On the Gold-Catalyzed Intramolecular 7-exo-trig Hydroamination of Allenes

Aniline derivatives with allene side tethers were tested as substrates for a gold‐catalyzed 7‐exo‐trig hydroamination reaction. The nucleophilicity of the aniline derivatives plays an important role for the outcome of the reaction. While electron‐deficient protecting groups at the nitrogen led to co...

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Veröffentlicht in:	Advanced synthesis & catalysis 2013-05, Vol.355 (7), p.1383-1393
Hauptverfasser:	Pflästerer, Daniel, Dolbundalchok, Praphasiri, Rafique, Shahid, Rudolph, Matthias, Rominger, Frank, Hashmi, A. Stephen K.
Format:	Artikel
Sprache:	eng
Schlagworte:	alkenes Allene allenes benzoxazepines gold hydroamination
Online-Zugang:	Volltext
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