Photochemistry in a 3D Metal–Organic Framework (MOF): Monitoring Intermediates and Reactivity of the fac-to-mer Photoisomerization of Re(diimine)(CO)3Cl Incorporated in a MOF

The mechanism and intermediates in the UV-light-initiated ligand rearrangement of fac-Re(diimine)(CO)3Cl to form the mer isomer, when incorporated into a 3D metal–organic framework (MOF), have been investigated. The structure hosting the rhenium diimine complex is a 3D network with the formula {Mn(D...

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Veröffentlicht in:	Inorganic chemistry 2014-03, Vol.53 (5), p.2606-2612
Hauptverfasser:	Easun, Timothy L, Jia, Junhua, Calladine, James A, Blackmore, Danielle L, Stapleton, Christopher S, Vuong, Khuong Q, Champness, Neil R, George, Michael W
Format:	Artikel
Sprache:	eng
Schlagworte:	Carboxylic Acids - chemistry Imines - chemistry Isomerism Manganese - chemistry Metals - chemistry Molecular Structure Organometallic Compounds - chemistry Photochemistry Quantum Theory Rhenium - chemistry Spectroscopy, Fourier Transform Infrared
Online-Zugang:	Volltext
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