Facile Synthesis of β- and α‑Arabinofuranosides and Application to Cell Wall Motifs of M. tuberculosis

Propargyl 1,2-orthoesters of arabinose are exploited for the synthesis of 1,2-trans furanosides; easily accessible 1,2-trans ribofuranosides are converted to challenging 1,2-cis-arabinofuranosides by oxidoreduction. Utility of these protocols was demonstrated by the successful synthesis of major str...

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Veröffentlicht in:	Organic letters 2013-05, Vol.15 (10), p.2466-2469
Hauptverfasser:	Thadke, Shivaji A, Mishra, Bijoyananda, Hotha, Srinivas
Format:	Artikel
Sprache:	eng
Schlagworte:	Arabinose - analogs & derivatives Arabinose - chemical synthesis Arabinose - chemistry Cell Wall - chemistry Glycosides - chemical synthesis Glycosides - chemistry Gold Molecular Structure Mycobacterium tuberculosis - chemistry Mycobacterium tuberculosis - metabolism Oxidation-Reduction
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