Redox Properties of Structural Fe in Clay Minerals: 3. Relationships between Smectite Redox and Structural Properties

Structural Fe in clay minerals is an important redox-active species in many pristine and contaminated environments as well as in engineered systems. Understanding the extent and kinetics of redox reactions involving Fe-bearing clay minerals has been challenging due to the inability to relate structu...

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Veröffentlicht in:	Environmental science & technology 2013-12, Vol.47 (23), p.13477-13485
Hauptverfasser:	Gorski, Christopher A, Klüpfel, Laura E, Voegelin, Andreas, Sander, Michael, Hofstetter, Thomas B
Format:	Artikel
Sprache:	eng
Schlagworte:	Aluminum Silicates - chemistry Clay Correlation analysis Earth sciences Earth, ocean, space Electrochemical Techniques Electron transfer Electron Transport Engineering and environment geology. Geothermics Exact sciences and technology Iron - chemistry Kinetics Marine and continental quaternary Models, Chemical Oxidation Oxidation-Reduction Pollution, environment geology Silicates - chemistry Spectroscopy, Mossbauer Surficial geology X-Ray Absorption Spectroscopy
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