Effect of residence time on chemical and structural properties of hydrochar obtained by hydrothermal carbonization of water hyacinth
Hydrothermal carbonization of water hyacinth was experimentally conducted in the range of 30 min to 24 h at 240 °C, chemical and structural properties of hydrochar products were investigated. Oxygen/carbon ratio, and hydrogen/carbon ratio in all hydrochar products were 0.19–0.45, and 0.94 to 1.51. H...
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Veröffentlicht in: | Energy (Oxford) 2013-09, Vol.58, p.376-383 |
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creator | Gao, Ying Wang, Xianhua Wang, Jun Li, Xiangpeng Cheng, Jianjun Yang, Haiping Chen, Hanping |
description | Hydrothermal carbonization of water hyacinth was experimentally conducted in the range of 30 min to 24 h at 240 °C, chemical and structural properties of hydrochar products were investigated. Oxygen/carbon ratio, and hydrogen/carbon ratio in all hydrochar products were 0.19–0.45, and 0.94 to 1.51. Higher heating value of hydrochar products was 16.83 MJ/kg to 20.63 MJ/kg. Residence time had little effect on the chemical properties of hydrochar samples after 4 h. When the residence time was more than 4 h, hydrochar products exhibited almost the same pyrolysis behavior under TGA (thermogravimetric analysis). Hydrochar developed better structural characterization as time increased. The formation of microspheres on the surface of hydrochar was discussed, and transformation of cellulose and hemicellulose should be the reaction for microsphere production.
•We choose water hyacinth as raw material.•Hydrochar products can be characterized as high heating value and carbon rich with residence time increasing.•Residence time had little effect on the chemical properties of hydrochar.•Hydrochar developed better structural characterization as time increased. |
doi_str_mv | 10.1016/j.energy.2013.06.023 |
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•We choose water hyacinth as raw material.•Hydrochar products can be characterized as high heating value and carbon rich with residence time increasing.•Residence time had little effect on the chemical properties of hydrochar.•Hydrochar developed better structural characterization as time increased.</description><subject>Applied sciences</subject><subject>carbon</subject><subject>Carbonation</subject><subject>cellulose</subject><subject>Eichhornia crassipes</subject><subject>Energy</subject><subject>Exact sciences and technology</subject><subject>heat</subject><subject>hemicellulose</subject><subject>Hydrochar</subject><subject>hydrochars</subject><subject>hydrogen</subject><subject>Hydrothermal</subject><subject>hydrothermal carbonization</subject><subject>oxygen</subject><subject>physicochemical properties</subject><subject>pyrolysis</subject><subject>thermogravimetry</subject><subject>Water hyacinth</subject><issn>0360-5442</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNqFkc1u1DAUhbMoEqXtGyA1GyQ2k_ovjrNBQlULSJVY0K4t_1w3Hk3i4doDGtY8OB6lYgkry9Z3ju37Nc1bSjpKqLzZdrAAPh87RijviOwI42fNOeGSbHoh2OvmTc5bQkivxvG8-X0XArjSptAi5OhhcdCWOEObltZNMEdndq1ZfJsLHlw5YN3uMe0BS4R8yk1Hj8lNBttki4kL-NYe19MyAc414AzatMRfpsRaWzM_TQGsjHFxKdNl8yqYXYarl_Wiebq_e7z9vHn4-unL7ceHjRMjK5veCBaYZd5SLwcIwhkpRtELr4QdlfIcfFCSDkCDVY7agVpw1lM1WgVA-EXzfu2tH_h-gFz0HLOD3c4skA5Z0570nEtF-P9RIUUvGR9YRcWKOkw5IwS9xzgbPGpK9MmJ3urViT450UTq6qTG3r3cYHKdcUCzuJj_ZtkguRx7UbnrlQsmafOMlXn6VotkdSiFGodKfFgJqLP7EQF1dvEk0kesbrVP8d9P-QO8ULLS</recordid><startdate>20130901</startdate><enddate>20130901</enddate><creator>Gao, Ying</creator><creator>Wang, Xianhua</creator><creator>Wang, Jun</creator><creator>Li, Xiangpeng</creator><creator>Cheng, Jianjun</creator><creator>Yang, Haiping</creator><creator>Chen, Hanping</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>FBQ</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7ST</scope><scope>C1K</scope><scope>SOI</scope></search><sort><creationdate>20130901</creationdate><title>Effect of residence time on chemical and structural properties of hydrochar obtained by hydrothermal carbonization of water hyacinth</title><author>Gao, Ying ; Wang, Xianhua ; Wang, Jun ; Li, Xiangpeng ; Cheng, Jianjun ; Yang, Haiping ; Chen, Hanping</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c492t-5a42f2b2db1d67ef4ca649454d84b988d3edf8617e1fb8c1b71becbd189b8ee03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Applied sciences</topic><topic>carbon</topic><topic>Carbonation</topic><topic>cellulose</topic><topic>Eichhornia crassipes</topic><topic>Energy</topic><topic>Exact sciences and technology</topic><topic>heat</topic><topic>hemicellulose</topic><topic>Hydrochar</topic><topic>hydrochars</topic><topic>hydrogen</topic><topic>Hydrothermal</topic><topic>hydrothermal carbonization</topic><topic>oxygen</topic><topic>physicochemical properties</topic><topic>pyrolysis</topic><topic>thermogravimetry</topic><topic>Water hyacinth</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gao, Ying</creatorcontrib><creatorcontrib>Wang, Xianhua</creatorcontrib><creatorcontrib>Wang, Jun</creatorcontrib><creatorcontrib>Li, Xiangpeng</creatorcontrib><creatorcontrib>Cheng, Jianjun</creatorcontrib><creatorcontrib>Yang, Haiping</creatorcontrib><creatorcontrib>Chen, Hanping</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Environment Abstracts</collection><jtitle>Energy (Oxford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gao, Ying</au><au>Wang, Xianhua</au><au>Wang, Jun</au><au>Li, Xiangpeng</au><au>Cheng, Jianjun</au><au>Yang, Haiping</au><au>Chen, Hanping</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of residence time on chemical and structural properties of hydrochar obtained by hydrothermal carbonization of water hyacinth</atitle><jtitle>Energy (Oxford)</jtitle><date>2013-09-01</date><risdate>2013</risdate><volume>58</volume><spage>376</spage><epage>383</epage><pages>376-383</pages><issn>0360-5442</issn><coden>ENEYDS</coden><abstract>Hydrothermal carbonization of water hyacinth was experimentally conducted in the range of 30 min to 24 h at 240 °C, chemical and structural properties of hydrochar products were investigated. Oxygen/carbon ratio, and hydrogen/carbon ratio in all hydrochar products were 0.19–0.45, and 0.94 to 1.51. Higher heating value of hydrochar products was 16.83 MJ/kg to 20.63 MJ/kg. Residence time had little effect on the chemical properties of hydrochar samples after 4 h. When the residence time was more than 4 h, hydrochar products exhibited almost the same pyrolysis behavior under TGA (thermogravimetric analysis). Hydrochar developed better structural characterization as time increased. The formation of microspheres on the surface of hydrochar was discussed, and transformation of cellulose and hemicellulose should be the reaction for microsphere production.
•We choose water hyacinth as raw material.•Hydrochar products can be characterized as high heating value and carbon rich with residence time increasing.•Residence time had little effect on the chemical properties of hydrochar.•Hydrochar developed better structural characterization as time increased.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.energy.2013.06.023</doi><tpages>8</tpages></addata></record> |
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subjects | Applied sciences carbon Carbonation cellulose Eichhornia crassipes Energy Exact sciences and technology heat hemicellulose Hydrochar hydrochars hydrogen Hydrothermal hydrothermal carbonization oxygen physicochemical properties pyrolysis thermogravimetry Water hyacinth |
title | Effect of residence time on chemical and structural properties of hydrochar obtained by hydrothermal carbonization of water hyacinth |
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