Coherent electron spin manipulation in a dilute oriented ensemble of molecular nanomagnets: pulsed EPR on doped single crystals

Doping a Cr7Zn molecular nanomagnet into a diamagnetic and isostructural host allows pulsed X-band EPR on single crystals, including relaxation and nutation experiments on the S = 3/2 ground state.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-01, Vol.50 (1), p.91-93
Hauptverfasser: Moro, Fabrizio, Kaminski, Danielle, Tuna, Floriana, Whitehead, George F S, Timco, Grigore A, Collison, David, Winpenny, Richard E P, Ardavan, Arzhang, McInnes, Eric J L
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Sprache:eng
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Zusammenfassung:Doping a Cr7Zn molecular nanomagnet into a diamagnetic and isostructural host allows pulsed X-band EPR on single crystals, including relaxation and nutation experiments on the S = 3/2 ground state.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc46326e