A Giant Polyaluminum Species S−Al32 and Two Aluminum Polyoxocations Involving Coordination by Sulfate Ions S−Al32 and S−K−Al13

The giant polyaluminum species [Al32O8(OH)60(H2O)28(SO4)2]16+ (S−Al32) and [Al13O4(OH)25(H2O)10(SO4)]4+ (S−K−Al13) [S means that sulfate ions take part in coordination of the aluminum polycation; K represents the Keggin structure] were obtained in the structures of [Al32O8(OH)60(H2O)28(SO4)2][SO4]7[...

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Veröffentlicht in:Inorganic chemistry 2011-01, Vol.50 (2), p.559-564
Hauptverfasser: Sun, Zhong, Wang, Hui, Tong, Honggeer, Sun, Shaofan
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Sprache:eng
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