Dicobaltbisnorbornadienetetracarbonyl [Co 2 (Nbd) 2 (CO) 4 ] Reacts with Oxygen-Containing Alkynes and Gives Crossover Products in the Presence of other Alkenes

Dicobaltbisnorbornadienetetracarbonyl [Co 2 (Nbd) 2 (CO) 4 ] Reacts with Oxygen-Containing Alkynes and Gives Crossover Products in the Presence of other Alkenes

Dicobaltbisnorbornadienetetracarbonyl, [Co2(nbd)2(CO)4] DDTC, (nbd = norbornadiene) which has previously been reported to be unreactive with alkynes is shown to react with oxygen-containing alkynes; in the presence of other alkenes crossover reaction is seen which has important implications for the...

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Veröffentlicht in:Journal of chemical research 2008-09, Vol.2008 (9), p.516-519
Hauptverfasser: Coogan, Michael P, Wilkins, Derek S
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Alkenes
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description Dicobaltbisnorbornadienetetracarbonyl, [Co2(nbd)2(CO)4] DDTC, (nbd = norbornadiene) which has previously been reported to be unreactive with alkynes is shown to react with oxygen-containing alkynes; in the presence of other alkenes crossover reaction is seen which has important implications for the mechanism of this, and possibly other, reactions.
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title Dicobaltbisnorbornadienetetracarbonyl [Co 2 (Nbd) 2 (CO) 4 ] Reacts with Oxygen-Containing Alkynes and Gives Crossover Products in the Presence of other Alkenes
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