Carbaborane-Substituted 1,2,3-Triphospholanes and 1-Aza-2,5-diphospholane: New Synthetic Approaches
New phosphorus‐containing, five‐membered P,P,P and P,N,P heterocycles were synthesized and fully characterized. The P,P,P heterocycles, 1,2,3‐triphospholanes, can be synthesized by two different facile pathways, whereas the P,N,P compound, a 1‐aza‐2,5‐diphospholane, can only be obtained with silylam...
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| Veröffentlicht in: | Chemistry : a European journal 2014-01, Vol.20 (5), p.1434-1439 |
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| container_issue | 5 |
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| container_title | Chemistry : a European journal |
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| creator | Kreienbrink, Anika Heinicke, Sarah Duong Pham, Thi Thuy Frank, René Lönnecke, Peter Hey-Hawkins, Evamarie |
| description | New phosphorus‐containing, five‐membered P,P,P and P,N,P heterocycles were synthesized and fully characterized. The P,P,P heterocycles, 1,2,3‐triphospholanes, can be synthesized by two different facile pathways, whereas the P,N,P compound, a 1‐aza‐2,5‐diphospholane, can only be obtained with silylamine.
Carbaboranyl‐based triphospholanes (see figure) are readily available by two synthetic routes. The carbaboranyl backbone renders these phosphaheterocycles water stable and moderately air stable. |
| doi_str_mv | 10.1002/chem.201302878 |
| format | Article |
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Carbaboranyl‐based triphospholanes (see figure) are readily available by two synthetic routes. The carbaboranyl backbone renders these phosphaheterocycles water stable and moderately air stable.</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201302878</identifier><identifier>PMID: 24357460</identifier><identifier>CODEN: CEUJED</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>azadiphospholane ; carbaborane ; carborane ; Chemistry ; heterocycles ; phosphorous heterocycles ; triphospholane</subject><ispartof>Chemistry : a European journal, 2014-01, Vol.20 (5), p.1434-1439</ispartof><rights>Copyright © 2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4778-2d7e8f8a7480a91e6cc5e2fe523c627d6199394cada5f54ffadf0d0327642243</citedby><cites>FETCH-LOGICAL-c4778-2d7e8f8a7480a91e6cc5e2fe523c627d6199394cada5f54ffadf0d0327642243</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.201302878$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.201302878$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1416,27922,27923,45572,45573</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/24357460$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Kreienbrink, Anika</creatorcontrib><creatorcontrib>Heinicke, Sarah</creatorcontrib><creatorcontrib>Duong Pham, Thi Thuy</creatorcontrib><creatorcontrib>Frank, René</creatorcontrib><creatorcontrib>Lönnecke, Peter</creatorcontrib><creatorcontrib>Hey-Hawkins, Evamarie</creatorcontrib><title>Carbaborane-Substituted 1,2,3-Triphospholanes and 1-Aza-2,5-diphospholane: New Synthetic Approaches</title><title>Chemistry : a European journal</title><addtitle>Chem. Eur. J</addtitle><description>New phosphorus‐containing, five‐membered P,P,P and P,N,P heterocycles were synthesized and fully characterized. The P,P,P heterocycles, 1,2,3‐triphospholanes, can be synthesized by two different facile pathways, whereas the P,N,P compound, a 1‐aza‐2,5‐diphospholane, can only be obtained with silylamine.
Carbaboranyl‐based triphospholanes (see figure) are readily available by two synthetic routes. The carbaboranyl backbone renders these phosphaheterocycles water stable and moderately air stable.</description><subject>azadiphospholane</subject><subject>carbaborane</subject><subject>carborane</subject><subject>Chemistry</subject><subject>heterocycles</subject><subject>phosphorous heterocycles</subject><subject>triphospholane</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqFkDtPIzEUhS20CMKjpUQjbbNFHK7fY7oosIAEQUAk6CzH41EGkkzWnlE2--vXUSBCNBRXLu53zj0-CJ0Q6BEAeuYmftajQBjQXOU7qEMEJZgpKX6gDmiusBRM76ODGF8BQEvG9tA-5UwoLqGD3MCGsR3Xwc49fmrHsamatvFFRrq0y_AoVItJHdNMExAzO08b3P9nMe0KXHxenmdDv8yeVvNm4pvKZf3FItQ25YtHaLe00-iP399DNPp9ORpc49v7q5tB_xY7rlSOaaF8XuZW8RysJl46JzwtvaDMSaoKSbRmmjtbWFEKXpa2KKEARpXkNP3oEP3a2Ka7f1ofGzOrovPTdbi6jYZwTaWWWquE_vyCvtZtmKdwhigplVYALFG9DeVCHWPwpVmEambDyhAw6_bNun2zbT8JTt9t2_HMF1v8o-4E6A2wrKZ-9Y2dGVxf3n02xxttFRv_d6u14c1IxZQwz8Mr8_IwzHNy8WiA_QfwUJ6q</recordid><startdate>20140127</startdate><enddate>20140127</enddate><creator>Kreienbrink, Anika</creator><creator>Heinicke, Sarah</creator><creator>Duong Pham, Thi Thuy</creator><creator>Frank, René</creator><creator>Lönnecke, Peter</creator><creator>Hey-Hawkins, Evamarie</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope></search><sort><creationdate>20140127</creationdate><title>Carbaborane-Substituted 1,2,3-Triphospholanes and 1-Aza-2,5-diphospholane: New Synthetic Approaches</title><author>Kreienbrink, Anika ; Heinicke, Sarah ; Duong Pham, Thi Thuy ; Frank, René ; Lönnecke, Peter ; Hey-Hawkins, Evamarie</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4778-2d7e8f8a7480a91e6cc5e2fe523c627d6199394cada5f54ffadf0d0327642243</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>azadiphospholane</topic><topic>carbaborane</topic><topic>carborane</topic><topic>Chemistry</topic><topic>heterocycles</topic><topic>phosphorous heterocycles</topic><topic>triphospholane</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kreienbrink, Anika</creatorcontrib><creatorcontrib>Heinicke, Sarah</creatorcontrib><creatorcontrib>Duong Pham, Thi Thuy</creatorcontrib><creatorcontrib>Frank, René</creatorcontrib><creatorcontrib>Lönnecke, Peter</creatorcontrib><creatorcontrib>Hey-Hawkins, Evamarie</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kreienbrink, Anika</au><au>Heinicke, Sarah</au><au>Duong Pham, Thi Thuy</au><au>Frank, René</au><au>Lönnecke, Peter</au><au>Hey-Hawkins, Evamarie</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Carbaborane-Substituted 1,2,3-Triphospholanes and 1-Aza-2,5-diphospholane: New Synthetic Approaches</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chem. Eur. J</addtitle><date>2014-01-27</date><risdate>2014</risdate><volume>20</volume><issue>5</issue><spage>1434</spage><epage>1439</epage><pages>1434-1439</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><coden>CEUJED</coden><abstract>New phosphorus‐containing, five‐membered P,P,P and P,N,P heterocycles were synthesized and fully characterized. The P,P,P heterocycles, 1,2,3‐triphospholanes, can be synthesized by two different facile pathways, whereas the P,N,P compound, a 1‐aza‐2,5‐diphospholane, can only be obtained with silylamine.
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| subjects | azadiphospholane carbaborane carborane Chemistry heterocycles phosphorous heterocycles triphospholane |
| title | Carbaborane-Substituted 1,2,3-Triphospholanes and 1-Aza-2,5-diphospholane: New Synthetic Approaches |
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