Effects of Cu on the precipitation of intermetallic compounds and the intergranular corrosion of hyper duplex stainless steels

► Cu addition to the base alloy reduces the total amount of intermetallic phases. ► Retardation of intermetallic phases formation due to the decrease of activity of Mo. ► The Cu added alloy reduces the degree of sensitization. To elucidate the effects of Cu on the precipitation of intermetallic comp...

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Veröffentlicht in:Corrosion science 2013-01, Vol.66, p.217-224
Hauptverfasser: Jeon, Soon-Hyeok, Kim, Soon-Tae, Lee, In-Sung, Kim, Ji-Soo, Kim, Kwang-Tae, Park, Yong-Soo
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container_end_page 224
container_issue
container_start_page 217
container_title Corrosion science
container_volume 66
creator Jeon, Soon-Hyeok
Kim, Soon-Tae
Lee, In-Sung
Kim, Ji-Soo
Kim, Kwang-Tae
Park, Yong-Soo
description ► Cu addition to the base alloy reduces the total amount of intermetallic phases. ► Retardation of intermetallic phases formation due to the decrease of activity of Mo. ► The Cu added alloy reduces the degree of sensitization. To elucidate the effects of Cu on the precipitation of intermetallic compounds and the intergranular corrosion of the hyper duplex stainless steels, a double loop potentiokinetic reactivation test, a scanning electron microscope analysis and thermodynamic calculation were conducted. The addition of Cu to the base alloy reduces the total amount of intermetallic compounds. Particularly, Cu addition to the base alloy results in pronouncedly suppressing the amount of sigma phase whereas it slightly increases chi phases. The Cu added alloy reduces the degree of sensitization due to the delayed precipitation of intermetallic compounds, compared with that of the base alloy.
doi_str_mv 10.1016/j.corsci.2012.09.023
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subjects A. Copper
A. Stainless
Alloying additive
Applied sciences
B. Polarization
B. SEM
C. Intergranular corrosion
Copper
Corrosion
Corrosion environments
Duplex stainless steels
Exact sciences and technology
Intergranular corrosion
Intermetallic compounds
Intermetallics
Metals. Metallurgy
Precipitation
Scanning electron microscopy
title Effects of Cu on the precipitation of intermetallic compounds and the intergranular corrosion of hyper duplex stainless steels
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