Estimating the Acidity of Transition Metal Hydride and Dihydrogen Complexes by Adding Ligand Acidity Constants

A simple equation (pK a THF = ∑A L + C charge + C nd + C d6) can be used to obtain an estimate of the pK a of diamagnetic transition metal hydride and dihydrogen complexes in tetrahydrofuran, and, by use of conversion equations, in other solvents. It involves adding acidity constants A L for each of...

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Veröffentlicht in:	Journal of the American Chemical Society 2014-02, Vol.136 (5), p.1948-1959
1. Verfasser:	Morris, Robert H
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetonitriles - chemistry Acids - chemistry Coordination Complexes - chemistry Ferrous Compounds - chemistry Hydrogen - chemistry Hydrogen Bonding Ligands Metallocenes Models, Chemical Solvents - chemistry Transition Elements - chemistry
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