The Pre-concentration and determination of Iridium and Palladium in environmental water by imprinted polymer-based method
In this study, the imprinted aniline-formaldehyde was used as an adsorbent for removal of Iridium and Palladium ions from aqueous solutions through batch equilibrium. The sorbent was characterized by fourier transform infrared spectroscopy. The influence of pH, equilibrium time, temperature and init...
Gespeichert in:
| Veröffentlicht in: | International journal of environmental science and technology (Tehran) 2013-09, Vol.10 (5), p.1091-1102 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1102 |
|---|---|
| container_issue | 5 |
| container_start_page | 1091 |
| container_title | International journal of environmental science and technology (Tehran) |
| container_volume | 10 |
| creator | Kalal, H. Sid Taghiof, M Hoveid, H Pakizvand, N Vahidi, H Panahi, H.A Tavangari, S |
| description | In this study, the imprinted aniline-formaldehyde was used as an
adsorbent for removal of Iridium and Palladium ions from aqueous
solutions through batch equilibrium. The sorbent was characterized by
fourier transform infrared spectroscopy. The influence of pH,
equilibrium time, temperature and initial concentration of metal ions
on adsorbed amount of both ions were investigated. The maximum
adsorption capacity in initial concentration of 100 mg/L was found to
be 12.5 mg/g at pH 7.0 and 14.3 mg/g at pH 8.0 for Iridium and
Palladium, respectively. In addition, the best desorption of the metal
ions from resin was obtained by 0.5 mol/L nitric acid as eluting agent.
The profile of both ions uptake on this sorbent reflects good
accessibility of the chelating sites in the imprinted
aniline-formaldehyde. Langmuir, Freundlich, Temkin and Redlich-Peterson
isotherm models were applied to analyze the experimental data.
Moreover, Langmuir linear method was used to obtain the isotherm
parameters. However, Langmuir type II achieved the highest coefficient
which led to the best fit for the palladium and the best fit for
Iridium obtained from linear Redlich-Peterson. However, the
thermodynamic parameters (ΔG°, ΔH°, and
ΔS°) were also determined using the equilibrium constant
values obtained at different temperatures. The results showed that the
adsorption for Iridium and Palladium ions was spontaneous nature and
endothermic. Moreover, the method was applied for the determination of
both ions from tap water samples. |
| doi_str_mv | 10.1007/s13762-013-0308-y |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1505329070</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1505329070</sourcerecordid><originalsourceid>FETCH-LOGICAL-b431t-12c78a5409e8105a129d3f7d431bd0cdce02067dd56974bc5ee6d9db27b9c3313</originalsourceid><addsrcrecordid>eNp9kcFO3DAQhqOqlUppH6A3S730YpixnXhzrBAFJCQ40LPl2LPFKLG3dpYqb4-X0KrqgZM9M_83M_bfNJ8RThBAnxaUuhMcUHKQsOHLm-YItWy56CS8fbmj0uJ986GUBwDVKYVHzXJ3T-w2E3cpOopztnNIkdnomaeZ8hTimklbdpWDD_vpuXhrx9E-RyEyio8hpzhV3o7st60cGxYWpl0OcSbPdmlcJsp8sKVGE833yX9s3m3tWOjTy3nc_Ph-fnd2ya9vLq7Ovl3zQUmcOQqnN7ZV0NMGobUoei-32tfi4MF5RyCg0963Xa_V4Fqizvd-EHronZQoj5uva99dTr_2VGYzheKorh8p7YvBFlopetBQpV_-kz6kfY51O4OqV6BVB31V4apyOZWSaWvqMyebF4NgDmaY1QxTzTAHM8xSGbEy5fAlPyn_0_kV6GSFhpDGEOnvHJeDNX-Sdcsyo0To5BOkdp-M</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1494074609</pqid></control><display><type>article</type><title>The Pre-concentration and determination of Iridium and Palladium in environmental water by imprinted polymer-based method</title><source>Free Full-Text Journals in Chemistry</source><source>SpringerLink Journals - AutoHoldings</source><creator>Kalal, H. Sid ; Taghiof, M ; Hoveid, H ; Pakizvand, N ; Vahidi, H ; Panahi, H.A ; Tavangari, S</creator><creatorcontrib>Kalal, H. Sid ; Taghiof, M ; Hoveid, H ; Pakizvand, N ; Vahidi, H ; Panahi, H.A ; Tavangari, S</creatorcontrib><description>In this study, the imprinted aniline-formaldehyde was used as an
adsorbent for removal of Iridium and Palladium ions from aqueous
solutions through batch equilibrium. The sorbent was characterized by
fourier transform infrared spectroscopy. The influence of pH,
equilibrium time, temperature and initial concentration of metal ions
on adsorbed amount of both ions were investigated. The maximum
adsorption capacity in initial concentration of 100 mg/L was found to
be 12.5 mg/g at pH 7.0 and 14.3 mg/g at pH 8.0 for Iridium and
Palladium, respectively. In addition, the best desorption of the metal
ions from resin was obtained by 0.5 mol/L nitric acid as eluting agent.
The profile of both ions uptake on this sorbent reflects good
accessibility of the chelating sites in the imprinted
aniline-formaldehyde. Langmuir, Freundlich, Temkin and Redlich-Peterson
isotherm models were applied to analyze the experimental data.
Moreover, Langmuir linear method was used to obtain the isotherm
parameters. However, Langmuir type II achieved the highest coefficient
which led to the best fit for the palladium and the best fit for
Iridium obtained from linear Redlich-Peterson. However, the
thermodynamic parameters (ΔG°, ΔH°, and
ΔS°) were also determined using the equilibrium constant
values obtained at different temperatures. The results showed that the
adsorption for Iridium and Palladium ions was spontaneous nature and
endothermic. Moreover, the method was applied for the determination of
both ions from tap water samples.</description><identifier>ISSN: 1735-1472</identifier><identifier>EISSN: 1735-2630</identifier><identifier>DOI: 10.1007/s13762-013-0308-y</identifier><language>eng</language><publisher>Berlin/Heidelberg: Center for Environment and Energy Research and Studies (CEERS)</publisher><subject>Adsorption ; Adsorption isotherms ; Aquatic Pollution ; Earth and Environmental Science ; Ecotoxicology ; Environment ; Environmental Chemistry ; Environmental Science and Engineering ; Error analysis ; Kinetic studies ; Kinetics ; Original Paper ; Polymers ; Soil Science & Conservation ; Spectrum analysis ; Thermodynamics ; Waste Water Technology ; Water Management ; Water Pollution Control</subject><ispartof>International journal of environmental science and technology (Tehran), 2013-09, Vol.10 (5), p.1091-1102</ispartof><rights>2013 - Center for Environment and Energy Research and Studies (CEERS)</rights><rights>Islamic Azad University (IAU) 2013</rights><rights>Copyright Springer Science & Business Media Sep 2013</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-b431t-12c78a5409e8105a129d3f7d431bd0cdce02067dd56974bc5ee6d9db27b9c3313</citedby><cites>FETCH-LOGICAL-b431t-12c78a5409e8105a129d3f7d431bd0cdce02067dd56974bc5ee6d9db27b9c3313</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s13762-013-0308-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s13762-013-0308-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Kalal, H. Sid</creatorcontrib><creatorcontrib>Taghiof, M</creatorcontrib><creatorcontrib>Hoveid, H</creatorcontrib><creatorcontrib>Pakizvand, N</creatorcontrib><creatorcontrib>Vahidi, H</creatorcontrib><creatorcontrib>Panahi, H.A</creatorcontrib><creatorcontrib>Tavangari, S</creatorcontrib><title>The Pre-concentration and determination of Iridium and Palladium in environmental water by imprinted polymer-based method</title><title>International journal of environmental science and technology (Tehran)</title><addtitle>Int. J. Environ. Sci. Technol</addtitle><description>In this study, the imprinted aniline-formaldehyde was used as an
adsorbent for removal of Iridium and Palladium ions from aqueous
solutions through batch equilibrium. The sorbent was characterized by
fourier transform infrared spectroscopy. The influence of pH,
equilibrium time, temperature and initial concentration of metal ions
on adsorbed amount of both ions were investigated. The maximum
adsorption capacity in initial concentration of 100 mg/L was found to
be 12.5 mg/g at pH 7.0 and 14.3 mg/g at pH 8.0 for Iridium and
Palladium, respectively. In addition, the best desorption of the metal
ions from resin was obtained by 0.5 mol/L nitric acid as eluting agent.
The profile of both ions uptake on this sorbent reflects good
accessibility of the chelating sites in the imprinted
aniline-formaldehyde. Langmuir, Freundlich, Temkin and Redlich-Peterson
isotherm models were applied to analyze the experimental data.
Moreover, Langmuir linear method was used to obtain the isotherm
parameters. However, Langmuir type II achieved the highest coefficient
which led to the best fit for the palladium and the best fit for
Iridium obtained from linear Redlich-Peterson. However, the
thermodynamic parameters (ΔG°, ΔH°, and
ΔS°) were also determined using the equilibrium constant
values obtained at different temperatures. The results showed that the
adsorption for Iridium and Palladium ions was spontaneous nature and
endothermic. Moreover, the method was applied for the determination of
both ions from tap water samples.</description><subject>Adsorption</subject><subject>Adsorption isotherms</subject><subject>Aquatic Pollution</subject><subject>Earth and Environmental Science</subject><subject>Ecotoxicology</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Science and Engineering</subject><subject>Error analysis</subject><subject>Kinetic studies</subject><subject>Kinetics</subject><subject>Original Paper</subject><subject>Polymers</subject><subject>Soil Science & Conservation</subject><subject>Spectrum analysis</subject><subject>Thermodynamics</subject><subject>Waste Water Technology</subject><subject>Water Management</subject><subject>Water Pollution Control</subject><issn>1735-1472</issn><issn>1735-2630</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>RBI</sourceid><sourceid>8G5</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNp9kcFO3DAQhqOqlUppH6A3S730YpixnXhzrBAFJCQ40LPl2LPFKLG3dpYqb4-X0KrqgZM9M_83M_bfNJ8RThBAnxaUuhMcUHKQsOHLm-YItWy56CS8fbmj0uJ986GUBwDVKYVHzXJ3T-w2E3cpOopztnNIkdnomaeZ8hTimklbdpWDD_vpuXhrx9E-RyEyio8hpzhV3o7st60cGxYWpl0OcSbPdmlcJsp8sKVGE833yX9s3m3tWOjTy3nc_Ph-fnd2ya9vLq7Ovl3zQUmcOQqnN7ZV0NMGobUoei-32tfi4MF5RyCg0963Xa_V4Fqizvd-EHronZQoj5uva99dTr_2VGYzheKorh8p7YvBFlopetBQpV_-kz6kfY51O4OqV6BVB31V4apyOZWSaWvqMyebF4NgDmaY1QxTzTAHM8xSGbEy5fAlPyn_0_kV6GSFhpDGEOnvHJeDNX-Sdcsyo0To5BOkdp-M</recordid><startdate>20130901</startdate><enddate>20130901</enddate><creator>Kalal, H. Sid</creator><creator>Taghiof, M</creator><creator>Hoveid, H</creator><creator>Pakizvand, N</creator><creator>Vahidi, H</creator><creator>Panahi, H.A</creator><creator>Tavangari, S</creator><general>Center for Environment and Energy Research and Studies (CEERS)</general><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>RBI</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7QO</scope><scope>7ST</scope><scope>7T7</scope><scope>7XB</scope><scope>8AF</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>8G5</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>C1K</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FR3</scope><scope>GNUQQ</scope><scope>GUQSH</scope><scope>HCIFZ</scope><scope>L6V</scope><scope>M2O</scope><scope>M7S</scope><scope>MBDVC</scope><scope>P64</scope><scope>PADUT</scope><scope>PATMY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>PYCSY</scope><scope>Q9U</scope><scope>SOI</scope><scope>7QH</scope><scope>7UA</scope><scope>F1W</scope><scope>H97</scope><scope>L.G</scope></search><sort><creationdate>20130901</creationdate><title>The Pre-concentration and determination of Iridium and Palladium in environmental water by imprinted polymer-based method</title><author>Kalal, H. Sid ; Taghiof, M ; Hoveid, H ; Pakizvand, N ; Vahidi, H ; Panahi, H.A ; Tavangari, S</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-b431t-12c78a5409e8105a129d3f7d431bd0cdce02067dd56974bc5ee6d9db27b9c3313</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Adsorption</topic><topic>Adsorption isotherms</topic><topic>Aquatic Pollution</topic><topic>Earth and Environmental Science</topic><topic>Ecotoxicology</topic><topic>Environment</topic><topic>Environmental Chemistry</topic><topic>Environmental Science and Engineering</topic><topic>Error analysis</topic><topic>Kinetic studies</topic><topic>Kinetics</topic><topic>Original Paper</topic><topic>Polymers</topic><topic>Soil Science & Conservation</topic><topic>Spectrum analysis</topic><topic>Thermodynamics</topic><topic>Waste Water Technology</topic><topic>Water Management</topic><topic>Water Pollution Control</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kalal, H. Sid</creatorcontrib><creatorcontrib>Taghiof, M</creatorcontrib><creatorcontrib>Hoveid, H</creatorcontrib><creatorcontrib>Pakizvand, N</creatorcontrib><creatorcontrib>Vahidi, H</creatorcontrib><creatorcontrib>Panahi, H.A</creatorcontrib><creatorcontrib>Tavangari, S</creatorcontrib><collection>Bioline International</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Biotechnology Research Abstracts</collection><collection>Environment Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>STEM Database</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Research Library (Alumni Edition)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>Agricultural & Environmental Science Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>Natural Science Collection</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Engineering Research Database</collection><collection>ProQuest Central Student</collection><collection>Research Library Prep</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Engineering Collection</collection><collection>Research Library</collection><collection>Engineering Database</collection><collection>Research Library (Corporate)</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Research Library China</collection><collection>Environmental Science Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><collection>Environmental Science Collection</collection><collection>ProQuest Central Basic</collection><collection>Environment Abstracts</collection><collection>Aqualine</collection><collection>Water Resources Abstracts</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 3: Aquatic Pollution & Environmental Quality</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><jtitle>International journal of environmental science and technology (Tehran)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kalal, H. Sid</au><au>Taghiof, M</au><au>Hoveid, H</au><au>Pakizvand, N</au><au>Vahidi, H</au><au>Panahi, H.A</au><au>Tavangari, S</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Pre-concentration and determination of Iridium and Palladium in environmental water by imprinted polymer-based method</atitle><jtitle>International journal of environmental science and technology (Tehran)</jtitle><stitle>Int. J. Environ. Sci. Technol</stitle><date>2013-09-01</date><risdate>2013</risdate><volume>10</volume><issue>5</issue><spage>1091</spage><epage>1102</epage><pages>1091-1102</pages><issn>1735-1472</issn><eissn>1735-2630</eissn><abstract>In this study, the imprinted aniline-formaldehyde was used as an
adsorbent for removal of Iridium and Palladium ions from aqueous
solutions through batch equilibrium. The sorbent was characterized by
fourier transform infrared spectroscopy. The influence of pH,
equilibrium time, temperature and initial concentration of metal ions
on adsorbed amount of both ions were investigated. The maximum
adsorption capacity in initial concentration of 100 mg/L was found to
be 12.5 mg/g at pH 7.0 and 14.3 mg/g at pH 8.0 for Iridium and
Palladium, respectively. In addition, the best desorption of the metal
ions from resin was obtained by 0.5 mol/L nitric acid as eluting agent.
The profile of both ions uptake on this sorbent reflects good
accessibility of the chelating sites in the imprinted
aniline-formaldehyde. Langmuir, Freundlich, Temkin and Redlich-Peterson
isotherm models were applied to analyze the experimental data.
Moreover, Langmuir linear method was used to obtain the isotherm
parameters. However, Langmuir type II achieved the highest coefficient
which led to the best fit for the palladium and the best fit for
Iridium obtained from linear Redlich-Peterson. However, the
thermodynamic parameters (ΔG°, ΔH°, and
ΔS°) were also determined using the equilibrium constant
values obtained at different temperatures. The results showed that the
adsorption for Iridium and Palladium ions was spontaneous nature and
endothermic. Moreover, the method was applied for the determination of
both ions from tap water samples.</abstract><cop>Berlin/Heidelberg</cop><pub>Center for Environment and Energy Research and Studies (CEERS)</pub><doi>10.1007/s13762-013-0308-y</doi><tpages>12</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1735-1472 |
| ispartof | International journal of environmental science and technology (Tehran), 2013-09, Vol.10 (5), p.1091-1102 |
| issn | 1735-1472 1735-2630 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1505329070 |
| source | Free Full-Text Journals in Chemistry; SpringerLink Journals - AutoHoldings |
| subjects | Adsorption Adsorption isotherms Aquatic Pollution Earth and Environmental Science Ecotoxicology Environment Environmental Chemistry Environmental Science and Engineering Error analysis Kinetic studies Kinetics Original Paper Polymers Soil Science & Conservation Spectrum analysis Thermodynamics Waste Water Technology Water Management Water Pollution Control |
| title | The Pre-concentration and determination of Iridium and Palladium in environmental water by imprinted polymer-based method |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-11T14%3A00%3A38IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=The%20Pre-concentration%20and%20determination%20of%20Iridium%20and%20Palladium%20in%20environmental%20water%20by%20imprinted%20polymer-based%20method&rft.jtitle=International%20journal%20of%20environmental%20science%20and%20technology%20(Tehran)&rft.au=Kalal,%20H.%20Sid&rft.date=2013-09-01&rft.volume=10&rft.issue=5&rft.spage=1091&rft.epage=1102&rft.pages=1091-1102&rft.issn=1735-1472&rft.eissn=1735-2630&rft_id=info:doi/10.1007/s13762-013-0308-y&rft_dat=%3Cproquest_cross%3E1505329070%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1494074609&rft_id=info:pmid/&rfr_iscdi=true |