Predicting Cellulose Solvating Capabilities of Acid-Base Conjugate Ionic Liquids

Different acid–base conjugates were made by combining a range of bases and superbases with acetic and propionic acid. Only the combinations that contained superbases were capable of dissolving cellulose. Proton affinities were calculated for the bases. A range, within which cellulose dissolution occ...

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Veröffentlicht in:	ChemSusChem 2013-11, Vol.6 (11), p.2161-2169
Hauptverfasser:	Parviainen, Arno, King, Alistair W. T., Mutikainen, Ilpo, Hummel, Michael, Selg, Christoph, Hauru, Lauri K. J., Sixta, Herbert, Kilpeläinen, Ilkka
Format:	Artikel
Sprache:	eng
Schlagworte:	ab initio calculations Acetic Acid - chemistry Acids Biomass Cellulose Cellulose - chemistry cellulose dissolution Chemical bonds Hydrogen Bonding hydrogen bonds Hydrogen-Ion Concentration ionic liquids Ionic Liquids - chemistry Ions Liquids Propionates - chemistry Solubility Solvents Viscosity
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