Direct determination and quantification of sulphur forms in heavy petroleum and coals: 2. The sulphur K edge X-ray absorption spectroscopy approach
A sulphur K edge X-ray absorption spectroscopic method has been developed for the direct determination and quantification of the sulphidic and thiophenic forms of organically bound sulphur in non-volatile petroleum and coal samples. XANES spectra were taken of a number of model compounds, mixtures o...
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Veröffentlicht in: | Fuel (Guildford) 1990-08, Vol.69 (8), p.945-949 |
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creator | Gorbaty, Martin L. George, Graham N. Kelemen, Simon R. |
description | A sulphur K edge X-ray absorption spectroscopic method has been developed for the direct determination and quantification of the sulphidic and thiophenic forms of organically bound sulphur in non-volatile petroleum and coal samples. XANES spectra were taken of a number of model compounds, mixtures of model compounds, heavy petroleum and coal samples. A third-derivative analysis of these spectra allowed approximate quantification of the sulphidic and thiophenic components of the model mixtures and the heavy petroleum and coal samples. |
doi_str_mv | 10.1016/0016-2361(90)90002-8 |
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The sulphur K edge X-ray absorption spectroscopy approach</title><source>Elsevier ScienceDirect Journals</source><creator>Gorbaty, Martin L. ; George, Graham N. ; Kelemen, Simon R.</creator><creatorcontrib>Gorbaty, Martin L. ; George, Graham N. ; Kelemen, Simon R.</creatorcontrib><description>A sulphur K edge X-ray absorption spectroscopic method has been developed for the direct determination and quantification of the sulphidic and thiophenic forms of organically bound sulphur in non-volatile petroleum and coal samples. XANES spectra were taken of a number of model compounds, mixtures of model compounds, heavy petroleum and coal samples. 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The sulphur K edge X-ray absorption spectroscopy approach</title><title>Fuel (Guildford)</title><description>A sulphur K edge X-ray absorption spectroscopic method has been developed for the direct determination and quantification of the sulphidic and thiophenic forms of organically bound sulphur in non-volatile petroleum and coal samples. XANES spectra were taken of a number of model compounds, mixtures of model compounds, heavy petroleum and coal samples. A third-derivative analysis of these spectra allowed approximate quantification of the sulphidic and thiophenic components of the model mixtures and the heavy petroleum and coal samples.</description><subject>coal</subject><subject>petroleum</subject><subject>sulphur</subject><issn>0016-2361</issn><issn>1873-7153</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1990</creationdate><recordtype>article</recordtype><recordid>eNo9UbtOxDAQtBBIHI8_oHCFoAj4EScOBRI6ngKJ5go6y7HXnFEuDnaCxHfww_juEM2uNDszu5pF6ISSC0podUlyKRiv6FlDzhtCCCvkDppRWfOipoLvotk_ZR8dpPSRObUU5Qz93PoIZsQWRogr3-vRhx7r3uLPSfejd95soeBwmrphOUXsQlwl7Hu8BP31jQcYY-hgWm1kJuguXWF2gRdL-Jc8Y7DvgN-KqL-xblOIw8Y1DXl5DMmEIePDEIM2yyO057IJHP_1Q7S4v1vMH4uX14en-c1LoVnFxoK3lQYtnC1ryo2zrWRNTUwjhLTOEF6BZC7PXF0yKqhlxplKV7Llglnd8kN0urXNWz8nSKNa-WSg63QPYUqKCkLLUshMvN4SIR_z5SGqZDz0BuwmO2WDV5So9SvUOme1zlk1RG1eoST_Be0qgCI</recordid><startdate>19900801</startdate><enddate>19900801</enddate><creator>Gorbaty, Martin L.</creator><creator>George, Graham N.</creator><creator>Kelemen, Simon R.</creator><general>Elsevier Ltd</general><scope>7ST</scope><scope>C1K</scope><scope>SOI</scope></search><sort><creationdate>19900801</creationdate><title>Direct determination and quantification of sulphur forms in heavy petroleum and coals: 2. The sulphur K edge X-ray absorption spectroscopy approach</title><author>Gorbaty, Martin L. ; George, Graham N. ; Kelemen, Simon R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a262t-3b6aea5fd4713cfdb82970c9558dfc036e82f471f742151d2cfc6a68b352dab3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1990</creationdate><topic>coal</topic><topic>petroleum</topic><topic>sulphur</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gorbaty, Martin L.</creatorcontrib><creatorcontrib>George, Graham N.</creatorcontrib><creatorcontrib>Kelemen, Simon R.</creatorcontrib><collection>Environment Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Environment Abstracts</collection><jtitle>Fuel (Guildford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gorbaty, Martin L.</au><au>George, Graham N.</au><au>Kelemen, Simon R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Direct determination and quantification of sulphur forms in heavy petroleum and coals: 2. The sulphur K edge X-ray absorption spectroscopy approach</atitle><jtitle>Fuel (Guildford)</jtitle><date>1990-08-01</date><risdate>1990</risdate><volume>69</volume><issue>8</issue><spage>945</spage><epage>949</epage><pages>945-949</pages><issn>0016-2361</issn><eissn>1873-7153</eissn><abstract>A sulphur K edge X-ray absorption spectroscopic method has been developed for the direct determination and quantification of the sulphidic and thiophenic forms of organically bound sulphur in non-volatile petroleum and coal samples. XANES spectra were taken of a number of model compounds, mixtures of model compounds, heavy petroleum and coal samples. A third-derivative analysis of these spectra allowed approximate quantification of the sulphidic and thiophenic components of the model mixtures and the heavy petroleum and coal samples.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/0016-2361(90)90002-8</doi><tpages>5</tpages></addata></record> |
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source | Elsevier ScienceDirect Journals |
subjects | coal petroleum sulphur |
title | Direct determination and quantification of sulphur forms in heavy petroleum and coals: 2. The sulphur K edge X-ray absorption spectroscopy approach |
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