Novel Catalyst System for Hydrostannation of Alkynes
A catalyst system was developed for the highly regio‐ and stereoselective hydrostannation of a range of alkynes with tributylstannane under mild conditions. The active catalytic species was generated from a stable diruthenium complex by illuminating household fluorescent light (30 W) at room tempera...
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| Veröffentlicht in: | Chemistry : a European journal 2014-01, Vol.20 (5), p.1267-1271 |
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| container_end_page | 1271 |
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| container_issue | 5 |
| container_start_page | 1267 |
| container_title | Chemistry : a European journal |
| container_volume | 20 |
| creator | Gupta, Sreya Do, Youngshil Lee, Jin Hee Lee, Miryeong Han, Junghoon Rhee, Young Ho Park, Jaiwook |
| description | A catalyst system was developed for the highly regio‐ and stereoselective hydrostannation of a range of alkynes with tributylstannane under mild conditions. The active catalytic species was generated from a stable diruthenium complex by illuminating household fluorescent light (30 W) at room temperature.
An efficient catalyst system was developed for the highly regio‐ and stereoselective hydrostannation of a wide range of alkynes with tributylstannane under mild conditions (see scheme). The active catalytic species was generated from a stable diruthenium complex by illuminating with household fluorescent light (30 W) at room temperature. |
| doi_str_mv | 10.1002/chem.201303057 |
| format | Article |
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An efficient catalyst system was developed for the highly regio‐ and stereoselective hydrostannation of a wide range of alkynes with tributylstannane under mild conditions (see scheme). The active catalytic species was generated from a stable diruthenium complex by illuminating with household fluorescent light (30 W) at room temperature.</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201303057</identifier><identifier>PMID: 24402671</identifier><identifier>CODEN: CEUJED</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>alkynes ; Chemistry ; hydrostannation ; photolysis ; radicals ; ruthenium</subject><ispartof>Chemistry : a European journal, 2014-01, Vol.20 (5), p.1267-1271</ispartof><rights>Copyright © 2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4777-f6a17c3da2995545f1fed35b676d3926a7d36c7869c613c5a261725e420730023</citedby><cites>FETCH-LOGICAL-c4777-f6a17c3da2995545f1fed35b676d3926a7d36c7869c613c5a261725e420730023</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.201303057$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.201303057$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,777,781,1412,27905,27906,45555,45556</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/24402671$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Gupta, Sreya</creatorcontrib><creatorcontrib>Do, Youngshil</creatorcontrib><creatorcontrib>Lee, Jin Hee</creatorcontrib><creatorcontrib>Lee, Miryeong</creatorcontrib><creatorcontrib>Han, Junghoon</creatorcontrib><creatorcontrib>Rhee, Young Ho</creatorcontrib><creatorcontrib>Park, Jaiwook</creatorcontrib><title>Novel Catalyst System for Hydrostannation of Alkynes</title><title>Chemistry : a European journal</title><addtitle>Chem. Eur. J</addtitle><description>A catalyst system was developed for the highly regio‐ and stereoselective hydrostannation of a range of alkynes with tributylstannane under mild conditions. The active catalytic species was generated from a stable diruthenium complex by illuminating household fluorescent light (30 W) at room temperature.
An efficient catalyst system was developed for the highly regio‐ and stereoselective hydrostannation of a wide range of alkynes with tributylstannane under mild conditions (see scheme). The active catalytic species was generated from a stable diruthenium complex by illuminating with household fluorescent light (30 W) at room temperature.</description><subject>alkynes</subject><subject>Chemistry</subject><subject>hydrostannation</subject><subject>photolysis</subject><subject>radicals</subject><subject>ruthenium</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqFkD1PwzAQhi0EoqWwMqJILCwp_oh9eERRaRGlVBSExGK5iSPS5qPEKZB_j6uUCrGw3C3P--juReiU4D7BmF5GbybvU0wYZpjDHuoSTonPQPB91MUyAF9wJjvoyNoFxlgKxg5RhwYBpgJIFwWT8sNkXqhrnTW29mZumNxLysobNXFV2loXha7TsvDKxLvOlk1h7DE6SHRmzcl299DzzeApHPnjh-FteD32owAA_ERoAhGLNZWS84AnJDEx43MBImaSCg0xExFcCRkJwiKuqSBAuQkoBuaeYz100XpXVfm-NrZWeWojk2W6MOXaKhI4iwTMuUPP_6CLcl0V7jpFQAhwFCGO6rdU5D6zlUnUqkpzXTWKYLXpU236VLs-XeBsq13PcxPv8J8CHSBb4DPNTPOPToWjwf1vud9mU9f51y6rq6USwICrl8lQTR9f70azCVVT9g1avo36</recordid><startdate>20140127</startdate><enddate>20140127</enddate><creator>Gupta, Sreya</creator><creator>Do, Youngshil</creator><creator>Lee, Jin Hee</creator><creator>Lee, Miryeong</creator><creator>Han, Junghoon</creator><creator>Rhee, Young Ho</creator><creator>Park, Jaiwook</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope></search><sort><creationdate>20140127</creationdate><title>Novel Catalyst System for Hydrostannation of Alkynes</title><author>Gupta, Sreya ; Do, Youngshil ; Lee, Jin Hee ; Lee, Miryeong ; Han, Junghoon ; Rhee, Young Ho ; Park, Jaiwook</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4777-f6a17c3da2995545f1fed35b676d3926a7d36c7869c613c5a261725e420730023</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>alkynes</topic><topic>Chemistry</topic><topic>hydrostannation</topic><topic>photolysis</topic><topic>radicals</topic><topic>ruthenium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gupta, Sreya</creatorcontrib><creatorcontrib>Do, Youngshil</creatorcontrib><creatorcontrib>Lee, Jin Hee</creatorcontrib><creatorcontrib>Lee, Miryeong</creatorcontrib><creatorcontrib>Han, Junghoon</creatorcontrib><creatorcontrib>Rhee, Young Ho</creatorcontrib><creatorcontrib>Park, Jaiwook</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gupta, Sreya</au><au>Do, Youngshil</au><au>Lee, Jin Hee</au><au>Lee, Miryeong</au><au>Han, Junghoon</au><au>Rhee, Young Ho</au><au>Park, Jaiwook</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Novel Catalyst System for Hydrostannation of Alkynes</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chem. Eur. J</addtitle><date>2014-01-27</date><risdate>2014</risdate><volume>20</volume><issue>5</issue><spage>1267</spage><epage>1271</epage><pages>1267-1271</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><coden>CEUJED</coden><abstract>A catalyst system was developed for the highly regio‐ and stereoselective hydrostannation of a range of alkynes with tributylstannane under mild conditions. The active catalytic species was generated from a stable diruthenium complex by illuminating household fluorescent light (30 W) at room temperature.
An efficient catalyst system was developed for the highly regio‐ and stereoselective hydrostannation of a wide range of alkynes with tributylstannane under mild conditions (see scheme). The active catalytic species was generated from a stable diruthenium complex by illuminating with household fluorescent light (30 W) at room temperature.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>24402671</pmid><doi>10.1002/chem.201303057</doi><tpages>5</tpages></addata></record> |
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| ispartof | Chemistry : a European journal, 2014-01, Vol.20 (5), p.1267-1271 |
| issn | 0947-6539 1521-3765 |
| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | alkynes Chemistry hydrostannation photolysis radicals ruthenium |
| title | Novel Catalyst System for Hydrostannation of Alkynes |
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