Guanidine-Catalyzed Triple Functionalization of [gamma]-Substituted Allenoates with Aldehydes by a Four-Step Reaction Cascade

The bicyclic guanidine 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) was discovered as an efficient catalyst for the reaction of [gamma]-substituted allenoates with aromatic aldehydes. 4H-1,3-Dioxin-6-ylpropanoates with four newly formed bonds and four stereogenic centers were obtained in good yields an...

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Veröffentlicht in:	Advanced synthesis & catalysis 2013-02, Vol.355 (2-3), p.297-302
Hauptverfasser:	Selig, Philipp, Turockin, Aleksej, Raven, William
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes
Online-Zugang:	Volltext
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