Dicobalt-μ-oxo polyoxometalate compound, [(α(2)-P2W17O61Co)2O](14-): a potent species for water oxidation, C-H bond activation, and oxygen transfer

High-valent oxo compounds of transition metals are often implicated as active species in oxygenation of hydrocarbons through carbon-hydrogen bond activation or oxygen transfer and also in water oxidation. Recently, several examples of cobalt-catalyzed water oxidation have been reported, and cobalt(I...

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Veröffentlicht in:	Inorganic chemistry 2014-02, Vol.53 (3), p.1779-1787
Hauptverfasser:	Barats-Damatov, Delina, Shimon, Linda J W, Weiner, Lev, Schreiber, Roy E, Jiménez-Lozano, Pablo, Poblet, Josep M, de Graaf, Coen, Neumann, Ronny
Format:	Artikel
Sprache:	eng
Schlagworte:	Cobalt - chemistry Crystallography, X-Ray Hydrogen Bonding Models, Molecular Oxidation-Reduction Oxygen - chemistry Ozone - chemistry Spectrum Analysis Tungsten Compounds - chemistry Water - chemistry
Online-Zugang:	Volltext
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