Oxidative Radical Arylation of Anilines with Arylhydrazines and Dioxygen from Air

Substituted 2-aminobiphenyls have been prepared from arylhydrazine hydrochlorides and anilines in biphasic radical arylation reactions with dioxygen from air as a most simple and readily available oxidant. Under optimized conditions, the free amino functionality of the aniline leads to high ortho:me...

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Veröffentlicht in:	Journal of organic chemistry 2014-03, Vol.79 (5), p.2314-2320
Hauptverfasser:	Hofmann, Josefa, Jasch, Hannelore, Heinrich, Markus R
Format:	Artikel
Sprache:	eng
Schlagworte:	Air Aminobiphenyl Compounds - chemical synthesis Aminobiphenyl Compounds - chemistry Aniline Compounds - chemistry Catalysis Hydrazines - chemistry Molecular Structure Oxidation-Reduction Oxygen - chemistry Stereoisomerism
Online-Zugang:	Volltext
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