Energetic aqueous rechargeable sodium-ion battery based on Na2 CuFe(CN)6 -NaTi2 (PO4 )3 intercalation chemistry
Aqueous rechargeable sodium-ion batteries have the potential to meet growing demand for grid-scale electric energy storage because of the widespread availability and low cost of sodium resources. In this study, we synthesized a Na-rich copper hexacyanoferrate(II) Na2 CuFe(CN)6 as a high potential ca...
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| Veröffentlicht in: | ChemSusChem 2014-02, Vol.7 (2), p.407-411 |
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| container_title | ChemSusChem |
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| creator | Wu, Xian-Yong Sun, Meng-Ying Shen, Yi-Fei Qian, Jiang-Feng Cao, Yu-Liang Ai, Xin-Ping Yang, Han-Xi |
| description | Aqueous rechargeable sodium-ion batteries have the potential to meet growing demand for grid-scale electric energy storage because of the widespread availability and low cost of sodium resources. In this study, we synthesized a Na-rich copper hexacyanoferrate(II) Na2 CuFe(CN)6 as a high potential cathode and used NaTi2 (PO4 )3 as a Na-deficient anode to assemble an aqueous sodium ion battery. This battery works very well with a high average discharge voltage of 1.4 V, a specific energy of 48 Wh kg(-1) , and an excellent high-rate cycle stability with approximately 90 % capacity retention over 1000 cycles, achieving a new record in the electrochemical performance of aqueous Na-ion batteries. Moreover, all the anode, cathode, and electrolyte materials are low cost and naturally abundant and are affordable for widespread applications. |
| doi_str_mv | 10.1002/cssc.201301036 |
| format | Article |
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In this study, we synthesized a Na-rich copper hexacyanoferrate(II) Na2 CuFe(CN)6 as a high potential cathode and used NaTi2 (PO4 )3 as a Na-deficient anode to assemble an aqueous sodium ion battery. This battery works very well with a high average discharge voltage of 1.4 V, a specific energy of 48 Wh kg(-1) , and an excellent high-rate cycle stability with approximately 90 % capacity retention over 1000 cycles, achieving a new record in the electrochemical performance of aqueous Na-ion batteries. Moreover, all the anode, cathode, and electrolyte materials are low cost and naturally abundant and are affordable for widespread applications.</description><identifier>EISSN: 1864-564X</identifier><identifier>DOI: 10.1002/cssc.201301036</identifier><identifier>PMID: 24464957</identifier><language>eng</language><publisher>Germany</publisher><subject>Electric Power Supplies ; Electrodes ; Ferrocyanides - chemistry ; Sodium - chemistry ; Titanium - chemistry ; Water - chemistry</subject><ispartof>ChemSusChem, 2014-02, Vol.7 (2), p.407-411</ispartof><rights>Copyright © 2014 WILEY-VCH Verlag GmbH & Co. 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| source | MEDLINE; Wiley Online Library All Journals |
| subjects | Electric Power Supplies Electrodes Ferrocyanides - chemistry Sodium - chemistry Titanium - chemistry Water - chemistry |
| title | Energetic aqueous rechargeable sodium-ion battery based on Na2 CuFe(CN)6 -NaTi2 (PO4 )3 intercalation chemistry |
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