Reversible photochromism of an N-salicylidene aniline anion

Reversible photochromism of an N-salicylidene aniline anion

The first N-salicylidene aniline anion showing reversible solid state thermochromic and photochromic properties is described. The photo-isomerization involves a trans-keto form which is stabilized thanks to the local anion surrounding. This photochromic anion can be used as a guest for the preparati...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-01, Vol.50 (6), p.649-651
Hauptverfasser: Jacquemin, Pierre-Loïc, Robeyns, Koen, Devillers, Michel, Garcia, Yann
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Aniline
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container_title Chemical communications (Cambridge, England)
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creator Jacquemin, Pierre-Loïc
Robeyns, Koen
Devillers, Michel
Garcia, Yann
description The first N-salicylidene aniline anion showing reversible solid state thermochromic and photochromic properties is described. The photo-isomerization involves a trans-keto form which is stabilized thanks to the local anion surrounding. This photochromic anion can be used as a guest for the preparation of hybrid materials by insertion into a cationic host matrix.
doi_str_mv 10.1039/c3cc45080e
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Aniline
title Reversible photochromism of an N-salicylidene aniline anion
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