Molecular Transport through Surfactant-Covered Oil−Water Interfaces: Role of Physical Properties of Solutes and Surfactants in Creating Energy Barriers for Transport

Mechanisms of molecular transport across oil−water interfaces covered by nonionic surfactants are investigated using coarse-grained molecular dynamics simulations. Resistance of the surfactant monolayer to the solute transport is shown to be controlled by dense regions in the monolayer. The dense re...

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Veröffentlicht in:	Langmuir 2011-03, Vol.27 (6), p.2420-2436
Hauptverfasser:	Ahn, Yong Nam, Gupta, Ashish, Chauhan, Anuj, Kopelevich, Dmitry I
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology General and physical chemistry Interfaces: Adsorption, Reactions, Films, Forces Molecular Dynamics Simulation Oils - chemistry Surface physical chemistry Surface-Active Agents - chemistry Water - chemistry
Online-Zugang:	Volltext
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