Spatio-temporal dynamics of heavy metals in sediments of the river estuarine system: Mahanadi basin (India)
Dynamics of heavy metals in the surface sediments of Mahanadi river estuarine system were studied for three different seasons. This study demonstrates that the relative abundance of these metals follows in the order of Fe > Mn > Zn > Pb > Cr > Ni ≥ Co > Cu > Cd. The spatial patt...
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Veröffentlicht in: | Environmental earth sciences 2014-02, Vol.71 (4), p.1893-1909 |
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description | Dynamics of heavy metals in the surface sediments of Mahanadi river estuarine system were studied for three different seasons. This study demonstrates that the relative abundance of these metals follows in the order of Fe > Mn > Zn > Pb > Cr > Ni ≥ Co > Cu > Cd. The spatial pattern of heavy metals supported by enrichment ratio data, suggests their anthropogenic sources possibly from various industrial wastes and municipal wastes as well as agricultural runoff. The metal concentrations in estuarine sediments are relatively higher than in the river due to adsorption/accumulation of metals on sediments during saline mixing, while there is a decreasing trend of heavy metal concentrations towards the marine side. The temporal variations for metals, such as Fe, Mn, Zn, Ni and Pb exhibit higher values during monsoon season, which are related to agricultural runoff. Higher elemental concentrations are observed during pre-monsoon season for these above metals (except Ni) at the polluted stations and for metals, such as Cr, Co and Cd at all sites, which demonstrate the intensity of anthropogenic contribution. R-mode factor analysis reveals that “Fe–Mn oxy hydroxide”, “organic matter”, “CaCO₃”, and “textural variables” factors are the major controlling geochemical factors for the enrichment of heavy metals in river estuarine sediment and their seasonal variations, though their intensities were different for different seasons. The relationships among the stations are highlighted by cluster analysis, represented in dendrograms to categorize different contributing sites for the enrichment of heavy metals in the river estuarine system. |
doi_str_mv | 10.1007/s12665-013-2594-6 |
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This study demonstrates that the relative abundance of these metals follows in the order of Fe > Mn > Zn > Pb > Cr > Ni ≥ Co > Cu > Cd. The spatial pattern of heavy metals supported by enrichment ratio data, suggests their anthropogenic sources possibly from various industrial wastes and municipal wastes as well as agricultural runoff. The metal concentrations in estuarine sediments are relatively higher than in the river due to adsorption/accumulation of metals on sediments during saline mixing, while there is a decreasing trend of heavy metal concentrations towards the marine side. The temporal variations for metals, such as Fe, Mn, Zn, Ni and Pb exhibit higher values during monsoon season, which are related to agricultural runoff. Higher elemental concentrations are observed during pre-monsoon season for these above metals (except Ni) at the polluted stations and for metals, such as Cr, Co and Cd at all sites, which demonstrate the intensity of anthropogenic contribution. R-mode factor analysis reveals that “Fe–Mn oxy hydroxide”, “organic matter”, “CaCO₃”, and “textural variables” factors are the major controlling geochemical factors for the enrichment of heavy metals in river estuarine sediment and their seasonal variations, though their intensities were different for different seasons. The relationships among the stations are highlighted by cluster analysis, represented in dendrograms to categorize different contributing sites for the enrichment of heavy metals in the river estuarine system.</description><identifier>ISSN: 1866-6280</identifier><identifier>EISSN: 1866-6299</identifier><identifier>DOI: 10.1007/s12665-013-2594-6</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer-Verlag</publisher><subject>adsorption ; Agricultural runoff ; anthropogenic activities ; Anthropogenic factors ; Basins ; Biogeosciences ; Brackish ; Cadmium ; calcium carbonate ; chromium ; cluster analysis ; cobalt ; Earth and Environmental Science ; Earth Sciences ; Earth, ocean, space ; Engineering and environment geology. Geothermics ; Environmental Science and Engineering ; estuarine sediments ; Exact sciences and technology ; Factor analysis ; Geochemistry ; Geology ; Heavy metals ; Hydrology ; Hydrology. Hydrogeology ; Hydrology/Water Resources ; Industrial wastes ; iron ; Lead ; manganese ; Metal concentrations ; monsoon season ; Monsoons ; Municipal wastes ; nickel ; Organic matter ; Original Article ; Pollution, environment geology ; Relative abundance ; Rivers ; Seasonal variations ; Seasons ; Sediments ; Terrestrial Pollution ; zinc</subject><ispartof>Environmental earth sciences, 2014-02, Vol.71 (4), p.1893-1909</ispartof><rights>Springer-Verlag Berlin Heidelberg 2013</rights><rights>2015 INIST-CNRS</rights><rights>Springer-Verlag Berlin Heidelberg 2014</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a426t-57b351a5b0db066915a4eb6c66bdf07a9a11537f2bfd8f9099cbd8d604baa2703</citedby><cites>FETCH-LOGICAL-a426t-57b351a5b0db066915a4eb6c66bdf07a9a11537f2bfd8f9099cbd8d604baa2703</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12665-013-2594-6$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12665-013-2594-6$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=28270637$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Sundaray, Sanjay Kumar</creatorcontrib><creatorcontrib>Nayak, Binod Bihari</creatorcontrib><creatorcontrib>Lee, Byeong-Gweon</creatorcontrib><creatorcontrib>Bhatta, Dinabandhu</creatorcontrib><title>Spatio-temporal dynamics of heavy metals in sediments of the river estuarine system: Mahanadi basin (India)</title><title>Environmental earth sciences</title><addtitle>Environ Earth Sci</addtitle><description>Dynamics of heavy metals in the surface sediments of Mahanadi river estuarine system were studied for three different seasons. This study demonstrates that the relative abundance of these metals follows in the order of Fe > Mn > Zn > Pb > Cr > Ni ≥ Co > Cu > Cd. The spatial pattern of heavy metals supported by enrichment ratio data, suggests their anthropogenic sources possibly from various industrial wastes and municipal wastes as well as agricultural runoff. The metal concentrations in estuarine sediments are relatively higher than in the river due to adsorption/accumulation of metals on sediments during saline mixing, while there is a decreasing trend of heavy metal concentrations towards the marine side. The temporal variations for metals, such as Fe, Mn, Zn, Ni and Pb exhibit higher values during monsoon season, which are related to agricultural runoff. Higher elemental concentrations are observed during pre-monsoon season for these above metals (except Ni) at the polluted stations and for metals, such as Cr, Co and Cd at all sites, which demonstrate the intensity of anthropogenic contribution. R-mode factor analysis reveals that “Fe–Mn oxy hydroxide”, “organic matter”, “CaCO₃”, and “textural variables” factors are the major controlling geochemical factors for the enrichment of heavy metals in river estuarine sediment and their seasonal variations, though their intensities were different for different seasons. The relationships among the stations are highlighted by cluster analysis, represented in dendrograms to categorize different contributing sites for the enrichment of heavy metals in the river estuarine system.</description><subject>adsorption</subject><subject>Agricultural runoff</subject><subject>anthropogenic activities</subject><subject>Anthropogenic factors</subject><subject>Basins</subject><subject>Biogeosciences</subject><subject>Brackish</subject><subject>Cadmium</subject><subject>calcium carbonate</subject><subject>chromium</subject><subject>cluster analysis</subject><subject>cobalt</subject><subject>Earth and Environmental Science</subject><subject>Earth Sciences</subject><subject>Earth, ocean, space</subject><subject>Engineering and environment geology. Geothermics</subject><subject>Environmental Science and Engineering</subject><subject>estuarine sediments</subject><subject>Exact sciences and technology</subject><subject>Factor analysis</subject><subject>Geochemistry</subject><subject>Geology</subject><subject>Heavy metals</subject><subject>Hydrology</subject><subject>Hydrology. Hydrogeology</subject><subject>Hydrology/Water Resources</subject><subject>Industrial wastes</subject><subject>iron</subject><subject>Lead</subject><subject>manganese</subject><subject>Metal concentrations</subject><subject>monsoon season</subject><subject>Monsoons</subject><subject>Municipal wastes</subject><subject>nickel</subject><subject>Organic matter</subject><subject>Original Article</subject><subject>Pollution, environment geology</subject><subject>Relative abundance</subject><subject>Rivers</subject><subject>Seasonal variations</subject><subject>Seasons</subject><subject>Sediments</subject><subject>Terrestrial Pollution</subject><subject>zinc</subject><issn>1866-6280</issn><issn>1866-6299</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9kU9rFTEUxQdRsLT9AK4MiFAXozd_Z-JOitZCSxdt1-FmkvSlzmSeybzC-_amTinioneTC_d3DoecpnlH4TMF6L4UypSSLVDeMqlFq141B7RXqlVM69fPew9vm-NS7qEOp1yDOmh-XW9xiXO7-Gk7ZxyJ2yec4lDIHMjG48OeTH7BsZCYSPEuTj4tf4_LxpMcH3wmviw7zDF5UvalGn0ll7jBhC4Si6XqTs6Ti_jpqHkTqpM_fnoPm9sf329Of7YXV2fnp98uWhRMLa3sLJcUpQVnQSlNJQpv1aCUdQE61Eip5F1gNrg-aNB6sK53CoRFZB3ww-Zk9d3m-feupjNTLIMfR0x-3hVDZf20jvaMVvTDf-j9vMuppqsUF1T0uusrRVdqyHMp2QezzXHCvDcUzGMDZm3A1AbMYwNGVc3HJ2csA44hYxpieRayviZVvKscW7lST-nO538SvGD-fhUFnA3e5Wp8e82ACgAKUgjN_wDnHJ5w</recordid><startdate>20140201</startdate><enddate>20140201</enddate><creator>Sundaray, Sanjay Kumar</creator><creator>Nayak, Binod Bihari</creator><creator>Lee, Byeong-Gweon</creator><creator>Bhatta, Dinabandhu</creator><general>Springer-Verlag</general><general>Springer Berlin Heidelberg</general><general>Springer</general><general>Springer Nature B.V</general><scope>FBQ</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7ST</scope><scope>7TG</scope><scope>7UA</scope><scope>7XB</scope><scope>88I</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>C1K</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>F1W</scope><scope>GNUQQ</scope><scope>H96</scope><scope>HCIFZ</scope><scope>KL.</scope><scope>L.G</scope><scope>M2P</scope><scope>PATMY</scope><scope>PCBAR</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PYCSY</scope><scope>Q9U</scope><scope>SOI</scope><scope>7QH</scope><scope>7TV</scope><scope>H97</scope></search><sort><creationdate>20140201</creationdate><title>Spatio-temporal dynamics of heavy metals in sediments of the river estuarine system: Mahanadi basin (India)</title><author>Sundaray, Sanjay Kumar ; Nayak, Binod Bihari ; Lee, Byeong-Gweon ; Bhatta, Dinabandhu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a426t-57b351a5b0db066915a4eb6c66bdf07a9a11537f2bfd8f9099cbd8d604baa2703</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>adsorption</topic><topic>Agricultural runoff</topic><topic>anthropogenic activities</topic><topic>Anthropogenic factors</topic><topic>Basins</topic><topic>Biogeosciences</topic><topic>Brackish</topic><topic>Cadmium</topic><topic>calcium carbonate</topic><topic>chromium</topic><topic>cluster analysis</topic><topic>cobalt</topic><topic>Earth and Environmental Science</topic><topic>Earth Sciences</topic><topic>Earth, ocean, space</topic><topic>Engineering and environment geology. 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This study demonstrates that the relative abundance of these metals follows in the order of Fe > Mn > Zn > Pb > Cr > Ni ≥ Co > Cu > Cd. The spatial pattern of heavy metals supported by enrichment ratio data, suggests their anthropogenic sources possibly from various industrial wastes and municipal wastes as well as agricultural runoff. The metal concentrations in estuarine sediments are relatively higher than in the river due to adsorption/accumulation of metals on sediments during saline mixing, while there is a decreasing trend of heavy metal concentrations towards the marine side. The temporal variations for metals, such as Fe, Mn, Zn, Ni and Pb exhibit higher values during monsoon season, which are related to agricultural runoff. Higher elemental concentrations are observed during pre-monsoon season for these above metals (except Ni) at the polluted stations and for metals, such as Cr, Co and Cd at all sites, which demonstrate the intensity of anthropogenic contribution. R-mode factor analysis reveals that “Fe–Mn oxy hydroxide”, “organic matter”, “CaCO₃”, and “textural variables” factors are the major controlling geochemical factors for the enrichment of heavy metals in river estuarine sediment and their seasonal variations, though their intensities were different for different seasons. The relationships among the stations are highlighted by cluster analysis, represented in dendrograms to categorize different contributing sites for the enrichment of heavy metals in the river estuarine system.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer-Verlag</pub><doi>10.1007/s12665-013-2594-6</doi><tpages>17</tpages></addata></record> |
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subjects | adsorption Agricultural runoff anthropogenic activities Anthropogenic factors Basins Biogeosciences Brackish Cadmium calcium carbonate chromium cluster analysis cobalt Earth and Environmental Science Earth Sciences Earth, ocean, space Engineering and environment geology. Geothermics Environmental Science and Engineering estuarine sediments Exact sciences and technology Factor analysis Geochemistry Geology Heavy metals Hydrology Hydrology. Hydrogeology Hydrology/Water Resources Industrial wastes iron Lead manganese Metal concentrations monsoon season Monsoons Municipal wastes nickel Organic matter Original Article Pollution, environment geology Relative abundance Rivers Seasonal variations Seasons Sediments Terrestrial Pollution zinc |
title | Spatio-temporal dynamics of heavy metals in sediments of the river estuarine system: Mahanadi basin (India) |
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