplinary physics: materials science
rheology
Electronics
Exact sciences and technology
Liquid phase epitaxy
deposition from liquid phases (melts, solutions, and surface layers on liquids)
Materials
Materials Science
Methods of deposition of films and coatings
film growth and epitaxy
Optical and Electronic Materials
Optical constants: refractive index, complex dielectric constant, absorption, reflection and transmission coefficients, emissivity
Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation
Optical properties of bulk materials and thin films
Physics
Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices
title Optical and electrical properties of new organic thin film
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