Synthesis, Crystal Structure, and Proton Conductivity of One-Dimensional, Two-Dimensional, and Three-Dimensional Zirconium Phosphonates Based on Glyphosate and Glyphosine

The reaction of two small phosphono-amino acids based on glycine (glyphosine and glyphosate) with zirconium under mild conditions led to the attainment of three related zirconium derivatives with 1D, 2D, and 3D structures of formulas ZrF[H3(O3PCH2NHCH2COO)2] (1), Zr3H8[(O3PCH2)2NCH2COO]4·2H2O (2), a...

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Veröffentlicht in:Inorganic chemistry 2013-10, Vol.52 (20), p.12131-12139
Hauptverfasser: Taddei, Marco, Donnadio, Anna, Costantino, Ferdinando, Vivani, Riccardo, Casciola, Mario
Format: Artikel
Sprache:eng
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