Selective Retention of Methanol over Ethanol by a Cyclen-Based Cryptand/Copper(II) Complex
A cyclen-based cryptand (2) was prepared in a two-step synthesis from dioxocyclen. When a Cu(CF3SO3)2 complex with 2 was prepared in methanol, the 2/Cu(CF3SO3)2 complex incorporated one methanol in the cavity formed by the diethyleneoxy unit and the NH group of the cyclen. When prepared in ethanol,...
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| Veröffentlicht in: | Inorganic chemistry 2013-10, Vol.52 (20), p.11697-11699 |
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| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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