Mutually ordered self-assembly of discotic liquid crystal-graphene nanocomposites

The room temperature anthraquinone discotic 1,5-dihydroxy-2,3,6,7-tetrakis(3,7-dimethyloctyloxy)-9,10-anthraquinone (RTAQ) self-assembles in the presence of octadecylamine functionalized graphene (f-graphene) into an ordered sandwich like structure, where the discotic molecules form columnar structu...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-01, Vol.50 (6), p.710-712
Hauptverfasser: Shivanandareddy, Avinash B, Krishnamurthy, Suvratha, Lakshminarayanan, V, Kumar, Sandeep
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container_title Chemical communications (Cambridge, England)
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creator Shivanandareddy, Avinash B
Krishnamurthy, Suvratha
Lakshminarayanan, V
Kumar, Sandeep
description The room temperature anthraquinone discotic 1,5-dihydroxy-2,3,6,7-tetrakis(3,7-dimethyloctyloxy)-9,10-anthraquinone (RTAQ) self-assembles in the presence of octadecylamine functionalized graphene (f-graphene) into an ordered sandwich like structure, where the discotic molecules form columnar structures on graphene sheets. Cryo-SEM and SEM images provide evidence for this ordering. This behaviour is also supported by polarizing optical microscopy, differential scanning calorimetry, X-ray diffraction and conductivity studies of nanocomposites.
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subjects Columnar structure
title Mutually ordered self-assembly of discotic liquid crystal-graphene nanocomposites
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