Calcium and strontium salts of (glycinato-κ2N,O)oxidobis(peroxido-κ2O,O′)vanadate(V) tetrahydrate
The title salts calcium (glycinato‐κ2N,O)oxidobis(peroxido‐κ2O,O′)vanadate(V) tetrahydrate, Ca[VO(O2)2(NH2CH2COO)]·4H2O, and strontium (glycinato‐κ2N,O)oxidobis(peroxido‐κ2O,O′)vanadate(V) tetrahydrate, Sr[VO(O2)2(NH2CH2COO)]·4H2O, crystallized at pH ca 7.4 with similar lattice parameters. The glyci...
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Veröffentlicht in: | Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2013-12, Vol.69 (12), p.1494-1497 |
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creator | Higuchi, Takeshi Uchida, Ayana Hashimoto, Masato |
description | The title salts calcium (glycinato‐κ2N,O)oxidobis(peroxido‐κ2O,O′)vanadate(V) tetrahydrate, Ca[VO(O2)2(NH2CH2COO)]·4H2O, and strontium (glycinato‐κ2N,O)oxidobis(peroxido‐κ2O,O′)vanadate(V) tetrahydrate, Sr[VO(O2)2(NH2CH2COO)]·4H2O, crystallized at pH ca 7.4 with similar lattice parameters. The glycinate anion acts as a bidentate N,O‐chelating ligand, and the V atom has a pentagonal bipyramidal geometry, with two η2‐peroxo groups and the glycinate N atom in the equatorial plane, and one terminal oxo and a glycinate O atom at the axial positions. The H atoms of three of the four water molecules in the strontium salt exhibited disorder over three positions for each molecule. |
doi_str_mv | 10.1107/S0108270113031181 |
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The glycinate anion acts as a bidentate N,O‐chelating ligand, and the V atom has a pentagonal bipyramidal geometry, with two η2‐peroxo groups and the glycinate N atom in the equatorial plane, and one terminal oxo and a glycinate O atom at the axial positions. The H atoms of three of the four water molecules in the strontium salt exhibited disorder over three positions for each molecule.</description><identifier>ISSN: 0108-2701</identifier><identifier>EISSN: 1600-5759</identifier><identifier>DOI: 10.1107/S0108270113031181</identifier><language>eng</language><publisher>5 Abbey Square, Chester, Cheshire CH1 2HU, England: International Union of Crystallography</publisher><subject>(glycinato)oxidobis(peroxido)vanadate(V) ; Calcium ; calcium salt ; crystal structure ; Molecules ; Salt ; strontium salt ; Tetrahedra</subject><ispartof>Acta crystallographica. Section C, Crystal structure communications, 2013-12, Vol.69 (12), p.1494-1497</ispartof><rights>International Union of Crystallography, 2013</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c3451-7f73ef216c4886292b4c0aade14093c862c87d9ed0ee215af2842c1a6fafe0b43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1107%2FS0108270113031181$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1107%2FS0108270113031181$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids></links><search><creatorcontrib>Higuchi, Takeshi</creatorcontrib><creatorcontrib>Uchida, Ayana</creatorcontrib><creatorcontrib>Hashimoto, Masato</creatorcontrib><title>Calcium and strontium salts of (glycinato-κ2N,O)oxidobis(peroxido-κ2O,O′)vanadate(V) tetrahydrate</title><title>Acta crystallographica. Section C, Crystal structure communications</title><addtitle>Acta Cryst. C</addtitle><description>The title salts calcium (glycinato‐κ2N,O)oxidobis(peroxido‐κ2O,O′)vanadate(V) tetrahydrate, Ca[VO(O2)2(NH2CH2COO)]·4H2O, and strontium (glycinato‐κ2N,O)oxidobis(peroxido‐κ2O,O′)vanadate(V) tetrahydrate, Sr[VO(O2)2(NH2CH2COO)]·4H2O, crystallized at pH ca 7.4 with similar lattice parameters. The glycinate anion acts as a bidentate N,O‐chelating ligand, and the V atom has a pentagonal bipyramidal geometry, with two η2‐peroxo groups and the glycinate N atom in the equatorial plane, and one terminal oxo and a glycinate O atom at the axial positions. The H atoms of three of the four water molecules in the strontium salt exhibited disorder over three positions for each molecule.</description><subject>(glycinato)oxidobis(peroxido)vanadate(V)</subject><subject>Calcium</subject><subject>calcium salt</subject><subject>crystal structure</subject><subject>Molecules</subject><subject>Salt</subject><subject>strontium salt</subject><subject>Tetrahedra</subject><issn>0108-2701</issn><issn>1600-5759</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNqFkE1u2zAQRomgBeKmPUB3ArqxgaidISVRWgZGYwcw7EX6g66IMUWlSmXRJek23vVMWeYQOUROUqoOsmgXXXGG33sE8TH2GuEtIsh3l4BQcgmIAgRiiUdshAVAmsu8esZGQ5wO-TF74f01AHDOxYiZKXW63W0S6uvEB2f7MGyeuuAT2yTjq26v256CTe_v-PJ0NbE3bW3XrR9vjfszD8HqdPXw63byg3qqKZjxp0kSTHD0dV-7uL9kzxvqvHn1eJ6wj-fvP0zn6WI1u5ieLVItshxT2UhhGo6Fzsqy4BVfZxqIaoMZVELHK13KujI1GMMxp4aXGddIRUONgXUmTtj48O7W2e8744PatF6brqPe2J1XmFWZKETFZUTf_IVe253r4-8iVeSxL4kDhQdKO-u9M43aunZDbq8Q1FC8-qf46JQH52fbmf3_BXX2ZXo-E3GOanpQWx_MzZNK7psqpJC5-rycqflSAlwu5momfgNiOJXb</recordid><startdate>201312</startdate><enddate>201312</enddate><creator>Higuchi, Takeshi</creator><creator>Uchida, Ayana</creator><creator>Hashimoto, Masato</creator><general>International Union of Crystallography</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>201312</creationdate><title>Calcium and strontium salts of (glycinato-κ2N,O)oxidobis(peroxido-κ2O,O′)vanadate(V) tetrahydrate</title><author>Higuchi, Takeshi ; Uchida, Ayana ; Hashimoto, Masato</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3451-7f73ef216c4886292b4c0aade14093c862c87d9ed0ee215af2842c1a6fafe0b43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>(glycinato)oxidobis(peroxido)vanadate(V)</topic><topic>Calcium</topic><topic>calcium salt</topic><topic>crystal structure</topic><topic>Molecules</topic><topic>Salt</topic><topic>strontium salt</topic><topic>Tetrahedra</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Higuchi, Takeshi</creatorcontrib><creatorcontrib>Uchida, Ayana</creatorcontrib><creatorcontrib>Hashimoto, Masato</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Acta crystallographica. Section C, Crystal structure communications</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Higuchi, Takeshi</au><au>Uchida, Ayana</au><au>Hashimoto, Masato</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Calcium and strontium salts of (glycinato-κ2N,O)oxidobis(peroxido-κ2O,O′)vanadate(V) tetrahydrate</atitle><jtitle>Acta crystallographica. Section C, Crystal structure communications</jtitle><addtitle>Acta Cryst. C</addtitle><date>2013-12</date><risdate>2013</risdate><volume>69</volume><issue>12</issue><spage>1494</spage><epage>1497</epage><pages>1494-1497</pages><issn>0108-2701</issn><eissn>1600-5759</eissn><abstract>The title salts calcium (glycinato‐κ2N,O)oxidobis(peroxido‐κ2O,O′)vanadate(V) tetrahydrate, Ca[VO(O2)2(NH2CH2COO)]·4H2O, and strontium (glycinato‐κ2N,O)oxidobis(peroxido‐κ2O,O′)vanadate(V) tetrahydrate, Sr[VO(O2)2(NH2CH2COO)]·4H2O, crystallized at pH ca 7.4 with similar lattice parameters. The glycinate anion acts as a bidentate N,O‐chelating ligand, and the V atom has a pentagonal bipyramidal geometry, with two η2‐peroxo groups and the glycinate N atom in the equatorial plane, and one terminal oxo and a glycinate O atom at the axial positions. The H atoms of three of the four water molecules in the strontium salt exhibited disorder over three positions for each molecule.</abstract><cop>5 Abbey Square, Chester, Cheshire CH1 2HU, England</cop><pub>International Union of Crystallography</pub><doi>10.1107/S0108270113031181</doi><tpages>4</tpages></addata></record> |
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subjects | (glycinato)oxidobis(peroxido)vanadate(V) Calcium calcium salt crystal structure Molecules Salt strontium salt Tetrahedra |
title | Calcium and strontium salts of (glycinato-κ2N,O)oxidobis(peroxido-κ2O,O′)vanadate(V) tetrahydrate |
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